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1. 发明申请

WO2008042498A1 POLYCARBONATE-POLYSILOXANE COPOLYMERS, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：聚碳酸酯 - 聚硅氧烷共聚物，制备方法和形成的制品
公开(公告)号：WO2008042498A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/074720
申请日：2007-07-30
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , MULLEN, Brian, D.
发明人： LENS, Jan, Pleun , MULLEN, Brian, D.
IPC分类号： C08G64/18
CPC分类号： C08G64/186 , C08G77/448
摘要： A polycarbonate copolymer comprising 40 to 89 mol% of units derived from a bisphenol of the formula (1) wherein R a' and R b' are each independently C 1-12 alkyl, T is a C 5-16 cycloalkylene, a C 5-16 cylcloalkyliden, a C 1-5 alkylene, a C 1-5 alkylidene, a C 6-13 arylene, a C 7-12 arylatkylene, C 7-12 arylalkylidene, a C 7-12 alkyiarylene, or a a C 7-12 arylenealkyi, and r and s are each independently 1 to 4; 2 to 35 wt.% of units derived from a polysiloxane diol of the formulas (2) or (2') or a combination thereof, wherein Ar is a substituted or unsubstituted C 6-36 arylene group, each R is the same or different C 1-13 monovalent organic group, each R 6 is the same or different divalent C 1 -C 30 organic group, and E is an integer from 4 to 100; and 11 to 60 mol% of units derived from a dihydroxy aromatic compound of formula (3) wherein R a and R b are each independently a halogen or C 1-12 alkyl group, X a is a direct bond or a C 1-18 organic group, p and q are each independently integers of 0 to 4, and the dihydroxy aromatic compound of formula 3 is not the same as the bisphenol of formula 1 or the polysiloxane diols. The polymers are of particular utility in medical applications.
摘要翻译：包含40至89摩尔％的衍生自式（1）的双酚的单元的聚碳酸酯共聚物，其中R a a'和R b''各自独立地为C 1-12烷基，T是C 5-16亚烷基，C 5-16亚烷基亚烷基，C 1-5 - 亚烷基亚烷基，C 1-5亚烷基，C 6-13亚芳基，C 7-12芳基亚烷基，C 7 -12芳烷基亚烷基，C 7-12亚烷基亚芳基或C 7-12亚芳基烷基，r和s各自独立地为1至4; 2〜35重量％的衍生自式（2）或（2'）的聚硅氧烷二醇的单元或其组合，其中Ar是取代或未取代的C 6〜36亚芳基，每个R是相同或不同的C 1-13个一价有机基团，每个R 6是相同或不同的二价C 1 -C 1 - SUB> 30 有机基团，E为4至100的整数; 和11至60摩尔％的衍生自式（3）的二羟基芳族化合物的单元，其中R a和R b各自独立地为卤素或C 1 -12个烷基，X a是直接键或C 1-18族有机基团，p和q各自独立地为0至4的整数，并且式3的二羟基芳族化合物与式1的双酚或聚硅氧烷二醇不同。聚合物在医疗应用中特别有用。

