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1. 发明申请

WO2008018952A1 POLYMER COMPOSITIONS COMPRISING CYCLIC OLEFIN COPOLYMERS AND POLYOLEFIN MODIFIERS 审中-公开
标题翻译：包含环烯烃共聚物和聚烯烃改性剂的聚合物组合物
公开(公告)号：WO2008018952A1
公开(公告)日：2008-02-14
申请号：PCT/US2007/014381
申请日：2007-06-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SQUIRE, Kevin, R. , OSHINSKI, Alan, J. , ROBINSON, Kevin, D. , MEHNERT, Christian, Peter , ARVEDSON, Marsha, M. , POOLE, Beverly, J. , PATIL, Abhimanyu, Onkar , BAUGH, Lisa, Saunders , COLLE, Karla, Schall
发明人： SQUIRE, Kevin, R. , OSHINSKI, Alan, J. , ROBINSON, Kevin, D. , MEHNERT, Christian, Peter , ARVEDSON, Marsha, M. , POOLE, Beverly, J. , PATIL, Abhimanyu, Onkar , BAUGH, Lisa, Saunders , COLLE, Karla, Schall
IPC分类号： C08L23/02 , C08L45/00 , C08L23/08 , C08L23/16 , C08L53/00
CPC分类号： C08L23/0823 , C08L23/16 , C08L53/00 , C08L2314/06 , C08L2666/24 , C08L2666/06
摘要： A polymer composition comprises (a) greater than 50 wt% (based upon the weight of the composition) of a cyclic olefin copolymer comprising at least one acyclic olefin and at least 20 weight % of one or more cyclic olefins (based upon the weight of the cyclic olefin copolymer), wherein at least a portion of the cyclic olefin copolymer has a glass transition temperature of greater than 150°C; and (b) less than 50 wt% (based upon the weight of the composition) of an acyclic olefin polymer modifier, at least a portion of the modifier having a glass transition temperature of less than -30°C; and no portion of the modifier having a softening point greater than +30°C, wherein the Bicerano solubility parameter of the modifier being no more than 0.6 J 0.5 /cm 1.5 less than the Bicerano solubility parameter of the cyclic olefin copolymer. The polymer composition has a notched Izod impact resistance measured at 23°C of greater than 500 J/m and a heat distortion temperature measured using a 0.46 MPa load of greater than 135°C.
摘要翻译：聚合物组合物包含（a）大于50重量％（基于组合物的重量）的包含至少一种非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃共聚物（基于环烯烃共聚物），其中至少一部分环烯烃共聚物的玻璃化转变温度大于150℃; 和（b）小于50重量％（基于组合物的重量）无环烯烃聚合物改性剂，至少一部分改性剂的玻璃化转变温度低于-30℃; 并且所述改性剂的任何部分的软化点大于+ 30℃，其中所述改性剂的比卡拉诺溶解度参数不大于0.6J≤0.5/ cm×1.5以下比环烯烃共聚物的Bicerano溶解度参数。聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于500J / m，并且使用大于135℃的0.46MPa载荷测量的热变形温度。

2. 发明申请

WO2008018951A1 POLYMER COMPOSITIONS COMPRISING CYCLIC OLEFIN POLYMERS, POLYOLEFIN MODIFIERS, AND FILLERS 审中-公开
标题翻译：包含环烯烃聚合物，聚烯烃改性剂和填料的聚合物组合物
公开(公告)号：WO2008018951A1
公开(公告)日：2008-02-14
申请号：PCT/US2007/014368
申请日：2007-06-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SQUIRE, Kevin, R. , OSHINSKI, Alan, J. , ROBINSON, Kevin, D. , MEHNERT, Christian, Peter , ARVEDSON, Marsha, M. , POOLE, Beverly, J. , PATIL, Abhimanyu, Onkar , BAUGH, Lisa, Saunders , COLLE, Karla, Schall
发明人： SQUIRE, Kevin, R. , OSHINSKI, Alan, J. , ROBINSON, Kevin, D. , MEHNERT, Christian, Peter , ARVEDSON, Marsha, M. , POOLE, Beverly, J. , PATIL, Abhimanyu, Onkar , BAUGH, Lisa, Saunders , COLLE, Karla, Schall
IPC分类号： C08L23/02 , C08L45/00 , C08L23/08 , C08L23/16 , C08L51/06 , C08L53/02 , C08K3/34
CPC分类号： C08L23/0823 , C08K3/34 , C08L23/16 , C08L51/06 , C08L53/02 , C08L2666/06 , C08L2666/02 , C08L2666/24
摘要： A polymer composition comprises (a) least 40 wt% (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100°C; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt% (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23°C of greater than 100 J/m and a flexural modulus (1 % secant method) of greater than 1400 MPa.
摘要翻译：聚合物组合物包含（a）至少40重量％（基于组合物的重量）包含至少一个非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃聚合物（基于环烯烃聚合物），其中至少一部分环烯烃聚合物的玻璃化转变温度大于100℃; （b）至多40重量％（基于组合物的重量）的非环烯烃聚合物改性剂; 和（c）至少10重量％（基于组合物的重量）为更多填料之一。聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于100J / m，挠曲模量（1％割线法）大于1400MPa。

