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1. 发明申请

WO2013043287A2 HYDROCARBON CONVERSION PROCESS 审中-公开
标题翻译：石油转化过程
公开(公告)号：WO2013043287A2
公开(公告)日：2013-03-28
申请号：PCT/US2012/051436
申请日：2012-08-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HERSHKOWITZ, Frank , KEUSENKOTHEN, Paul, F. , FREDERICK, Jeffrey, W. , BASILE, Richard, J. , FULTON, John, W.
发明人： HERSHKOWITZ, Frank , KEUSENKOTHEN, Paul, F. , FREDERICK, Jeffrey, W. , BASILE, Richard, J. , FULTON, John, W.
IPC分类号： C07C4/02 , C10G9/38 , C10G9/00 , C10G9/18 , B01J8/04
CPC分类号： C10G9/16 , B01J19/2485 , B01J2219/00164 , B01J2219/2411 , B01J2219/2419 , B01J2219/2434 , C07C5/327 , C07C5/333 , C07C5/35 , C10B23/00 , C10B27/06 , C10B43/10 , C10B47/02 , C10G9/18 , C10G9/26 , C10G2400/20
摘要： The invention relates to a process for converting hydrocarbons into unsaturated products such as acetylene and/or ethylene. The invention also relates to converting acetylene to olefins such as ethylene and/or propylene, to polymerizing the olefins, and to equipment useful for these processes.
摘要翻译：本发明涉及将烃转化为不饱和产物如乙炔和/或乙烯的方法。本发明还涉及将乙炔转化为烯烃如乙烯和/或丙烯以使烯烃聚合，以及可用于这些方法的设备。

2. 发明申请

WO2012161873A1 COKE GASIFICATION ON CATALYTICALLY ACTIVE SURFACES 审中-公开
标题翻译：焦化气化催化活性表面
公开(公告)号：WO2012161873A1
公开(公告)日：2012-11-29
申请号：PCT/US2012/032735
申请日：2012-04-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F. , IACCINO, Larry, L. , SEARLE, Ronald, G. , DAVIS, Mark, S.
发明人： KEUSENKOTHEN, Paul, F. , IACCINO, Larry, L. , SEARLE, Ronald, G. , DAVIS, Mark, S.
IPC分类号： B01J8/04 , C10G9/20 , C10G9/16
CPC分类号： C10G1/06 , C10B1/02 , C10G9/16 , C10G9/20 , C10G2300/708
摘要： A method and system for converting hydrocarbons into C 2+ unsaturates is described. The method includes providing a structural member upstream of a reaction zone having a surface of a catalytic material, wherein the catalytic material is rendered catalytically active to promote the reaction of coke and/or coke precursors with hydrogen (H 2 ) and/or an oxidant. Then, the method involves exposing a hydrocarbon stream to the catalytic material, wherein the hydrocarbon stream comprising coke and/or coke precursors react in the presence of the catalytic material to convert at least a portion of the coke and/or coke precursors to vapor products. Finally, the hydrocarbons in the hydrocarbon stream containing vapor products and hydrocarbons are converted in the reaction zone to produce a reactor product having C 2+ unsaturates.
摘要翻译：描述了将烃转化为C2 +不饱和物的方法和系统。该方法包括在具有催化材料表面的反应区域的上游提供结构构件，其中催化材料具有催化活性以促进焦炭和/或焦炭前体与氢（H 2）和/或氧化剂的反应。然后，该方法包括将烃流暴露于催化材料中，其中包含焦炭和/或焦炭前体的烃流在催化材料存在下反应，以将至少一部分焦炭和/或焦炭前体转化为蒸气产物。最后，在反应区中转化含有蒸气产物和烃的烃物流中的烃，生成具有C2 +不饱和物的反应器产物。

3. 发明申请

WO2012099673A3 HYDROCARBON CONVERSION PROCESS 审中-公开
公开(公告)号：WO2012099673A3
公开(公告)日：2012-07-26
申请号：PCT/US2011/066174
申请日：2011-12-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F. , HERSHKOWITZ, Frank
发明人： KEUSENKOTHEN, Paul, F. , HERSHKOWITZ, Frank
IPC分类号： C07C29/16 , C07C45/50 , C07C31/10 , C07C47/02 , C08F10/06
摘要： The invention relates to a process for converting hydrocarbons into products containing aldehydes and/or alcohols. The invention also relates to producing olefins from the aldehyde and alcohol, to polymerizing the olefins, and to equipment useful for these processes.

