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1. 发明申请

WO2008008599A2 GLOSSY COLORED INJECTION MOLDED ARTICLE 审中-公开
标题翻译： GLOSSY彩色注塑成型品
公开(公告)号：WO2008008599A2
公开(公告)日：2008-01-17
申请号：PCT/US2007/071557
申请日：2007-06-19
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan- Pleun , TAKEMORI, Michael, Teruki , VAN DE GRAMPEL, Hendrik, Theodorus
发明人： KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan- Pleun , TAKEMORI, Michael, Teruki , VAN DE GRAMPEL, Hendrik, Theodorus
CPC分类号： C08G63/64 , C08G64/06 , C08K5/523 , C08L25/12 , C08L27/18 , C08L55/02 , C08L69/00 , C08L83/10 , C08L2666/02
摘要： An injection molded article comprising a polycarbonate composition. The polycarbonate composition is scratch resistant, flame retardant, has a low chlorine and bromine content and is dark colored.
摘要翻译：一种包含聚碳酸酯组合物的注塑制品。聚碳酸酯组合物具有耐划伤性，阻燃性，氯和溴含量低，呈深色。

2. 发明申请

WO2008136841A1 POLY(CARBONATE-CO-UREA) COPOLYMERS AND MELT TRANSESTERIFICATION METHOD OF PREPARING THESE COPOLYMERS 审中-公开
标题翻译：聚（碳酸酯 - 共聚物）共聚物和制备这些共聚物的熔融纺丝方法
公开(公告)号：WO2008136841A1
公开(公告)日：2008-11-13
申请号：PCT/US2007/073978
申请日：2007-07-20
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan-pleun
发明人： KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan-pleun
IPC分类号： C08G64/02 , C08G64/12 , C08G64/16 , C08G64/18 , C08G64/20 , C08G71/02 , C08L101/02
CPC分类号： C08G64/12 , C08G63/64 , C08G71/02
摘要： Disclosed herein is a process to prepare a poly(carbonate-co-urea) copolymer comprising reacting in the melt: (a) a dihydroxy reaction component comprising a dihydroxy compound, (b) a diaryl carbonate reaction component comprising a diaryl carbonate, (c) a urea reaction component comprising a urea compound in the presence of (d) a transesterification catalyst during at least part of the reaction and removing a phenolic byproduct to produce a poly(carbonate-co-urea) copolymer, wherein the urea and dihydroxy compounds are reacted in a molar ratio: (total moles of urea compound)/((total moles of urea compound) + (total moles of dihydroxy compound)) of less than or equal to 0.5.
摘要翻译：本文公开了一种制备聚（碳酸酯 - 共 - 尿素）共聚物的方法，其包括在熔体中反应：（a）包含二羟基化合物的二羟基反应组分，（b）包含碳酸二芳基酯的碳酸二芳酯反应组分，（c ）在至少部分反应期间（d）酯交换催化剂存在下包含脲化合物的脲反应组分，并除去酚类副产物以产生聚（碳酸酯 - 共 - 尿素）共聚物，其中脲和二羟基化合物以摩尔比（尿素化合物的总摩尔数）/（（脲化合物的总摩尔数）+（二羟基化合物的总摩尔数））小于或等于0.5。

3. 发明申请

WO2008051652A1 BRANCHED POLYCARBONATE RESINS AND PROCESSES TO PREPARE THE SAME 审中-公开
标题翻译：分散的聚碳酸酯树脂及其制备方法
公开(公告)号：WO2008051652A1
公开(公告)日：2008-05-02
申请号：PCT/US2007/075888
申请日：2007-08-14
申请人： GENERAL ELECTRIC COMPANY , BRACK, Hans, Peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan, Pleun , LOOIJ, Hans , VERMULEN, Han
发明人： BRACK, Hans, Peter , JANSEN, Bernd , KAMPS, Jan, Henk , KUNG, Edward , LENS, Jan, Pleun , LOOIJ, Hans , VERMULEN, Han
IPC分类号： C08G64/14
CPC分类号： C08G64/06 , C08G64/307
摘要： A method of increasing the branching and polydispersity of a polycarbonate includes the steps of: (a) including in the polycarbonate at least one species of an alkyl substituted monomer, and (b) treating the polycarbonate at an elevated temperature and for a sufficient time to increase the branching and polydispersity relative to an otherwise equivalent polycarbonate without alkyl substituents.
摘要翻译：增加聚碳酸酯的支化和多分散性的方法包括以下步骤：（a）在聚碳酸酯中包含至少一种烷基取代的单体，和（b）在高温下处理聚碳酸酯足够的时间，相对于没有烷基取代基的其他等效聚碳酸酯，增加支化和多分散性。

