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1. 发明申请

WO2009000545A2 A METHOD FOR MODULATING THE RELEASE RATE OF MICROENCAPSULATED ACTIVE INGREDIENTS 审中-公开
标题翻译：一种调节微囊化活性成分释放速率的方法
公开(公告)号：WO2009000545A2
公开(公告)日：2008-12-31
申请号：PCT/EP2008/005271
申请日：2008-06-27
申请人： ENDURA S.p.A. , SIPCAM S.p.A. , GOBBI, Carlotta , BASSETTI, Lucio , BORZATTA, Valerio , BERNARDINI, Marco , BORGO, Francesca , CAPUZZI, Luigi
发明人： GOBBI, Carlotta , BASSETTI, Lucio , BORZATTA, Valerio , BERNARDINI, Marco , BORGO, Francesca , CAPUZZI, Luigi
IPC分类号： A01N25/28 , A01N25/04 , A01N53/00 , A01N43/653 , A01N33/18 , A01N25/32 , A01P3/00 , A01P7/00 , A01P13/00
CPC分类号： A01N25/28 , A01N25/02 , A01N25/04 , A01N25/30 , A01N33/18 , A01N33/22 , A01N37/20 , A01N37/26 , A01N43/50 , A01N43/54 , A01N43/58 , A01N43/653 , A01N51/00 , A01N53/00 , A01N57/16 , A01N2300/00
摘要： A method for modulating the release rate of microencapsulated active ingredients comprising the following steps: I) preparation of an aqueous suspension A) comprising microcapsules of at least one active ingredient, II) preparation of a liquid emulsifiable in water, component B), comprising a solvent of the active ingredient and at least a surfactant, III) water, component C), for diluting to the application dose the active ingredient, and mixing A), B) and C).
摘要翻译：一种用于调节微囊化活性成分释放速率的方法，包括以下步骤：I）包含至少一种活性成分的微胶囊的水性悬浮液A）的制备，II）在水中可乳化的液体的制备，组分B），其包含活性成分的溶剂和至少一种表面活性剂，III）水，组分C），用于稀释施用剂量的活性成分，并混合A），B）和C）。

2. 发明申请

WO2009086914A3 A METHOD FOR MODULATING THE RELEASE RATE OF MICROENCAPSULATED ACTIVES 审中-公开
公开(公告)号：WO2009086914A3
公开(公告)日：2009-07-16
申请号：PCT/EP2008/011093
申请日：2008-12-23
申请人： ENDURA S.P.A. , GOBBI, Carlotta , BASSETTI, Lucio , BORZATTA, Valerio
发明人： GOBBI, Carlotta , BASSETTI, Lucio , BORZATTA, Valerio
IPC分类号： A01N43/54 , A01N43/30 , A01N53/00 , A01N25/28
摘要： A method for regulating the release rate of microencapsulated actives comprising: 1a) addition or subtraction of piperonylbutoxide (PBO), component B) to 2a) formulations A) comprising at least one microencapsulated active having agrochemical activity, optionally PBO outside the microcapsule, 3a) dilution by water of component A) and/or component B) until the active application dose, the ratio by weight PBO/active ranges from 0.1 to 80, the PBO subtraction being feasible only when the PBO is present outside the microcapsule of the formulation A).