3. 发明申请

WO2008008112A1 ETHYLENE/DICYCLOPENTADIENE COPOLYMERS AND FUNCTIONALIZED DERIVATIVES THEREOF 审中-公开
标题翻译：乙烯/二烯丙基共聚物及其官能化衍生物
公开(公告)号：WO2008008112A1
公开(公告)日：2008-01-17
申请号：PCT/US2007/011284
申请日：2007-05-10
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BAUGH, Lisa, Saunders , PATIL, Abhimanyu, Onkar , MEHNERT, Christian, Peter , SQUIRE, Kevin, R. , COOK, Kenneth, A. , GONG, Caiguo , BERLUCHE, Enock , COLLE, Karla, Schall , OSHINSKI, Alan, J. , ZUSHMA, Stephen , POOLE, Beverly, J.
发明人： BAUGH, Lisa, Saunders , PATIL, Abhimanyu, Onkar , MEHNERT, Christian, Peter , SQUIRE, Kevin, R. , COOK, Kenneth, A. , GONG, Caiguo , BERLUCHE, Enock , COLLE, Karla, Schall , OSHINSKI, Alan, J. , ZUSHMA, Stephen , POOLE, Beverly, J.
IPC分类号： C08F210/02 , C08F8/04 , C08F8/08
CPC分类号： C08F210/02 , C08F8/04 , C08F8/08 , C08F232/00
摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, M w , of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, T g , of from about 8 °C to about 129°C, which also fit the equation T g (in °C) ≥ [(mole % DCPD x 3.142) - 4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics. Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl- fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3- position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.
摘要翻译：公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包括非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合等式T（g） C）= [（摩尔％DCPD×3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂的存在下，在环戊二烯基环的3-位具有取代基，优选甲基取代基的存在下，使乙烯与包含大于约4.0摩尔二环戊二烯的聚合混合物接触在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。然后回收和/或进一步氢化或官能化此类共聚物。

4. 发明申请

WO2008112106A1 ETHYLENE/DICYCLOPENTADIENE/NORBORNENE TERPOLYMER MATERIALS HAVING DESIRABLE STRUCTURAL AND THERMAL PROPERTIES 审中-公开
标题翻译：乙烯/二环戊二烯/异戊二烯合成材料具有可靠的结构和热性能
公开(公告)号：WO2008112106A1
公开(公告)日：2008-09-18
申请号：PCT/US2008/002898
申请日：2008-03-05
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , BAUGH, Lisa, S. , BERLUCHE, Enock , PATIL, Abhimanyu, O. , POOLE, Beverly, J. , ROBINSON, Kevin, D. , SQUIRE, Kevin, R.
发明人： BAUGH, Lisa, S. , BERLUCHE, Enock , PATIL, Abhimanyu, O. , POOLE, Beverly, J. , ROBINSON, Kevin, D. , SQUIRE, Kevin, R.
IPC分类号： C08F2/00
CPC分类号： C08F210/02 , C08F232/00 , C08F236/20 , C08F2500/25 , C08F2500/17 , C08F2500/03
摘要： Provided are selected types of terpolymer components having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbomene-based (NB) co-monomers Such terpolymer components have specified amounts of each co-monomer as well as specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation, epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties. Also provided are processes for preparing and derivatizing the terpolymer components herein Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbomene terpolymer components within the polymenzation mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.
摘要翻译：提供了选自具有源自乙烯（E），二环戊二烯（DCPD）和降冰片基（NB）共聚单体）的单体单元的三元共聚物组分。这些三元共聚物组分具有规定量的每种共聚单体以及特定的分子量和玻璃转变温度特性。还公开了通过氢化，环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别理想的结构和热性质的热塑性聚烯烃组合物。还提供了用于制备和衍生化三元共聚物组分的方法。这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂的存在下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而在聚酰胺混合物内形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分。然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。