4. 发明申请

WO2007053357A2 POLYMERS, POLYMER COMPOSITIONS AND METHOD OF PREPARATION 审中-公开
标题翻译：聚合物，聚合物组合物和制备方法
公开(公告)号：WO2007053357A2
公开(公告)日：2007-05-10
申请号：PCT/US2006/041351
申请日：2006-10-23
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , LENS, Jan-pleun , MAHOOD, James, A. , RADHAKRISHNA, A. S. , RAJ, Tilak, T. , SINGH, Ravindra, Vikram
发明人： KAMPS, Jan, Henk , LENS, Jan-pleun , MAHOOD, James, A. , RADHAKRISHNA, A. S. , RAJ, Tilak, T. , SINGH, Ravindra, Vikram
CPC分类号： C07C69/757 , C07C45/69 , C07C45/74 , C07C67/343 , C07C67/347 , C07C2601/14 , C08G64/14 , C07C49/223
摘要： A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, "n" is an integer having a value 0 to 4 and "m" is an integer having a value 0 to 4. Also described herein are polymers made using the dihydroxy compounds of Formula (I), methods of making these polymers and compositions comprising these polymers.
摘要翻译：具有式（I）的二羟基芳族化合物其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2个碳原子的脂族酯官能团至10个碳，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; 并且每个R 3和R 4在每次出现时可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂肪族官能团或具有3至10个碳的脂环族官能团，“n” 是值为0至4的整数，“m” 是具有值0至4的整数。本文还描述了使用式（I）的二羟基化合物制备的聚合物，制备这些聚合物的方法和包含这些聚合物的组合物。

5. 发明申请

WO2004041907A1 METHOD FOR MAKING COPOLYCARBONATES 审中-公开
标题翻译：制备共聚碳酸酯的方法
公开(公告)号：WO2004041907A1
公开(公告)日：2004-05-21
申请号：PCT/US2003/033716
申请日：2003-10-24
申请人： GENERAL ELECTRIC COMPANY , LENS, Jan, Pleun , KAMPS, Jan, Henk
发明人： LENS, Jan, Pleun , KAMPS, Jan, Henk
IPC分类号： C08G64/30
CPC分类号： C08G64/307 , C08G64/06
摘要： A melt polymerization method is presented which permits the efficient preparation of copolycarbonates in which one or more of the constituent dehydroxy aromatic compounds employed is relatively volatile, having a boiling point of less than about 340 °C. Relatively volatile dihydroxy aromatic compounds are illustrated by dihydroxybenzenes such as hydroquinone, methyl hydroquinone and resorcinol. Known methods for the preparation of members of this class of copolycarbonates, such as the melt reaction of bisphenol A and resorcinol diphenyl carbonate in the presence of sodium hydroxide and tetraalkylammonium salt catalyst systems, suffer losses in efficiency due to the resorcinol being entrained out of the polymerization mixture with by-product phenol. Catalyst systems including quaternary phosphonium salts are shown to have improved performance with respect to the amount of volatile dihydroxy aromatic compound actually incorporated into the product copolycarbonate.
摘要翻译：提出了熔融聚合方法，其可以有效地制备其中一种或多种所用的组分脱羟基芳族化合物相对挥发的共聚碳酸酯，其沸点低于约340℃。相对挥发性的二羟基芳族化合物由二羟基苯如氢醌，甲基氢醌和间苯二酚表示。用于制备这种类型的共聚碳酸酯的成员的已知方法，例如双酚A和间苯二酚碳酸二苯酯在氢氧化钠和四烷基铵盐催化剂体系的存在下的熔融反应，由于间苯二酚被夹带在聚合混合物与副产物苯酚。显示出包含季鏻盐的催化剂体系相对于实际掺入到产物共聚碳酸酯中的挥发性二羟基芳族化合物的量具有改进的性能。

