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    • 2. 发明申请
    • BIODIESEL-BASED EMULSION DEFOAMER AND METHOD FOR MAKING THE SAME
    • 基于生物物质的乳液除虫剂及其制备方法
    • WO2014179127A1
    • 2014-11-06
    • PCT/US2014/035091
    • 2014-04-23
    • ECOLAB USA INC.
    • FAN, YanruZHAO, Yulin
    • B01D19/02
    • B01D19/0404D21H17/74D21H21/12B01D19/0409
    • Disclosed are an oil-in-water emulsion defoamer and a preparation method thereof; said defoamer has an dispersed oil phase with a droplet size of 4 to 8 ?m, and a viscosity of 100 to 1000 cP, and is widely used for defoaming in paper coating and wet-end in a paper mill. A method for preparing an oil-in-water emulsion defoamer is also provided, said method comprising the steps of (i) adding 0.2 to 6 weight parts of an emulsifying agent to 30 to 60 weight parts of biodiesel, and mixing, then gradually adding 0.5 to 3 weight parts of hydrophobic fumed silica, and thoroughly stirring to disperse said silica, to obtain a mixture A; (ii) gradually adding 10 to 50 weight parts of water to 5 to 30 weight parts of a non-ionic surfactant, and stirring until uniform at a stirring rate adjusted according to the variation of the viscosity of the resulting mixture, to obtain a mixture B, in which said non-ionic surfactant has a cloud point of below 50C; and then (iii) gradually adding the mixture A to the mixture B, and stirring until uniform, to obtain said oil-in-water emulsion defoamer.
    • 本发明公开了一种水包油乳液消泡剂及其制备方法, 所述消泡剂具有液滴尺寸为4〜8μm的分散油相,粘度为100〜1000cP,广泛用于造纸厂的纸张涂布和湿式结晶中的消泡。 还提供了一种制备水包油乳液消泡剂的方法,所述方法包括以下步骤:(i)向30-60重量份生物柴油中加入0.2至6重量份的乳化剂,然后混合,然后逐渐加入 0.5〜3重量份疏水性热解法二氧化硅,充分搅拌分散二氧化硅,得到混合物A; (ii)向5〜30重量份的非离子表面活性剂中逐渐加入10〜50重量份的水,并搅拌直至根据所得混合物的粘度变化调节的搅拌速度均匀,得到混合物 B,其中所述非离子表面活性剂的浊点低于50℃; 然后(iii)将混合物A逐渐加入到混合物B中,并搅拌直到均匀,得到所述水包油乳液消泡剂。