5. 发明申请

WO2006062572A1 MODIFIED LAYERED FILLERS AND THEIR USE TO PRODUCE NANOCOMPOSITE COMPOSITIONS 审中-公开
标题翻译：改性层状填料及其用于生产纳米复合材料的用途
公开(公告)号：WO2006062572A1
公开(公告)日：2006-06-15
申请号：PCT/US2005/036013
申请日：2005-10-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , GONG, Caiguo , WENG, Weiqing , TSE, Mun-Fu , DIAS, Anthony, J. , STOKES, James, P. , GALUSKA, Alan, A. , POOLE, Beverly, J. , NEAGU, Carmen , KARP, Kriss , JOHNSTON, Molly, W.
发明人： GONG, Caiguo , WENG, Weiqing , TSE, Mun-Fu , DIAS, Anthony, J. , STOKES, James, P. , GALUSKA, Alan, A. , POOLE, Beverly, J. , NEAGU, Carmen , KARP, Kriss , JOHNSTON, Molly, W.
IPC分类号： C09C1/42 , C08K3/34 , C08K9/04
CPC分类号： C09C1/42 , C01P2002/72 , C08L23/22
摘要： The present invention relates to modified layered fillers made from layered fillers and modifying agents and processes to produce the same. The invention also relates to nanocomposite compositions made from these modified layered fillers and elastomers, and processes to produce the same, and their use in articles.
摘要翻译：本发明涉及由分层填料和改性剂制成的改性层状填料及其制备方法。本发明还涉及由这些改性层状填料和弹性体制备的纳米复合材料组合物及其制备方法及其在制品中的用途。

6. 发明申请

WO2006085957A2 POLYMERIC NANOCOMPOSITES AND PROCESSES FOR MAKING THE SAME 审中-公开
标题翻译：聚合物纳米复合材料及其制备方法
公开(公告)号：WO2006085957A2
公开(公告)日：2006-08-17
申请号：PCT/US2005/022714
申请日：2005-06-28
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , WENG, Weiqing , DIAS, Anthony, J. , GONG, Caiguo , POOLE, Beverly, J. , NEAGU, Carmen , KARP, Kriss, R. , JOHNSTON, Molly, W. , AYERS, James, R.
发明人： WENG, Weiqing , DIAS, Anthony, J. , GONG, Caiguo , POOLE, Beverly, J. , NEAGU, Carmen , KARP, Kriss, R. , JOHNSTON, Molly, W. , AYERS, James, R.
CPC分类号： C08K3/346 , B82Y30/00 , C08K2201/011 , C08L21/00 , C08L23/16
摘要： The present invention relates to processes to produce nanocomposites. In particular, the invention relates to solution processes using organic solvents and mixtures of solvents to produce polymeric nanocomposites.
摘要翻译：本发明涉及制备纳米复合材料的方法。特别地，本发明涉及使用有机溶剂和溶剂混合物来生产聚合物纳米复合材料的溶液方法。

7. 发明申请

WO2004005388A1 FUNCTIONALIZED ELASTOMER NANOCOMPOSITE 审中-公开
标题翻译：功能性弹性体纳米复合材料
公开(公告)号：WO2004005388A1
公开(公告)日：2004-01-15
申请号：PCT/US2003/017204
申请日：2003-05-30
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
发明人： GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
IPC分类号： C08K3/34
CPC分类号： B82Y30/00 , C08F8/00 , C08K3/346 , C08K9/04 , C08K2201/011 , C08F10/00 , C08L15/00 , C08L19/006 , C08L19/00
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C 2 to C 10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized by reacting free radical generating agents and unsaturated carboxylic acids, unsaturated esters, unsaturated imides, and the like, with the elastomer. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译：本发明的一个实施方案是纳米复合材料，其包含粘土和包含至少C2-C10烯烃衍生单元的弹性体; 其中弹性体还包括垂直于弹性体的官能化单体单元。弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过使自由基产生剂和不饱和羧酸，不饱和酯，不饱和酰亚胺和像弹性体一样。粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。本发明的纳米复合材料具有改进的空气阻隔性能，例如可用于轮胎内衬和内管。