2. 发明申请

WO2008054884A2 FLAME RETARDANT AND SCRATCH RESISTANT THERMOPLASTIC POLYCARBONATE COMPOSITIONS 审中-公开
标题翻译：阻燃和抗刮擦热塑性聚碳酸酯组合物
公开(公告)号：WO2008054884A2
公开(公告)日：2008-05-08
申请号：PCT/US2007/070674
申请日：2007-06-08
申请人： GENERAL ELECTRIC COMPANY , SIRIPURAPU, Srinivas , AGARWAL, Naveen , LENS, Jan, Pleun
发明人： SIRIPURAPU, Srinivas , AGARWAL, Naveen , LENS, Jan, Pleun
CPC分类号： C08L69/00 , C08K5/005 , C08K5/523 , C08L51/04 , C08L53/00 , C08L55/02 , C08L83/10 , C08L2666/02
摘要： A thermoplastic composition comprising in combination a polycarbonate homopolymer or copolymer comprising repeat carbonate units having the following structure: (I) wherein Ri and R2 are independently at each occurrence a Ci -C4 alkyl, n and p are each an integer having a value of 1 to 4, and T is selected from the group consisting of C5-Ci0 cycloalkanes attached to the aryl groups at one or two carbons, Ci-C5 alkyl groups, C6-C13 aryl groups, and C7-C12 aryl alkyl groups; an impact modifier, wherein the impact modifier comprises a first impact modifier comprising a polycarbonate - polysiloxane copolymer and a second impact modifier different from the first impact modifier; and a flame retardant is disclosed. The compositions have excellent scratch resistance as well as an improved balance of physical properties such as impact strength and spiral flow, while at the same time maintaining their good flame performance.
摘要翻译：一种热塑性组合物，其包含组合包含具有以下结构的重复碳酸酯单元的聚碳酸酯均聚物或共聚物：（I）其中R 1和R 2在每次出现时独立地为C 1 -C 4烷基，n和p为每个整数具有1至4的值，并且T选自由一个或两个碳原子连接至芳基的C 1 -C 10环烷烃，C 1 -C 5烷基，C 6 -C 13芳基和C 7 -C 10芳基组成的组， C12芳基烷基; 冲击改性剂，其中所述抗冲改性剂包含第一抗冲改性剂，所述第一抗冲改性剂包含聚碳酸酯 - 聚硅氧烷共聚物和不同于所述第一抗冲改性剂的第二抗冲改性剂; 并公开了阻燃剂。该组合物具有优异的耐刮擦性以及物理性能如冲击强度和螺旋流动的平衡的改善，同时保持其良好的火焰性能。

3. 发明申请

WO2004041907A1 METHOD FOR MAKING COPOLYCARBONATES 审中-公开
标题翻译：制备共聚碳酸酯的方法
公开(公告)号：WO2004041907A1
公开(公告)日：2004-05-21
申请号：PCT/US2003/033716
申请日：2003-10-24
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , KAMPS, Jan, Henk
发明人： LENS, Jan, Pleun , KAMPS, Jan, Henk
IPC分类号： C08G64/30
CPC分类号： C08G64/307 , C08G64/06
摘要： A melt polymerization method is presented which permits the efficient preparation of copolycarbonates in which one or more of the constituent dehydroxy aromatic compounds employed is relatively volatile, having a boiling point of less than about 340 °C. Relatively volatile dihydroxy aromatic compounds are illustrated by dihydroxybenzenes such as hydroquinone, methyl hydroquinone and resorcinol. Known methods for the preparation of members of this class of copolycarbonates, such as the melt reaction of bisphenol A and resorcinol diphenyl carbonate in the presence of sodium hydroxide and tetraalkylammonium salt catalyst systems, suffer losses in efficiency due to the resorcinol being entrained out of the polymerization mixture with by-product phenol. Catalyst systems including quaternary phosphonium salts are shown to have improved performance with respect to the amount of volatile dihydroxy aromatic compound actually incorporated into the product copolycarbonate.
摘要翻译：提出了熔融聚合方法，其可以有效地制备其中一种或多种所用的组分脱羟基芳族化合物相对挥发的共聚碳酸酯，其沸点低于约340℃。相对挥发性的二羟基芳族化合物由二羟基苯如氢醌，甲基氢醌和间苯二酚表示。用于制备这种类型的共聚碳酸酯的成员的已知方法，例如双酚A和间苯二酚碳酸二苯酯在氢氧化钠和四烷基铵盐催化剂体系的存在下的熔融反应，由于间苯二酚被夹带在聚合混合物与副产物苯酚。显示出包含季鏻盐的催化剂体系相对于实际掺入到产物共聚碳酸酯中的挥发性二羟基芳族化合物的量具有改进的性能。

