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    • 2. 发明申请
    • LIQUID CONTACTING OF POST-QUENCH EFFLUENT VAPOR STREAMS FROM OXYGENATE TO OLEFINS CONVERSION TO CAPTURE CATALYST FINES
    • 液体接触后氧化物蒸汽流从氧气转化为烯烃转化以捕获催化剂
    • WO2005017072A8
    • 2005-08-04
    • PCT/US2004019341
    • 2004-06-17
    • EXXONMOBIL CHEM PATENTS INCVAN EGMOND COR FDING ZHONG Y
    • VAN EGMOND COR FDING ZHONG Y
    • C07C1/20C10G3/00
    • C07C1/20C07C2529/83C07C2529/85C10G3/49C10G3/62C10G2400/20Y02P30/20Y02P30/42Y02P30/48C07C11/02
    • A process is provided for converting oxygenate to olefins from a fluidized bed reactor which comprises removal of catalyst fines from a quenched vaporous effluent by contacting with a liquid low in catalyst fines content, e.g., oxygenate feedstock, or by-product water from the oxygenates to olefins conversion which is stripped and/or filtered. The process comprises: contacting a feedstock comprising oxygenate with a catalyst comprising a molecular sieve under conditions effective to produce a deactivated catalyst having carbonaceous deposits and a product comprising the olefins; separating the deactivated catalyst from the product to provide a separated vaporous product which contains catalyst fines; quenching the separated vaporous product with a liquid medium containing water and catalyst fines, in an amount sufficient to form a light product fraction comprising light olefins and catalyst fines and a heavy product fraction comprising water, heavier hydrocarbons and catalyst fines; treating the light product fraction by contacting with a liquid substantially free of catalyst fines to provide a light product fraction having reduced catalyst fines content and a liquid fraction of increased fines content; compressing the light product fraction having reduced catalyst fines content; and recovering the light olefins from the compressed light product fraction.
    • 提供了一种从流化床反应器中将含氧化合物转化为烯烃的方法,其中包括通过与催化剂细粉含量较低的液体(例如含氧化合物原料或副产物水从含氧化合物到 烯烃转化,其被汽提和/或过滤。 该方法包括:在有效产生具有碳质沉积物的失活催化剂和包含烯烃的产物的条件下,使包含含氧化合物的原料与包含分子筛的催化剂接触; 将失活的催化剂与产物分离以提供含有催化剂细粉的分离的蒸汽产物; 用含有水和催化剂细粉的液体介质淬灭分离的蒸汽产物,其量足以形成包含轻质烯烃和催化剂细粒的轻质产物级分,以及包含水,较重烃和催化剂细粉的重质产物级分; 通过与基本上不含催化剂细粒的液体接触来处理轻质产物级分,以提供具有降低的催化剂细粉含量的轻质产物级分和增加的细粉含量的液体级分; 压缩具有降低的催化剂细粉含量的轻产品级分; 并从压缩轻质产物馏分中回收轻质烯烃。