4. 发明申请

WO2011008389A2 PROCESS AND APPARATUS FOR CONVERTING HIGH BOILING POINT RESID TO LIGHT UNSATURATED HYDROCARBONS 审中-公开
标题翻译：将高沸点转化为轻度不饱和烃的方法和装置
公开(公告)号：WO2011008389A2
公开(公告)日：2011-01-20
申请号：PCT/US2010/038356
申请日：2010-06-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F.
发明人： KEUSENKOTHEN, Paul, F.
IPC分类号： C10G9/00
CPC分类号： C10G9/007 , B01J8/0438 , C10G9/005 , C10G9/16 , C10G9/18 , C10G9/26 , C10G51/06 , C10G2300/107 , C10G2300/1077 , C10G2300/301
摘要： A process and apparatus process for preparing a resid-containing hydrocarbon feedstock for use in a regenerative pyrolysis reactor, comprising (a) feeding a resid- containing hydrocarbon feedstock to a thermal cracking unit; (b) thermally cracking at least about 60 wt.% of said resid having a boiling point of at least 565°C in said hydrocarbon feedstock to form a vapor phase containing cracked hydrocarbons; (c) separating said vapor phase from remaining non-volatiles; and (d) converting the separated vapor phase in a regenerative pyrolysis reactor system.
摘要翻译：一种用于制备用于再生热解反应器的含残余烃原料的方法和装置方法，包括（a）将含残余物的烃原料进料到热裂解单元; （b）在所述烃原料中热裂化至少约60重量％的所述具有至少565℃沸点的渣油以形成含有裂化烃的气相; （c）将所述气相与剩余的非挥发物分离; 和（d）在再生热解反应器系统中转化分离的气相。

5. 发明申请

WO2008091439A1 PROCESS FOR CRACKING SYNTHETIC CRUDE OIL-CONTAINING FEEDSTOCK 审中-公开
标题翻译：破碎含油原料的方法
公开(公告)号：WO2008091439A1
公开(公告)日：2008-07-31
申请号：PCT/US2007/085826
申请日：2007-11-29
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F. , MCCOY, James, N. , GRAHAM, James, E. , REIMANN, Chad, D.
发明人： KEUSENKOTHEN, Paul, F. , MCCOY, James, N. , GRAHAM, James, E. , REIMANN, Chad, D.
IPC分类号： C10G69/06
CPC分类号： C10G69/06 , Y10S585/921
摘要： A process for steam cracking liquid hydrocarbon feedstocks containing synthetic crude oil comprises i) hydroprocessing a wide boiling range aliquot containing a) normally liquid hydrocarbon portion substantially free of resids and b) thermally cracked hydrocarbon liquid, boiling in a range from 600° to 1050°F, to provide a synthetic crude oil substantially free of resids; ii) adding to the synthetic crude oil a normally liquid hydrocarbon component boiling in a range from 100° to 1050°F; and iii) cracking the mixture resulting from ii) in a cracker furnace comprising a radiant coil outlet to provide a cracked effluent, wherein the cracking is carried out under conditions sufficient to effect a radiant coil outlet temperature which is greater than the optimum radiant coil outlet temperature for cracking the synthetic crude oil separately. A method for upgrading synthetic crude for use in cracking is also provided, as well as a feedstock for cracking.
摘要翻译：一种用于蒸汽裂解含有合成原油的液体烃原料的方法包括：i）加氢处理宽沸点等分试样，其含有基本上不含残渣的通常为液体烃部分，和b）热裂化烃液体，沸点在600°至1050° F，提供基本上不含残渣的合成原油; ii）向合成原油中加入在100°F至1050°F范围内沸腾的常规液体烃组分; 和iii）在包含辐射线圈出口的裂化炉中裂解由ii）产生的混合物以提供裂化流出物，其中裂化在足以实现大于最佳辐射线圈出口的辐射盘管出口温度的条件下进行分别裂解合成原油的温度。还提供了用于提高用于裂化的合成粗品的方法以及用于裂化的原料。

6. 发明申请

WO2007047942A3 HYDROCARBON RESID PROCESSING AND VISBREAKING STEAM CRACKER FEED 审中-公开
公开(公告)号：WO2007047942A3
公开(公告)日：2007-04-26
申请号：PCT/US2006/041071
申请日：2006-10-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F. , BROWN, Stephen, H.
发明人： KEUSENKOTHEN, Paul, F. , BROWN, Stephen, H.
IPC分类号： C10G69/06
摘要： The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is treated by hydroprocessing and separating and then passed to a steam cracker to obtain a product comprising olefins .

7. 发明申请

WO2007047941A3 RESID PROCESSING FOR STEAM CRACKER FEED AND CATALYTIC CRACKING 审中-公开
公开(公告)号：WO2007047941A3
公开(公告)日：2007-04-26
申请号：PCT/US2006/041069
申请日：2006-10-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BUCHANAN, John, S. , KEUSENKOTHEN, Paul, F. , BROWN, Stephen, H. , WOLFENBARGER, Julian, A. , GRAHAM, James, E. , MCCOY, James, N.
发明人： BUCHANAN, John, S. , KEUSENKOTHEN, Paul, F. , BROWN, Stephen, H. , WOLFENBARGER, Julian, A. , GRAHAM, James, E. , MCCOY, James, N.
IPC分类号： C10G69/00 , C10G69/02 , C10G69/04
摘要： The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is treated by hydroprocessing and visbreaking and then the light fraction is passed to a steam cracker to obtain a product comprising olefins. The heavy fraction is then passed to a catalytic cracker.

