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1. 发明申请

WO2010074815A1 THERMOPLASTIC OLEFIN COMPOSITIONS 审中-公开
标题翻译：热塑性烯烃组合物
公开(公告)号：WO2010074815A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/063105
申请日：2009-11-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , DEKMEZIAN, Armenag , SQUIRE, Kevin, R. , DE GRACIA, Carlos, U. , JOLIBOIS, Keith, E. , GARCIA-FRANCO, Cesar, A. , THACKSTON, Ronald, R.
发明人： JIANG, Peijun , DEKMEZIAN, Armenag , SQUIRE, Kevin, R. , DE GRACIA, Carlos, U. , JOLIBOIS, Keith, E. , GARCIA-FRANCO, Cesar, A. , THACKSTON, Ronald, R.
IPC分类号： C08L23/10 , C08L23/20 , C08F4/64
CPC分类号： C08L23/12 , C08F4/65908 , C08F4/65927 , C08F210/06 , C08L23/142 , C08L2205/02 , C08L2205/025 , C08L2207/02 , C08L2308/00 , C08L2314/06 , C08L2666/06 , C08F210/16 , C08F2500/20 , C08F2500/12 , C08F2500/03 , C08F2500/11
摘要： An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) propylene-containing second polymer having a different crystallinity from the first polymer. The polymer blend has a melting temperature, Tm, of at least 135 °C, a melt flow rate of at least 70 dg/min, a tensile strength of at least 8 MPa, an elongation at break of at least 300%.
摘要翻译：反应器内聚合物共混物包含（a）含丙烯的第一聚合物; 和（b）与第一聚合物具有不同结晶度的含丙烯的第二聚合物。聚合物共混物具有至少135℃的熔融温度Tm，至少70dg / min的熔体流动速率，至少8MPa的拉伸强度，至少300％的断裂伸长率。

2. 发明申请

WO2010075111A2 THERMOPLASTIC ELASTOMER POLYOLEFIN IN-REACTOR BLENDS AND MOLDED ARTICLES THEREFROM 审中-公开
标题翻译：热塑性弹性体聚烯烃反应器混合物和其中的成型制品
公开(公告)号：WO2010075111A2
公开(公告)日：2010-07-01
申请号：PCT/US2009/068123
申请日：2009-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , DEKMEZIAN, Armenag , SQUIRE, Kevin, R. , GARCIA-FRANCO, Cesar, A.
发明人： JIANG, Peijun , DEKMEZIAN, Armenag , SQUIRE, Kevin, R. , GARCIA-FRANCO, Cesar, A.
IPC分类号： C08L23/04 , C08F10/02
CPC分类号： C08L23/16 , C08F10/06 , C08F210/06 , C08L23/12 , C08L2205/02 , C08L2207/02 , C08L2207/07 , C08L2308/00 , C08L2314/06 , C08F2/001 , C08F210/16 , C08F2500/04 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/20
摘要： This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene- containing polymer having a density of greater than 0.90 g/cm 3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm 3 , wherein the polymer blend has a Tm of at least 90 0C (DSC second melt), a density of less than 0.92 g/cm 3 , and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt% ethylene and from 0 to less than 10 wt% comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm 3 , an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt% ethylene and 30 to 10 wt% comonomer, said second ethylene polymer having a density of 0.910 g/cm 3 or less, wherein the polymer blend has: (a) a Tm of at least 100 0C over a density ranging from 0.84 to 0.92 g/cm 3 ; (b) a elongation at break of 300% or more; (c) a strain hardening index M300/M100 of at least 1.2; (d) a ratio of complex viscosity at 0.01 rad/s to the viscosity at 100 rad/s is of at least 30; and (e) a shear thinning slope of the plot of log(dynamic viscosity) versus log(frequency) less than -0.2.
摘要翻译：本发明涉及一种反应器内聚合物共混物，其包含：（a）密度大于0.90g / cm 3，Mw大于20,000g / mol的第一含乙烯聚合物和（b）第二含乙烯的聚合物聚合物的密度小于0.90g / cm 3，其中聚合物共混物具有至少90℃的Tm（DSC第二熔体），密度小于0.92g / cm 3，并且第一和第二聚合物的密度不同至少1％。具体而言，本发明涉及一种反应器内聚合物共混物，其包含：（a）包含90至100重量％乙烯和0至小于10重量％共聚单体的第一乙烯聚合物，所述第一乙烯聚合物组分的密度大于0.920g / cm3，Mw为20,000g / mol以上; 和（b）包含70-90wt％乙烯和30-10wt％共聚单体的第二乙烯聚合物，所述第二乙烯聚合物的密度为0.910g / cm 3或更低，其中所述聚合物共混物具有：（a）Tm 至少100℃，密度范围为0.84至0.92g / cm3; （b）断裂伸长率在300％以上; （c）至少为1.2的应变硬化指数M300 / M100; （d）0.01rad / s下的复数粘度与100rad / s下的粘度之比至少为30; 和（e）对数（动态粘度）对log（频率）小于-0.2的曲线的剪切变薄斜率。

