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    • 2. 发明申请
    • TOLUENE DISPROPORTIONATION CATALYST
    • TOLUENE分解催化剂
    • WO2008157539A3
    • 2009-02-12
    • PCT/US2008067206
    • 2008-06-17
    • FINA TECHNOLOGYBUTLER JAMESXIAO XINHALL ROSA
    • BUTLER JAMESXIAO XINHALL ROSA
    • C07C5/00
    • B01J37/20B01J29/24B01J35/002B01J37/0009B01J37/08B01J2229/20B01J2229/40B01J2229/42C07C6/123C07C2529/18Y02P20/52C07C15/04C07C15/08
    • A process for the disproportionation of a toluene containing feedstock employing a nickel modified mordcnite catalyst comprising particulate mordenite having nickel dispersed throughout the catalyst particles to provide surface nickel and interior nickel within the mordenite crystal structure. The catalyst is pretreated Io selectively deactivate the surface nickel to provide a surface nickel content of reduced catalytic activity. The interior nickel lhus has a higher catalytic activity than the surface nickel. The feedstock is supplied to a reaction zone containing the catalyst to cause disproportionation of toluene in the feedstock to produce a mixture of benzene and xylene. The non-aromatic content of the product is less than the non-aromatic content of a corresponding disproportionation product which would be produced by the disproportionation of the fecdstream in the presence of a corresponding nickel mordenite catalyst which has not been pretreated.
    • 含有甲苯的原料的歧化的方法,该方法使用镍改性的莫氏体催化剂,其包含分散在整个催化剂颗粒中的镍的颗粒丝光沸石,以在丝光沸石晶体结构内提供表面镍和内部镍。 预催化剂催化剂选择性地使表面镍失活以提供具有降低的催化活性的表面镍含量。 内部镍镉具有比表面镍更高的催化活性。 将原料供给到含有催化剂的反应区,以使原料中的甲苯发生歧化,产生苯和二甲苯的混合物。 产物的非芳香族含量小于相应的歧化产物的非芳香族含量,其将通过在未进行预处理的相应的镍丝光沸石催化剂的存在下通过歧管进行产生。
    • 3. 发明申请
    • TOLUENE DISPROPORTIONATION PROCESS UTILIZING MILD SULFIDING DURING STARTUP
    • 在启动过程中利用牛奶硫化的TOLUENE分解过程
    • WO2006074254A2
    • 2006-07-13
    • PCT/US2006000232
    • 2006-01-05
    • FINA TECHNOLOGYXIAO XINFUSSELL BECKYBUTLER JAMESGOMEZ BRANDI
    • XIAO XINFUSSELL BECKYBUTLER JAMESGOMEZ BRANDI
    • C07C5/22
    • B01J29/24B01J37/20C07C6/123C07C6/126C07C2529/18C07C2529/22Y02P20/52C07C15/08
    • A process for the disproportionation of toluene over a nickel-modified mordenite catalyst which has been pretreated with mild sulfiding procedure. The sulfur dose is employed in a minor amount relative to the nickel content of the catalyst. The modified mordenite catalyst is contacted with a sulfur-containing compound such as hydrogen sulfide or dimethyldisulfide (DMDS) under pretreatment conditions involving a temperature of at least 100°C. The sulfur-containing compound is employed in a relatively small amount to passivate only a minor portion of the active nickel sites. A toluene-containing feedstock is brought into contact with the pretreated catalyst under conditions effective for the disproportionation of toluene and a disproportionation product is removed from contact with the catalyst. The mordenite catalyst contains nickel in an amount within the range of 0.1-2 wt.%. The catalyst may contain another metal such as palladium or platinum, or a lanthanide series metal such as lanthanum or cerium. Pretreatment of the catalyst may be carried out by flowing a fluid pretreatment stream having a sulfur component into contact with the catalyst. The pretreatment stream comprises hydrogen sulfide or a thio compound which is converted to hydrogen sulfide under the pretreatment conditions.
    • 一种已经用轻度硫化方法预处理的镍改性丝光沸石催化剂歧化甲苯的方法。 硫剂量相对于催化剂的镍含量少量使用。 在涉及至少100℃的温度的预处理条件下,将修饰的丝光沸石催化剂与含硫化合物如硫化氢或二甲基二硫化物(DMDS)接触。 含硫化合物的使用量相对较少,仅钝化少部分活性镍部位。 使含甲苯的原料在有效用于歧化甲苯的条件下与预处理的催化剂接触,并且歧化产物被除去与催化剂的接触。 丝光沸石催化剂含有0.1-2重量%范围内的量的镍。 催化剂可以含有另一种金属如钯或铂,或镧系金属如镧或铈。 催化剂的预处理可以通过使具有硫成分的流体预处理流与催化剂接触来进行。 预处理流包含硫化氢或在预处理条件下转化为硫化氢的硫代化合物。
    • 4. 发明申请
    • USE OF AN OXIDANT IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE
    • 氧化剂在碳氢化合物与碳源的耦合中的使用
    • WO2013162629A3
    • 2014-05-08
    • PCT/US2012037725
    • 2012-05-14
    • FINA TECHNOLOGYBUTLER JAMESCHINTA SIVADINARAYANA
    • BUTLER JAMESCHINTA SIVADINARAYANA
    • C07C15/40
    • C07C2/862C07C2529/70C07C15/073C07C15/46
    • A process for making styrene including reacting toluene with a C1 source in the presence of a catalyst and a co-feed including at least one oxidizing agent in a reactor to form a product stream including ethylbenzene and styrene and, optionally, at least one de-oxidized oxidizing agent. The C1 source toluene is reacted with one or more of methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, and methylal. The co-feed includes an oxidizing agent selected from the group of oxygen, air, nitrobenzene, quinones, anthracene, nitrous oxide, and combinations thereof. The co-feed may be combined with nitrogen prior to combining the co- feed with the reactants. The co-feed may be combined with the reactants in any desired amounts. In an embodiment, the process of the present invention contains a reactant:co-feed molar ratio of at least 1:1.
    • 一种制备苯乙烯的方法,包括在催化剂存在下使甲苯与C1源反应,并且在反应器中包含至少一种氧化剂的共进料,以形成包含乙苯和苯乙烯的产物流, 氧化氧化剂。 C1源甲苯与一种或多种甲醇,甲醛,福尔马林,三恶烷,甲基甲缩醛,多聚甲醛和甲缩醛反应。 共进料包括选自氧,空气,硝基苯,醌,蒽,一氧化二氮及其组合的氧化剂。 在将共进料与反应物组合之前,共进料可以与氮组合。 共进料可以以任何所需量与反应物组合。 在一个实施方案中,本发明的方法含有至少1:1的反应物:共 - 进料摩尔比。