3. 发明申请

WO2005042512A1 PROCESS FOR SYNTHESISING HELIOTROPINE AND ITS DERIVATIVES 审中-公开
标题翻译：合成有机化合物及其衍生物的方法
公开(公告)号：WO2005042512A1
公开(公告)日：2005-05-12
申请号：PCT/EP2004/052710
申请日：2004-10-28
申请人： ENDURA S.P.A. , BORZATTA, Valerio , CAPPARELLA, Elisa , GOBBI, Carlotta , POLUZZI, Elisa
发明人： BORZATTA, Valerio , CAPPARELLA, Elisa , GOBBI, Carlotta , POLUZZI, Elisa
IPC分类号： C07D317/54
CPC分类号： C07D317/54
摘要： A new high-yield, easily industrialized process for synthesising compounds of formula (IV), in which X 1 and X 2 , the same or different, are linear or branched C1-C8 alkyls, n and m are 0,1 or 2, with the proviso that n and m are not simultaneously 0; or (OX 1 )n and (OX 2 )m taken together form an O-T-O group where T is chosen from -CH 2 -, -CH 2 CH 2 , -CH 2 CH 2 CH 2 -, -C(CH 3 ) 2 -. The process comprises treating a chloromethyl derivative (I) with an alkaline acetate to form the intermediate acetylderivative (II); the intermediate (II) is to hydrolysed to form the alcohol (III); the alcohol (III) is then oxidised in the presence of air and catalysts to obtain the desired derivative (IV). The process runs its course within a short period of time, with high yields and high selectivity; in addition, the process does not require purification and separation of the intermediates and can therefore be favourably conducted in a single batch.
摘要翻译：合成式（IV）化合物的新的高产率，易于工业化的方法，其中X1和X2相同或不同，为直链或支链C1-C8烷基，n和m为0,1或2，其中条件是n和m不同时为0; 或（OX 1）n和（OX 2）m一起形成O-T-O基团，其中T选自-CH 2 - ， - CH 2 CH 2，-CH 2 CH 2 CH 2 - ， - C（CH 3）2 - 。该方法包括用碱性乙酸盐处理氯甲基衍生物（I）以形成中间体乙酰衍生物（II）; 中间体（II）被水解形成醇（III）; 然后在空气和催化剂的存在下将醇（III）氧化以获得所需的衍生物（IV）。该过程在短时间内运行，产量高，选择性高; 此外，该方法不需要中间体的纯化和分离，因此可以在单次批次中有利地进行。

4. 发明申请

WO2006111570A2 NEW BIOLOGICALLY ACTIVE FORMULATION 审中-公开
标题翻译：新生物活性配方
公开(公告)号：WO2006111570A2
公开(公告)日：2006-10-26
申请号：PCT/EP2006/061724
申请日：2006-04-21
申请人： ENDURA S.P.A. , PICCOLO, Oreste , BORZATTA, Valerio , DELOGU, Giovanna , CAPPARELLA, Elisa , DE CANDIA, Cristina , GOBBI, Carlotta , DI BLASI, Giovanna
发明人： PICCOLO, Oreste , BORZATTA, Valerio , DELOGU, Giovanna , CAPPARELLA, Elisa , DE CANDIA, Cristina , GOBBI, Carlotta , DI BLASI, Giovanna
IPC分类号： A01N25/10 , A01N57/16 , A01N47/40 , A01N47/18 , A01N47/02 , A01N43/78 , A01N43/54 , A01N43/50 , A01P7/04 , A01N43/30
CPC分类号： A01N25/10
摘要： The present invention provides a formulation characterised by the simultaneous presence in cyclodextrin based supramolecular complexes, of two components, one of which possesses insecticidal, acaricidal, fungicidal, snailcidal or vermicidal activity and the other possesses an activity synergistic with the first, enhancing its effectiveness. The biologically active substance is chosen from the following classes of chemical products: carbamates, organophosphates, thioureas, pentatomic or hexatomic heterocycles in which 1 , 2 or 3 nitrogen atoms are present. The synergistic substance can be chosen from components containing at least one aromatic or non aromatic carbocyclic ring, such as piperonyl butoxide, sesamol, verbutin or MGK 264. For the same dose, the activity of the present formulations is greater than that of the mixture of the two active components alone or separately complexed with cyclodextrin. The process for preparing said formulation and its use for the activities herein indicated are further aspects of the present invention.
摘要翻译：本发明提供一种制剂，其特征在于同时存在两种组分的两种组分的基于环糊精的超分子复合物，其中一种具有杀虫，杀螨，杀真菌，杀虫或杀虫活性，另一种具有与第一种协同作用的活性，提高其有效性。生物活性物质选自以下类别的化学产品：其中存在1,2或3个氮原子的氨基甲酸酯，有机磷酸酯，硫脲，五原子或六原子杂环。协同物质可以选自含有至少一个芳族或非芳族碳环的组分，例如胡椒基丁醚，芝麻酚，鸟嘌呤或MGK 264.对于相同的剂量，本发明制剂的活性大于两种活性组分单独或分别与环糊精复合。制备所述制剂的方法及其用于本文所述活性的用途是本发明的另外的方面。