8. 发明申请

WO2008045012A2 FUNCTIONALIZED ISOBUTYLENE POLYMER-INORGANIC CLAY NANOCOMPOSITES AND ORGANIC-AQUEOUS EMULSION PROCESS 审中-公开
标题翻译：功能化异丁烯聚合物 - 无机粘土纳米复合材料和有机 - 水乳液法
公开(公告)号：WO2008045012A2
公开(公告)日：2008-04-17
申请号：PCT/US2006/020572
申请日：2006-05-26
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , WENG, Weiqing , GONG, Caiguo , DIAS, Anthony, J. , AYERS, James, R. , NEAGU, Carmen , KARP, Kriss, P. , POOLE, Beverly, J. , JOHNSTON, Molly, W.
发明人： WENG, Weiqing , GONG, Caiguo , DIAS, Anthony, J. , AYERS, James, R. , NEAGU, Carmen , KARP, Kriss, P. , POOLE, Beverly, J. , JOHNSTON, Molly, W.
CPC分类号： C08J5/005 , B82Y30/00 , C08J3/12 , C08J3/14 , C08J3/215 , C08J2323/28 , C08K9/04 , C08L23/283 , C08L15/02
摘要： A nanocomposite of a halogenated elastomer and an inorganic, exfoliated clay, suitable for use as an air barrier, is disclosed. The halogenated elastomer can be a polymer comprising C4 to C7 isoolefin derived units, para-methylstyrene derived units, and para-(halomethylstyrene) derived units, or can be a butyl-type rubber. The nanocomposite can be formed by contacting an aqueous slurry of inorganic clay with a polymer cement while agitating vigorously to form emulsions or micro-emulsions to intimately mix the inorganic clay and the elastomer. The nanocomposite so formed has improved air barrier properties and is suitable for use as an innerliner or innertube.
摘要翻译：公开了适合用作空气阻挡层的卤化弹性体和无机剥离粘土的纳米复合材料。卤化弹性体可以是包含C 4 -C 7异烯烃衍生单元，对甲基苯乙烯衍生单元和对 - （卤甲基苯乙烯）衍生单元的聚合物，或者可以是丁基型橡胶。纳米复合材料可通过使无机粘土的含水浆料与聚合物胶泥接触，同时剧烈搅拌以形成乳液或微乳液以密切混合无机粘土和弹性体来形成。这样形成的纳米复合材料具有改进的空气阻隔性能，并且适合用作内衬或内管。

9. 发明申请

WO2004005387A1 FUNCTIONALIZED ELASTOMER NANOCOMPOSITE 审中-公开
标题翻译：功能性弹性体纳米复合材料
公开(公告)号：WO2004005387A1
公开(公告)日：2004-01-15
申请号：PCT/US2003/016944
申请日：2003-05-30
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
发明人： GONG, Caiguo , DIAS, Anthony, J. , TSOU, Andy, H. , POOLE, Beverly, J. , KARP, Kriss, R.
IPC分类号： C08K3/34
CPC分类号： C08K3/346 , C08L51/00 , C08L23/22
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C 2 to C 10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene- co-p -alkylstyrene) elastomers and poly(isobutylene- co -isoprene) elastomers, which are functionalized via Friedel-Crafts reaction with a Lewis acid and a functionalizing agent such as acid anhydrides and/or acylhalides. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译：本发明的一个实施方案是纳米复合材料，其包含粘土和包含至少C2-C10烯烃衍生单元的弹性体; 其中弹性体还包括垂直于弹性体的官能化单体单元。弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过与路易斯酸和官能化试剂如酸酐和/ 或酰卤。粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。本发明的纳米复合材料具有改进的空气阻隔性能，例如可用于轮胎内衬和内管。

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