8. 发明申请

WO2012161872A1 METHOD OF FLUSHING PYROLYSIS REACTOR 审中-公开
标题翻译：冲洗热解反应器的方法
公开(公告)号：WO2012161872A1
公开(公告)日：2012-11-29
申请号：PCT/US2012/032730
申请日：2012-04-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F.
发明人： KEUSENKOTHEN, Paul, F.
IPC分类号： B01J19/24 , C07C11/24 , B01J8/04 , B01J19/00 , C10G9/26 , C07C4/04
CPC分类号： C10B43/08 , B01J8/0492 , B01J19/0026 , B01J19/2485 , B01J2208/0053 , B01J2219/00159 , B01J2219/00247 , C07C2/76 , C10G2300/301 , C10G2300/708 , C07C11/24
摘要： The present techniques provide a pyrolysis process that is reduced in coke and/or tar formation relative to comparable processes. A flushing fluid is applied or injected directly into a pyrolysis reactor to reduce high levels of coke and tar that can accumulate within the pyrolysis reactor during pyrolysis of the feed.
摘要翻译：本技术提供了相对于可比较的方法减少焦炭和/或焦油形成的热解方法。将冲洗流体直接施加或注入热解反应器中以减少在进料热解过程中可能积聚在热解反应器内的高水平焦炭和焦油。

9. 发明申请

WO2010135073A3 PYROLYSIS REACTOR MATERIALS AND METHODS 审中-公开
公开(公告)号：WO2010135073A3
公开(公告)日：2010-11-25
申请号：PCT/US2010/033423
申请日：2010-05-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HERSHKOWITZ, Frank , CHUN, ChangMin , KEUSENKOTHEN, Paul, F. , LING, Shiun , MOHR, Gary, D.
发明人： HERSHKOWITZ, Frank , CHUN, ChangMin , KEUSENKOTHEN, Paul, F. , LING, Shiun , MOHR, Gary, D.
IPC分类号： C10G9/00 , C04B35/48 , C01G25/02 , F23G7/00
摘要： In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 20600C and which remains in oxide form when exposed to a gas having an oxygen partial pressure of 10"15 bar, a carbon partial pressure above the carbon partial pressure of the zirconium carbide and zirconium oxide phase transition at the same temperature, and at temperatures below the temperature of the zirconium triple point at the oxygen partial pressure of 10"15 bar; and ii) when exposed to a gas having an oxygen partial pressure of 10"15 bar and at temperatures above the zirconium triple point at the oxygen partial pressure of 10"15 bar. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising the above refractory material.

10. 发明申请

WO2010065200A1 CONVERSION OF CO-FED METHANE AND LOW HYDROGEN CONTENT HYDROCARBON FEEDSTOCKS TO ACETYLENE 审中-公开
标题翻译： CO-FED甲烷和低氢含量碳氢化合物转化为乙炔的转化
公开(公告)号：WO2010065200A1
公开(公告)日：2010-06-10
申请号：PCT/US2009/061047
申请日：2009-10-16
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KEUSENKOTHEN, Paul, F. , HERSHKOWITZ, Frank
发明人： KEUSENKOTHEN, Paul, F. , HERSHKOWITZ, Frank
IPC分类号： C10G69/02 , C10G9/18
CPC分类号： C07C2/78 , C07C5/09 , C10G2400/24 , C07C11/24 , C07C11/04
摘要： A process and apparatus are provided to produce acetylene from a feed stream of low hydrogen content hydrocarbons such as coal by: (a) blending the hydrocarbons with methane to provide a blended mixture containing at least about 12.5 wt% atomic hydrogen; (b) partially combusting the blended mixture in a reactor in the presence of a source of oxygen to provide a partially combusted mixture at or above a temperature sufficient to produce methyl radicals; (c) maintaining the partially combusted mixture at or above the temperature for a residence time sufficient to produce a product stream containing enhanced yields of acetylene without significant formation of coke or coke precursors; (d) cooling the product stream to reduce the temperature of the product stream within a time sufficiently brief to substantially arrest any cracking reactions and provide a cooled product stream; and (e) recovering acetylene from the cooled product stream. The acetylene can be converted to ethylene by a conventional hydrogenation process.
摘要翻译：提供了一种方法和装置，用于通过以下方式从低含氢烃类进料流中产生乙炔：（a）将烃与甲烷混合，得到含有至少约12.5wt％原子氢的共混混合物; （b）在氧气源存在的情况下在反应器中部分燃烧混合物，以在足以产生甲基自由基的温度或高于其温度下提供部分燃烧的混合物; （c）将部分燃烧的混合物保持在等于或高于该温度的停留时间足以产生含有较高产率的乙炔的产物流，而不显着形成焦炭或焦炭前体; （d）冷却产物流以在足够短的时间内降低产物流的温度，以基本上阻止任何裂解反应并提供冷却的产物流; 和（e）从冷却的产物流中回收乙炔。乙炔可以通过常规的氢化方法转化为乙烯。

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