4. 发明申请

WO2006031668A1 METHOD FOR INCORPORATING ALKYL ESTER ENDGROUPS TO IMPROVE THE RELEASE PROPERTIES OF MELT POLYCARBONATE 审中-公开
标题翻译：用于加入烷基酯末端以提高熔融聚碳酸酯的释放性能的方法
公开(公告)号：WO2006031668A1
公开(公告)日：2006-03-23
申请号：PCT/US2005/032265
申请日：2005-09-09
申请人： GENERAL ELECTRIC COMPANY , BRACK, Hans-Peter , KARLIK, Dennis , LENS, Jan, Pleun
发明人： BRACK, Hans-Peter , KARLIK, Dennis , LENS, Jan, Pleun
IPC分类号： C08G64/42
CPC分类号： C08G64/42 , C08G2650/04
摘要： Alkyl ester end-capped polycarbonates have improved release properties and may be produced by a method Comprising the step of combining a polycarbonate having free terminal OH groups with an end-capping reagent comprising a symmetrical activated carbonate and an alkyl ester, whereby the end-capping reagent reacts with at least some of the free hydroxyl end groups of the polycarbonate to produce an end-capped polycarbonate comprising optionally substituted aliphatic ester end groups.
摘要翻译：烷基酯封端的聚碳酸酯具有改进的脱模性能，并且可以通过包括将具有游离的末端OH基团的聚碳酸酯与包含对称的活性碳酸酯和烷基酯的封端剂组合的步骤来制备，由此封端试剂与聚碳酸酯的至少一些游离羟基端基反应以制备包含任选取代的脂族酯端基的封端聚碳酸酯。

5. 发明申请

WO2008079447A1 SILYLATED POLYCARBONATE POLYMERS, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：硅烷聚合碳酸酯聚合物，其制备方法和形成的制品
公开(公告)号：WO2008079447A1
公开(公告)日：2008-07-03
申请号：PCT/US2007/074274
申请日：2007-07-25
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , RAJ, Tilak, Thulasi , SHYAMROY, Subarna , SRINIVASARAO, Arakali, Radhakrishna , SUBASH, Scindia, Dattu
发明人： LENS, Jan, Pleun , RAJ, Tilak, Thulasi , SHYAMROY, Subarna , SRINIVASARAO, Arakali, Radhakrishna , SUBASH, Scindia, Dattu
IPC分类号： C08G64/08
CPC分类号： C08G64/085
摘要： A silylated polycarbonate comprises silylated carbonate units, where the silylated carbonate units can be derived from a silylated dihydroxy aromatic compound of the formula (Ia): wherein G a and G b are each independently C 1-12 alkyl, -OSi(C 1 _ 1 2 alkyl) 3 , C 1-12 arylalkyl, or -OSi(C 1 _ 1 2 arylalkyl) 3 ; Z a and Z b are each independently a straight or branched C 2-18 alkylene, a C 8-18 arylalkylene, or a C 8-18 alkylarylene, X a is a direct bond, a heteroatom-containing group, or a C 1-18 organic group, and r and s are each independently 1 or 2. A method of forming the silylated dihydroxy aromatic compound, and for forming the silylated polycarbonate, are disclosed. Also disclosed is a thermoplastic composition comprising the silylated polycarbonate, and an article comprising the thermoplastic composition.
摘要翻译：甲硅烷基化的聚碳酸酯包括甲硅烷基化的碳酸酯单元，其中甲硅烷基化的碳酸酯单元可以衍生自式（Ia）的甲硅烷基化的二羟基芳族化合物：其中G a和H b都是各自独立地为C 1-12烷基，-OSi（C 1〜

6. 发明申请

WO2008051652A1 BRANCHED POLYCARBONATE RESINS AND PROCESSES TO PREPARE THE SAME 审中-公开
标题翻译：分散的聚碳酸酯树脂及其制备方法
公开(公告)号：WO2008051652A1
公开(公告)日：2008-05-02
申请号：PCT/US2007/075888
申请日：2007-08-14
申请人： GENERAL ELECTRIC COMPANY , BRACK, Hans, Peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan, Pleun , LOOIJ, Hans , VERMULEN, Han
发明人： BRACK, Hans, Peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan, Pleun , LOOIJ, Hans , VERMULEN, Han
IPC分类号： C08G64/14
CPC分类号： C08G64/06 , C08G64/307
摘要： A method of increasing the branching and polydispersity of a polycarbonate includes the steps of: (a) including in the polycarbonate at least one species of an alkyl substituted monomer, and (b) treating the polycarbonate at an elevated temperature and for a sufficient time to increase the branching and polydispersity relative to an otherwise equivalent polycarbonate without alkyl substituents.
摘要翻译：增加聚碳酸酯的支化和多分散性的方法包括以下步骤：（a）在聚碳酸酯中包含至少一种烷基取代的单体，和（b）在高温下处理聚碳酸酯足够的时间，相对于没有烷基取代基的其他等效聚碳酸酯，增加支化和多分散性。