3. 发明申请

WO2010075106A2 HETEROGENEOUS IN-REACTOR POLYMER BLENDS 审中-公开
标题翻译：异构反应器聚合物混合物
公开(公告)号：WO2010075106A2
公开(公告)日：2010-07-01
申请号：PCT/US2009/068116
申请日：2009-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DEGRACIA, Carlos, U. , SQUIRE, Kevin, R. , JIANG, Peijun , DEKMEZIAN, Armenag , POOLE, Beverly, Jean , GARCIA-FRANCO, Cesar, A.
发明人： DEGRACIA, Carlos, U. , SQUIRE, Kevin, R. , JIANG, Peijun , DEKMEZIAN, Armenag , POOLE, Beverly, Jean , GARCIA-FRANCO, Cesar, A.
IPC分类号： C08L23/10 , C08L23/04
CPC分类号： C08L23/16 , C08F10/06 , C08F210/06 , C08L23/12 , C08L2205/02 , C08L2207/02 , C08L2207/07 , C08L2308/00 , C08L2314/06 , C08F2/001 , C08F210/16 , C08F2500/04 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/20
摘要： An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt% and about 80 wt% units derived from ethylene and between about 50 wt% and about 20 wt% units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than -0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 1500C and a second melting point of at least 400C such that the difference between the first and second melting temperatures is at least 200C.
摘要翻译：反应器内聚合物共混物包含（a）含丙烯的第一聚合物; 和（b）含乙烯的第二聚合物，使得所述聚合物共混物包含约50重量％至约80重量％的衍生自乙烯的单元和约50重量％至约20重量％的衍生自丙烯的单元。该共混物基本上不含二烯，第二聚合物中乙烯 - 乙烯 - 乙烯三元共聚物形式的乙烯含量至少为40％。第二聚合物含有至少0.1个分支，每10,000个碳原子具有8个或更多个碳原子。此外，所述共混物具有至少1.8的应变硬化指数，对数（动态粘度）对log（频率）的曲线中的剪切稀化斜率小于-0.2，并且当经历差示扫描量热法时呈现至少两个峰（第一次熔化），对应于至少150℃的第一熔点和至少40℃的第二熔点，使得第一和第二熔化温度之间的差值至少为200℃。