5. 发明申请

WO2013135806A1 USE OF DERIVATIVE COMPOUNDS OF 1,3-BENZODIOXOLE IN INSECTICIDAL COMPOSITIONS 审中-公开
标题翻译：在杀虫剂组合物中使用1,3-苯二酮的衍生化合物
公开(公告)号：WO2013135806A1
公开(公告)日：2013-09-19
申请号：PCT/EP2013/055224
申请日：2013-03-14
申请人： ENDURA S.P.A.
发明人： GOBBI, Carlotta , BORZATTA, Valerio , CAPPARELLA, Elisa
IPC分类号： A01N43/30 , A01N53/00 , A01P7/00
CPC分类号： A01N25/32 , A01N43/30 , A01N47/10 , A01N53/00 , A01N57/16 , C07D317/44 , A01N47/22
摘要： The invention relates to the use of a derivative compound of 1,3-benzodioxole of formula (I) wherein R is a linear or branched (C 4 -C 10 ) alkyl substituent as a synergistic compound of insecticidal active ingredients insecticidal compositions comprising at least one compound of Formula (I) and at least one insecticidal active ingredient are also described.
摘要翻译：本发明涉及式（I）的1,3-苯并间二氧杂环戊烯衍生物的用途，其中R是直链或支链（C 4 -C 10）烷基取代基作为杀虫活性成分的杀虫组合物的协同化合物，其包含至少一种化合物的式（I）化合物和至少一种杀虫活性成分。

6. 发明申请

WO2014009269A1 INSECTICIDAL FORMULATIONS OF MICROCAPSULES 审中-公开
标题翻译：微生物的杀虫剂配方
公开(公告)号：WO2014009269A1
公开(公告)日：2014-01-16
申请号：PCT/EP2013/064242
申请日：2013-07-05
申请人： ENDURA S.P.A
发明人： GOBBI, Carlotta , CAMPANATI, Matteo , BORZATTA, Valerio
IPC分类号： A01N25/04 , A01N25/28 , A01N31/14 , A01N37/38 , A01N37/44 , A01N47/40 , A01N51/00 , A01N53/00 , A01N55/00 , A01P7/04
CPC分类号： A01N53/00 , A01N25/00 , A01N25/04 , A01N43/30 , A01N43/50 , A01N51/00 , A01N25/28
摘要： Use of formulations consisting of suspo-emuls ions comprising a microcapsule suspension, the microcapsules including at least one active ingredient selected from the pyrethroid and/or neonicotinoid classes, at least one synergistic agent, and an emulsion comprising at least an active ingredient of the above classes, and at least one synergistic agent, the microcapsules being formed of polyurea, obtainable by inter- facial polymerization of diphenylmethylen - 4, 4 ' -diisocyanate, optionally in admixture with polymethylenpolyphenylisocyanate, the formulations having a prolonged knockdown and killing effect, even of three months, even of six months or even of nine months, the suspo-emulsions comprising: component A) : microcapsules in suspension comprising inside the microcapsule at least one active ingredient, a synergistic agent, optionally a solvent, the total amount of these components being not higher than 50% by weight with respect to the weight of the suspension A), the complement to 100% by weight of component A) comprising the polymer of the micro-capsule shell, water and additives; component B) : emulsion comprising an amount of at least one active ingredient and one synergistic agent, the amount of active ingredient + synergistic agent being not higher than 50% by weight of the emulsion, of component B) constituted by water, additives, optionally solvents.
摘要翻译：包含由包含微胶囊悬浮液的悬浮乳液离子组成的制剂的使用，所述微胶囊包括至少一种选自拟除虫菊酯和/或新烟碱类的活性成分，至少一种协同剂，和至少包含上述活性成分的乳液类别和至少一种协同剂，微胶囊由聚脲形成，可通过二苯基亚甲基-4,4'-二异氰酸酯的面间聚合获得，任选与聚亚甲基聚苯基异氰酸酯混合，该制剂具有延长的杀伤和杀伤作用，甚至是三个月甚至六个月甚至九个月的悬浮乳液，包含：组分A）：悬浮液中的微胶囊，其包含至少一种活性成分，协同剂，任选的溶剂，微胶囊内的这些组分的总量相对于悬浮液A）的重量，不高于50重量％，补体至100重量％的组分A），其包含微胶囊壳的聚合物，水和添加剂; 组分B）：包含一定量的至少一种活性成分和一种协同剂的乳液，活性成分+协同剂的量不超过乳液的50重量％，组分B）由水，添加剂，任选地溶剂。

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