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    • 3. 发明申请
    • POLYMERIZATION PROCESS
    • 聚合工艺
    • WO2018063764A1
    • 2018-04-05
    • PCT/US2017/050421
    • 2017-09-07
    • EXXONMOBIL CHEMICAL PATENTS INC.
    • BRANDL, Corrine, L.EHRMAN, Fred, D.LATTNER, James, R.
    • C08F2/00C08F2/34C08F210/02
    • A process including contacting one or more monomers, at least one catalyst system, and at least two condensing agents under polymerizable conditions to produce a polyolefin polymer is provided where the vapor pressure of the condensing agents is ±4 bara of the optimum vapor pressure given by the formula: optimum vapor pressure = 614 - 716*D + 2.338*P + 3.603*ln(MI), where the optimum vapor pressure has units (bara), D is the polyolefin polymer density with units (g/cc), P is the polymerization condition pressure with units (barg), and MI is the polyolefin polymer melt index with units (g/lOmin). The invention also relates to a process where at least three condensing agents are used.
    • 包括在可聚合条件下使一种或多种单体,至少一种催化剂体系和至少两种缩合剂接触以制备聚烯烃聚合物的方法,其中缩合剂的蒸气压为±10℃; 最佳蒸汽压力为614-716 * D + 2.338 * P + 3.603 * ln(MI),其中最佳蒸汽压力为单位(巴),D为聚烯烃聚合物密度 单位为(g / cc),P是单位为(巴)的聚合条件压力,MI为聚烯烃聚合物熔体指数,单位为(g / 10min)。 本发明还涉及使用至少三种缩合剂的方法。