4. 发明申请

WO2004046214A2 MULTIPLE CATALYST SYSTEM FOR OLEFIN POLYMERIZATION AND POLYMERS PRODUCED THEREFROM 审中-公开
标题翻译：用于烯烃聚合的多元催化剂体系及其生产的聚合物
公开(公告)号：WO2004046214A2
公开(公告)日：2004-06-03
申请号：PCT/US2003/032910
申请日：2003-10-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , DEKMEZIAN, Armenag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , JOHNSRUD, David, R.
发明人： JIANG, Peijun , DEKMEZIAN, Armenag , CANICH, Jo, Ann, M. , SIMS, Charles, L. , ABHARI, Ramin , GARCIA-FRANCO, Cesar, A. , JOHNSRUD, David, R.
IPC分类号： C08F210/06
CPC分类号： C09J123/12 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08L57/02 , C08L2666/02 , C09J5/00 , C09J7/20 , C09J123/10 , C09J2201/606 , C09J2201/622 , C09J2205/31 , C09J2401/006 , C09J2421/00 , C09J2423/006 , C09J2423/046 , C09J2423/106 , C09J2427/006 , C09J2433/00 , Y10S526/943 , C08F4/65904 , C08F2500/15 , C08F2500/05 , C08F2500/20 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F236/20 , C08F2500/03 , C08F210/16 , C08F4/63904
摘要： This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g’) of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g’) of 0.95 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 100,000; and d) a heat of fusion of 1 to 70 J/g. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g’) of 0.98 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 60,000; d) a heat of fusion of 1 to 50 J/g. This invention also relates to a homopolypropylene or a copolymer of propylene and up to 5 mole % ehtylene having: a) an isotactic run length of 1 to 3o (isotactic run length “IRL” is defined to be the percent of mmmm pentad divided by 0.5 x percent of mmmr pentad) as determined by Carbon 13 NMR, preferably 3 to 25, more preferably 4 to 20, b) a percent of r dyad of greater than 20%, preferably from 20 to 70% as determined by Carbon 13 NMR, and c) a heat of fusion of 70 J/g or less, preferably 60 J/g or less, more preferably between 1 and 55 J/g, more preferably between 4 and 60 J/g. This invention further relates to a process to produce an olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less at selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, at the selected polymerization conditions in a reaction zone; 4) obtaining the polymer. This invention further relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 1000,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100 °C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.
摘要翻译：本发明涉及包含一种或多种C 3至C 40烯烃，任选一种或多种二烯烃和小于15摩尔％乙炔的聚合物，其中聚合物具有：a）1tonton或更大的Dot T-Peel; 和b）在聚合物的Mz下测量的支化指数（g'）为0.95或更小; c）Mw为100,000或更小。本发明还涉及一种包含一种或多种C 3至C 40烯烃的聚合物，其中聚合物具有：a）在牛皮纸上的1牛顿或更多的点T皮; b）在聚合物的Mz处测量的支化指数（g'）为0.95或更小; c）10,000至100,000的Mw; 和d）1至70J / g的熔化热。本发明还涉及一种包含一种或多种C 3至C 40烯烃的聚合物，其中聚合物具有：a）在牛皮纸上的1牛顿或更多的点T皮; b）在聚合物的Mz测量的支化指数（g'）为0.98或更小; c）10,000至60,000的Mw; d）熔化热为1〜50J / g。本发明还涉及丙烯和至多5摩尔％乙炔的均聚丙烯或共聚物，其具有：a）全同立构游程长度为1至3o（全同立构游程长度“IRL”定义为mmmm五元组的百分比除以0.5 通过碳13 NMR测定，优选3至25，更优选4至20，b）通过碳13 NMR测定的r二重比例大于20％，优选20至70％的百分比，和c）70J / g以下，优选为60J / g以下，更优选为1〜55J / g，更优选为4〜60J / g的熔融热。本发明还涉及一种生产烯烃聚合物的方法，包括：1）选择能够在选定的聚合条件下产生Mw为100,000以下且聚合度为5％以下的聚合物的第一催化剂组分; 2）选择能够在选定的聚合条件下产生Mw为100,000以下且结晶度为20％以上的聚合物的第二催化剂成分; 3）在一个或多个活化剂存在下，使催化剂组分与一种或多种C 3至C 40烯烃在选定的聚合条件下在反应区中接触; 4）获得聚合物。本发明还涉及一种制备支链烯烃聚合物的连续方法，包括：1）选择能够在选择的聚合条件下产生Mw为1000,000以下且结晶度为5％以下的聚合物的第一催化剂组分; 2）选择能够在选定的聚合条件下产生Mw为100,000以下且结晶度为20％以上的聚合物的第二催化剂成分; 3）在一种或多种活化剂存在下与一种或多种C 3至C 40烯烃和任选的一种或多种二烯烃接触催化剂组分; 4）在大于100℃的温度下; 5）停留时间为120分钟以下; 6），其中第一催化剂与第二催化剂的比例为1:1至50:1; 7）其中催化剂组分的活性为每克催化剂组分至少100千克聚合物; 并且其中至少20％的烯烃转化为聚合物。

5. 发明申请

WO2012094099A2 FOAMABLE THERMOPLASTIC REACTOR BLENDS AND FOAM ARTICLE THEREFROM 审中-公开
标题翻译：可发泡的热塑性反应器共混物及其泡沫制品
公开(公告)号：WO2012094099A2
公开(公告)日：2012-07-12
申请号：PCT/US2011/064139
申请日：2011-12-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , SAHNOUNE, Abdelhadi , DEKMEZIAN, Armenag
发明人： JIANG, Peijun , SAHNOUNE, Abdelhadi , DEKMEZIAN, Armenag
IPC分类号： C08J9/04 , C08J9/06 , C08L23/10 , C08F10/06
CPC分类号： C08L23/10 , C08F255/02 , C08J9/0061 , C08J2205/052 , C08J2323/10 , C08J2423/12 , C08L23/12 , C08L23/142 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2666/06
摘要： This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt% propylene and from 0 to less than 10 wt% comonomer, said first propylene component having a Tm of 120°C or more; and (b) a second propylene polymer component comprising from 30 to 90 wt% propylene and 70 to 10 wt% comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120°C; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%; and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec -1 and temperature of 180°C; and where when the blend is foamed with a foaming agent, the foamed article has a density of 800 kg/m 3 or less.
摘要翻译：本发明涉及包含反应器内聚合物共混物的可发泡共混物，其包含：（a）第一丙烯聚合物组分，其包含90至100wt％的丙烯和0至小于10wt％的共聚单体，所述第一丙烯组分的Tm为120℃或更高; 和（b）包含30-90重量％丙烯和70-10重量％共聚单体的第二丙烯聚合物组分，所述第二丙烯聚合物具有30,000g / mol或更高的Mw，并且所述第二含丙烯聚合物具有结晶度与第一聚合物相差至少5％，其中聚合物共混物在与发泡剂结合之前具有：（i）至少120℃的Tm; （ii）10dg / min或更高的MFR; （iii）至少8MPa的拉伸强度; （iv）至少200％的断裂伸长率; 和（v）当在1秒-1的应变速率和180℃的温度下测量伸长粘度时，断裂伸长粘度与线性粘度之比为5或更大; 当混合物用发泡剂发泡时，发泡制品的密度为800kg / m 3或更低。