6. 发明申请

WO2007146487A1 METHOD OF STABILIZATION OF DIHYDRIC PHENOLS 审中-公开
标题翻译：二羟基苯酚的稳定化方法
公开(公告)号：WO2007146487A1
公开(公告)日：2007-12-21
申请号：PCT/US2007/066842
申请日：2007-04-18
申请人： GENERAL ELECTRIC COMPANY , ASHTEKAR, Sunil , KAMPS, Jan, Henk , LENS, Jan, Pleun , NADKARNI, Pradeep , THAMPI, Jegadeesh
发明人： ASHTEKAR, Sunil , KAMPS, Jan, Henk , LENS, Jan, Pleun , NADKARNI, Pradeep , THAMPI, Jegadeesh
IPC分类号： C08G64/06 , C08G64/20 , C08K5/1535 , C08L69/00
CPC分类号： C08G64/20 , C08G64/06 , C08G64/307 , C08K5/1535 , C08L69/00
摘要： A method of producing a polycarbonate, the method comprising: polymerizing a dihydric phenol and a carbonate precursor in the presence of a stabilizer to provide a polycarbonate with a yellowness index of less than or equal to 10 measured in accordance with ASTM E313 test method on molded samples having a thickness of about 2.5 millimeters; wherein the stabilizer is selected from the group consisting of ascorbic acid, salts of ascorbic acid, esters of ascorbic acid and a mixture of two or more of the foregoing; wherein the dihydric phenol is represented by Formula (I), wherein R is a hydrogen atom or an aliphatic functionality having 1 to 6 carbon atoms; and n is an integer having a value of 1 to 4.
摘要翻译：一种制备聚碳酸酯的方法，该方法包括：在稳定剂存在下聚合二元酚和碳酸酯前体，以提供根据ASTM E313测试方法测量的黄色指数小于或等于10的聚碳酸酯样品厚度约2.5毫米; 其中所述稳定剂选自抗坏血酸，抗坏血酸盐，抗坏血酸酯和前述两种或多种的混合物; 其中二元酚由式（I）表示，其中R是氢原子或具有1至6个碳原子的脂族官能团; n为1〜4的整数。

7. 发明申请

WO2005073274A1 PROCESS FOR PRODUCTION OF COPOLYCARBONATES WITH REDUCED COLOR 审中-公开
标题翻译：生产具有降低颜色的共聚碳酸酯的方法
公开(公告)号：WO2005073274A1
公开(公告)日：2005-08-11
申请号：PCT/US2005/002186
申请日：2005-01-20
申请人： GENERAL ELECTRIC COMPANY? , KAMPS, Jan, Henk , LENS, Jan, Pleun
发明人： KAMPS, Jan, Henk , LENS, Jan, Pleun
IPC分类号： C08G64/30
CPC分类号： C08G64/307
摘要： A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps preparing a reaction mixture containing precursors of monomer residues, selecting a catalyst, introduction strategy and adding catalysts according to the strategy. The strategy is sufficient to result in a product copolycarbonate with improved color. The method further includes the steps of introducing the reaction mixture to a series of process units and allowing the reaction mixture to polymerize thereby forming a copolycarbonate. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the steps of selecting a catalyst introduction strategy and introducing catalysts according to the selected strategy.
摘要翻译：提供了一种减少在包括醌型残留物的共聚碳酸酯生产期间产生的颜色的方法。该方法包括制备含有单体残基前体的反应混合物，选择催化剂，引入策略和根据该策略加入催化剂的步骤。该策略足以产生具有改进颜色的产品共聚碳酸酯。该方法还包括将反应混合物引入一系列处理单元并使反应混合物聚合从而形成共聚碳酸酯的步骤。所得共聚碳酸酯与在不进行选择催化剂引入策略和引入催化剂的步骤的步骤中形成的方法相比，具有改进的颜色。

8. 发明申请

WO2005073273A1 PROCESS FOR THE PRODUCTION OF COPOLYCARBONATES WITH REDUCED COLOR 审中-公开
标题翻译：生产具有降低颜色的共聚碳酸酯的方法
公开(公告)号：WO2005073273A1
公开(公告)日：2005-08-11
申请号：PCT/US2005/001628
申请日：2005-01-20
申请人： GENERAL ELECTRIC COMPANY , KAMPS, Jan, Henk , LENS, Jan, Pleun
发明人： KAMPS, Jan, Henk , LENS, Jan, Pleun
IPC分类号： C08G64/30
CPC分类号： C08G64/307
摘要： A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps of mixing the precursors of monomer residues, a carbonate source and a polymerization catalyst into a reaction mixture. The method further includes the steps of introducing an antioxidant such as a hydroxycarboxylic acid to the reaction mixture in an amount sufficient to reduce color formation and introducing the reaction mixture to a series of process units wherein the reaction mixture polymerizes. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the step of introducing an antioxidant to the melt polymerization process.
摘要翻译：提供了一种减少在包括醌型残留物的共聚碳酸酯生产期间产生的颜色的方法。该方法包括将单体残基前体，碳酸酯源和聚合催化剂混合到反应混合物中的步骤。该方法还包括以下步骤：将足够减少颜色形成的量的羟基羧酸的抗氧化剂引入反应混合物中，并将反应混合物引入反应混合物聚合的一系列处理单元。所得共聚碳酸酯与在不进行熔融聚合反应的抗氧化剂步骤的方法中形成的共聚碳酸酯相比具有改善的颜色。