7. 发明申请

WO2008008584A2 FLAME RETARDANT AND SCRATCH RESISTANT THERMOPLASTIC POLYCARBONATE COMPOSITIONS 审中-公开
标题翻译：阻燃和耐刮擦热塑性聚碳酸酯组合物
公开(公告)号：WO2008008584A2
公开(公告)日：2008-01-17
申请号：PCT/US2007/070952
申请日：2007-06-12
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , MARUVADA, Sriramakrishna , SHEN, Dake , SINGH, Rajendra, Kashinath
发明人： LENS, Jan, Pleun , MARUVADA, Sriramakrishna , SHEN, Dake , SINGH, Rajendra, Kashinath
IPC分类号： C08K5/42 , C08L69/00 , C09K21/14
CPC分类号： C09K21/06 , C08K5/0066 , C08K5/42 , C08L69/00 , C08L2666/18
摘要： A thermoplastic composition comprising in combination a dialkyl bisphenol polycarbonate homopolymer or copolymer comprising repeat carbonate units having the following structure; wherein R 1 and R 2 are independently at each occurrence a C 1 -C 4 alkyl, n and p are each an integer having a value of 1 to 4, and T is selected from the group consisting of C 5 -C 10 cycloalkanes attached to the aryl groups at one or two carbons, C 1 -C 5 alkyl groups, C 6 -C 13 aryl groups, and C 7 -C 12 aryl alkyl groups; a flame retardant; and an anti-dripping agent is disclosed. The compositions have excellent scratch resistance as well as an improved balance of physical properties such as melt flow, while at the same time maintaining their good flame performance.
摘要翻译：一种热塑性组合物，其组合包含具有以下结构的重复碳酸酯单元的二烷基双酚聚碳酸酯均聚物或共聚物; 其中R 1和R 2各自独立地为C 1 -C 4烷基，n和p 各自是具有1至4的整数，并且T选自在一个或两个连接到芳基上的C 5 -C 10 - 环烷烃碳，C 1 -C 5烷基，C 6 -C 13芳基，C

8. 发明申请

WO2007146487A1 METHOD OF STABILIZATION OF DIHYDRIC PHENOLS 审中-公开
标题翻译：二羟基苯酚的稳定化方法
公开(公告)号：WO2007146487A1
公开(公告)日：2007-12-21
申请号：PCT/US2007/066842
申请日：2007-04-18
申请人： GENERAL ELECTRIC COMPANY , ASHTEKAR, Sunil , KAMPS, Jan, Henk , LENS, Jan, Pleun , NADKARNI, Pradeep , THAMPI, Jegadeesh
发明人： ASHTEKAR, Sunil , KAMPS, Jan, Henk , LENS, Jan, Pleun , NADKARNI, Pradeep , THAMPI, Jegadeesh
IPC分类号： C08G64/06 , C08G64/20 , C08K5/1535 , C08L69/00
CPC分类号： C08G64/20 , C08G64/06 , C08G64/307 , C08K5/1535 , C08L69/00
摘要： A method of producing a polycarbonate, the method comprising: polymerizing a dihydric phenol and a carbonate precursor in the presence of a stabilizer to provide a polycarbonate with a yellowness index of less than or equal to 10 measured in accordance with ASTM E313 test method on molded samples having a thickness of about 2.5 millimeters; wherein the stabilizer is selected from the group consisting of ascorbic acid, salts of ascorbic acid, esters of ascorbic acid and a mixture of two or more of the foregoing; wherein the dihydric phenol is represented by Formula (I), wherein R is a hydrogen atom or an aliphatic functionality having 1 to 6 carbon atoms; and n is an integer having a value of 1 to 4.
摘要翻译：一种制备聚碳酸酯的方法，该方法包括：在稳定剂存在下聚合二元酚和碳酸酯前体，以提供根据ASTM E313测试方法测量的黄色指数小于或等于10的聚碳酸酯样品厚度约2.5毫米; 其中所述稳定剂选自抗坏血酸，抗坏血酸盐，抗坏血酸酯和前述两种或多种的混合物; 其中二元酚由式（I）表示，其中R是氢原子或具有1至6个碳原子的脂族官能团; n为1〜4的整数。