6. 发明申请

WO2010077881A2 THERMOPLASTIC POLYOLEFIN IN-REACTOR BLENDS AND MOLDED ARTICLES THEREFROM 审中-公开
标题翻译：热塑性聚烯烃反应器混合物和其中的成型制品
公开(公告)号：WO2010077881A2
公开(公告)日：2010-07-08
申请号：PCT/US2009/068104
申请日：2009-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , JIANG, Peijun , DEKMEZIAN, Armenag , FLENDRIG, Joseph Gustaaf, Marie
发明人： JIANG, Peijun , DEKMEZIAN, Armenag , FLENDRIG, Joseph Gustaaf, Marie
IPC分类号： C08J5/00 , C08L23/12
CPC分类号： C08L23/16 , C08F10/06 , C08F210/06 , C08L23/12 , C08L2205/02 , C08L2207/02 , C08L2207/07 , C08L2308/00 , C08L2314/06 , C08F2/001 , C08F210/16 , C08F2500/04 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/20
摘要： This invention relates to a molded article comprising an in-reactor polymer blend comprising: (a) a first propylene polymer comprising 90 to 100 wt% propylene and from 0 to less than 10 wt% comonomer, said first propylene component having a Tm of 135°C or more; and (b) a second propylene polymer comprising from 30 to 90 wt% propylene and 70 to 10 wt% comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend has: (a) a Tm of at least 135°C, (b) a melt flow rate of at least 70 dg/min, (c) a tensile strength of at least 8 MPa, (d) an elongation at break of at least 200%, (e) a tensile strength at break of 10 MPa or more, and (f) a GME 60280 scratch resistance of less than 1.2 DL at a scratching load of 5 Newtons.
摘要翻译：本发明涉及包含反应器内聚合物共混物的模制品，其包含：（a）包含90至100重量％丙烯和0至小于10重量％共聚单体的第一丙烯聚合物，所述第一丙烯组分的Tm为135 ℃以上; 和（b）第二丙烯聚合物，其包含30至90重量％的丙烯和70至10重量％的共聚单体，所述第二丙烯聚合物的Mw为30,000g / mol或更高，并且所述第二丙烯聚合物具有不同的结晶度与第一聚合物相比至少5％，其中聚合物共混物具有：（a）Tm至少为135℃，（b）熔体流动速率至少为70dg / min，（c）拉伸强度至少8MPa，（d）断裂伸长率至少为200％，（e）断裂时的拉伸强度为10MPa以上，（f）在刮擦载荷下GME 60280耐擦伤性小于1.2DL 5牛顿。

7. 发明申请

WO2004072177A1 DIENE-MODIFIED PROPYLENE POLYMER NUCLEATING AGENTS 审中-公开
标题翻译：二烯改性丙烯聚合物核化剂
公开(公告)号：WO2004072177A1
公开(公告)日：2004-08-26
申请号：PCT/US2004/000299
申请日：2004-01-08
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , AGARWAL, Pawan, K. , DEKMEZIAN, Armenag , MEHTA, Aspy, K. , WENG, Weiqing
发明人： AGARWAL, Pawan, K. , DEKMEZIAN, Armenag , MEHTA, Aspy, K. , WENG, Weiqing
IPC分类号： C08L23/16
CPC分类号： C08L23/10 , C08L23/02 , C08L23/06 , C08L23/12 , C08L23/145 , C08L23/16 , C08L2205/02 , C08L2666/04 , C08L2666/06
摘要： This invention relates to compositions derived from polyolefins combined with polymeric nucleating agent. The nucleating agent is specifically a diene-propylene copolymer.
摘要翻译：本发明涉及由聚烯烃与聚合物成核剂组合得到的组合物。成核剂特别是二烯 - 丙烯共聚物。

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