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    • 10. 发明申请
    • HIGH CAPACITY CATHODE MATERIAL WITH STABILIZING NANOCOATINGS
    • 具有稳定性的高容量阴极材料
    • WO2014099878A1
    • 2014-06-26
    • PCT/US2013/075610
    • 2013-12-17
    • ENVIA SYSTEMS, INC.
    • BOWLING, Charles A.VENKATACHALAM, SubramanianLOPEZ, Herman A.KUMAR, Sujeet
    • H01M4/485H01M4/42H01M4/58
    • H01M4/131H01M4/1391H01M2004/028
    • A positive electrode active material comprising a lithium rich metal oxide active composition coated with aluminum zinc oxide coating composition is disclosed. The aluminum zinc oxide can be represented by the formula Α1 χ Ζn 1-3x/2 , where x is from about 0.01 to about 0.6. In some embodiments, the material can have an average voltage that is very stable with cycling, and a specific capacity of at least about 175 mAh/g and an average voltage of at least about 3.55V discharged at a rate of C/3 from 4.6V to 2V against lithium. The material can further comprise an overcoat of metal halide over the aluminum zinc oxide coating. In some embodiments, the material can have from about 1 mole percent to about 15 mole percent aluminum zinc oxide coating and from about 0.5 mole percent to about 3 mole percent aluminum halide overcoat.
    • 公开了一种包含涂覆有氧化铝锌涂层组合物的富锂金属氧化物活性组合物的正极活性材料。 氧化锌铝可由式&Agr; 1X&Zgr; n1-3x / 2表示,其中x为约0.01至约0.6。 在一些实施方案中,该材料可以具有在循环时非常稳定的平均电压,并且以4.6的C / 3速率从至少约175mAh / g的平均电压和至少约3.55V的平均电压放电 V至2V对锂。 该材料可以进一步包括在氧化铝锌涂层上的金属卤化物外涂层。 在一些实施方案中,该材料可具有约1摩尔%至约15摩尔%的氧化铝锌涂层和约0.5摩尔%至约3摩尔%卤化铝外涂层。