9. 发明申请

WO2005073274A1 PROCESS FOR PRODUCTION OF COPOLYCARBONATES WITH REDUCED COLOR 审中-公开
标题翻译：生产具有降低颜色的共聚碳酸酯的方法
公开(公告)号：WO2005073274A1
公开(公告)日：2005-08-11
申请号：PCT/US2005/002186
申请日：2005-01-20
申请人： GENERAL ELECTRIC COMPANY? , KAMPS, Jan, Henk , LENS, Jan, Pleun
发明人： KAMPS, Jan, Henk , LENS, Jan, Pleun
IPC分类号： C08G64/30
CPC分类号： C08G64/307
摘要： A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps preparing a reaction mixture containing precursors of monomer residues, selecting a catalyst, introduction strategy and adding catalysts according to the strategy. The strategy is sufficient to result in a product copolycarbonate with improved color. The method further includes the steps of introducing the reaction mixture to a series of process units and allowing the reaction mixture to polymerize thereby forming a copolycarbonate. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the steps of selecting a catalyst introduction strategy and introducing catalysts according to the selected strategy.
摘要翻译：提供了一种减少在包括醌型残留物的共聚碳酸酯生产期间产生的颜色的方法。该方法包括制备含有单体残基前体的反应混合物，选择催化剂，引入策略和根据该策略加入催化剂的步骤。该策略足以产生具有改进颜色的产品共聚碳酸酯。该方法还包括将反应混合物引入一系列处理单元并使反应混合物聚合从而形成共聚碳酸酯的步骤。所得共聚碳酸酯与在不进行选择催化剂引入策略和引入催化剂的步骤的步骤中形成的方法相比，具有改进的颜色。

10. 发明申请

WO2005014751A1 LIMITED PLAY DATA STORAGE MEDIA AND OF METHODS OF MANUFACTURE 审中-公开
标题翻译：有限公司数据存储介质及其制造方法
公开(公告)号：WO2005014751A1
公开(公告)日：2005-02-17
申请号：PCT/US2004/020691
申请日：2004-06-25
申请人： GENERAL ELECTRIC COMPANY , WISNUDEL, Marc, Brian , LONGLEY, Kathryn, Lynn , OSLON, Daniel, Robert , LENS, Jan, Pleun , LINDHOLM, Edward, Paul
发明人： WISNUDEL, Marc, Brian , LONGLEY, Kathryn, Lynn , OSLON, Daniel, Robert , LENS, Jan, Pleun , LINDHOLM, Edward, Paul
IPC分类号： C09J11/06
CPC分类号： G11B7/257 , C09J9/00 , C09J11/06 , C09J11/08 , G11B7/2433 , G11B7/246 , G11B7/252 , G11B7/2533 , G11B7/2534 , G11B7/2542 , G11B7/2548 , G11B7/256 , Y10T428/31938
摘要： The present invention provides a reactive adhesive formulation for use in a limited play data storage medium, the reactive adhesive formulation including at least one adhesive material, at least one reactive material disposed within the at least one adhesive material and at least one photo-bleaching retarder material disposed within the at least one adhesive material. The at least one photo-bleaching retarder material includes resorcinol, 4-hexylresorcinol and/or polyhydroxystyrene.
摘要翻译：本发明提供了一种用于有限播放数据存储介质的反应性粘合剂制剂，所述反应性粘合剂制剂包括至少一种粘合剂材料，至少一种反应性材料，其设置在所述至少一种粘合剂材料内，以及至少一种光漂白缓凝剂设置在所述至少一种粘合剂材料内的材料。所述至少一种光漂白缓凝剂材料包括间苯二酚，4-己基间苯二酚和/或多羟基苯乙烯。

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