9. 发明申请

WO2004060962A1 METHOD OF POLYCARBONATE PREPARATION 审中-公开
标题翻译：聚碳酸酯制备方法
公开(公告)号：WO2004060962A1
公开(公告)日：2004-07-22
申请号：PCT/US2003/039139
申请日：2003-12-10
申请人： GENERAL ELECTRIC COMPANY , MCCLOSKEY, Patrick, Joseph , LENS, Jan, Pleun , CELLA, James, Anthony , KAMPS, Jan, Henk , LONGLEY, Kathryn, Lynn , RAMESH, Narayan , REILLY, Warren, William , SMIGELSKI, Paul, Michael, Jr. , WISNUDEL, Marc, Brian
发明人： MCCLOSKEY, Patrick, Joseph , LENS, Jan, Pleun , CELLA, James, Anthony , KAMPS, Jan, Henk , LONGLEY, Kathryn, Lynn , RAMESH, Narayan , REILLY, Warren, William , SMIGELSKI, Paul, Michael, Jr. , WISNUDEL, Marc, Brian
IPC分类号： C08G64/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4’-biphenol have been prepared by the melt reacti on of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
摘要翻译：含有低或不可检测水平的弗里斯重排产物并且包含衍生自间苯二酚，氢醌，甲基氢醌，双酚A和4,4'-联苯酚中的一种或多种的重复单元的聚碳酸酯已经通过熔融反应在一种或多种上述具有酯取代的二芳基碳酸酯的二羟基芳族化合物，例如碳酸双甲基水杨酸酯。低产量或在许多情况下，不可检测的是，在由高效催化剂体系获得的产品聚碳酸酯中发现了油炸产品重排产物的水平，该催化剂体系抑制了Fries反应，并且相对于类似物所需的温度使用较低的熔体聚合温度使用碳酸二苯酯进行聚合反应。

10. 发明申请

WO2008070214A1 LIGHT TRANSMISSIVE ARTICLES AND METHODS THEREOF 审中-公开
标题翻译：光传输文章及其方法
公开(公告)号：WO2008070214A1
公开(公告)日：2008-06-12
申请号：PCT/US2007/073423
申请日：2007-07-13
申请人： GENERAL ELECTRIC COMPANY , BODEN, Eugene, Pauling , LAWRENCE, Brian, Lee , MONTGOMERY, Steven, James , CHAKRAVARTI, Shreyas , VOLLENBERG, Peter, Hendrikus , KUNG, Edward , KAMPS, Jan, Henk , PRADA, Lina , MCDERMOTT, John, Brian , TAKEMORI, Michael, Teruki
发明人： BODEN, Eugene, Pauling , LAWRENCE, Brian, Lee , MONTGOMERY, Steven, James , CHAKRAVARTI, Shreyas , VOLLENBERG, Peter, Hendrikus , KUNG, Edward , KAMPS, Jan, Henk , PRADA, Lina , MCDERMOTT, John, Brian , TAKEMORI, Michael, Teruki
IPC分类号： G02B5/22
CPC分类号： G02B5/223 , G02B5/208
摘要： The present invention provides methods for controlling the optical properties of a light transmissive article. The method includes identifying a target window in an Abbe diagram comprising reference polymeric materials. The method further includes selecting a first polymeric material from the reference polymeric materials and compounding the first polymeric material with a stable UV chromophore to provide a first polymer composition. The method further includes transforming the first polymer composition to provide the light transmissive article, wherein the light transmissive article has an Abbe number and a refractive index which falls within the target window. Light transmissive articles prepared using the above methods are also provided.
摘要翻译：本发明提供了控制透光性物品的光学特性的方法。该方法包括在包含参考聚合材料的阿贝图中识别目标窗口。该方法还包括从参考聚合物材料中选择第一聚合物材料并将第一聚合物材料与稳定的紫外发色团混合以提供第一聚合物组合物。该方法还包括转化第一聚合物组合物以提供透光制品，其中透光制品具有落在目标窗口内的阿贝数和折射率。还提供了使用上述方法制备的透光性物品。

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