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1. 发明申请

WO9102715A3 ULTRAVIOLET LIGHT-ABSORBING COMPOUNDS AND SUNSCREEN FORMULATIONS AND POLYMERIC MATERIALS CONTAINING SUCH COMPOUNDS OR RESIDUES THEREOF 审中-公开
标题翻译：超紫外线吸收化合物和含有这些化合物或其残基的SUNCREEN制剂和聚合物
公开(公告)号：WO9102715A3
公开(公告)日：1991-07-11
申请号：PCT/US9004573
申请日：1990-08-14
申请人： EASTMAN KODAK CO
发明人： KRUTAK JAMES JOHN , WEAVER MAX ALLEN , COATES CLARENCE ALVIN , HILBERT SAMUEL DAVID , OLDFIELD TERRY ANN , PARHAM WILLIAM WHITEFIELD , PRUETT WAYNE PAYTON
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00 , A61K7/42
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are certain poly-methine compounds having formula (I), wherein each R1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from -O- or -S-; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

2. 发明申请

WO8905832A3 CONDENSATION POLYMER CONTAINING THE RESIDUE OF A BENZODIOXYLMETHINE COMPOUND AND SHAPED ARTICLES PRODUCED THEREFROM 审中-公开
标题翻译：含有苯并二甲基甲基胺化合物残余物的凝聚聚合物及其制得的成型制品
公开(公告)号：WO8905832A3
公开(公告)日：1989-07-27
申请号：PCT/US8804554
申请日：1988-12-20
申请人： EASTMAN KODAK CO
发明人： WEAVER MAX ALLEN , PRUETT WAYNE PAYTON , HILBERT SAMUEL DAVID
IPC分类号： C08F299/04 , C08F283/01 , C08G63/54 , C08G63/685 , C08G63/688 , C08G64/00 , C08G64/04 , C08G63/62 , C08G63/68
CPC分类号： C08G63/6858 , C08G63/54 , C08G64/045
摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more benzodioxylmethine compounds having formula (I), wherein R1 is cyano, carboxy, alkenyloxycarbonyl or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; R2 is one of the groups specified for R1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or heterocyclic aryl radical; R3 is hydrogen or an unsubstitued or substituted alkyl, cycloalkyl or aryl radical; R4 is hydrogen, alkyl, alkoxy, or halogen; n is 1 or 2; and X is an unsubstituted or substituted methylene or ethylene radical; provided the benzodioxolylmethine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived, said benzodioxylmethine residue absorbing radiation in the range of about 250 nm to 390 nm and being nonextractable from said polymer and stable under polymer processing conditions. The benzodioxylmethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
摘要翻译：适用于模制成诸如食品容器，饮料瓶，固化结构塑料等的制品的组合物，其包含与其反应或在其中共聚一种或多种具有式（I）的一种或多种苯并二氧杂次甲基化合物的残余物的模塑级直链或不饱和聚酯或聚碳酸酯，其中 R1为氰基，羧基，烯氧基羰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; R2为R1或未取代或取代的芳基，氨基甲酰基，烷酰基，环烷酰基，芳酰基，烷基磺酰基，环烷基磺酰基，芳基磺酰基或杂环芳基指定的基团之一; R3是氢或未取代或取代的烷基，环烷基或芳基; R4是氢，烷基，烷氧基或卤素; n是1或2; X是未取代或取代的亚甲基或亚乙基; 条件是苯并间二氧杂环戊烯基甲炔化合物带有至少一个可与缩合聚合物衍生自其中的单体反应的取代基，所述苯并二氧杂次甲基胺残基吸收约250nm至390nm范围内的辐射并且不能从所述聚合物中得到并在聚合物下稳定加工条件。苯并二氧甲基甲炔残基作为聚合物链的组成部分存在于聚合物中并吸收约250至约390nm范围内的紫外辐射。残留物不能从聚合物中萃取出来，并且在制造和加工聚合物的条件下稳定。

3. 发明申请

WO8910349A3 NOVEL METHINE COMPOUNDS, POLYMERS CONTAINING THEM AND FORMED ARTICLES THEREFROM 审中-公开
标题翻译：新的甲基化合物，含有它们的聚合物和由其形成的制品
公开(公告)号：WO8910349A3
公开(公告)日：1989-11-30
申请号：PCT/US8901383
申请日：1989-04-05
申请人： EASTMAN KODAK CO
发明人： WEAVER MAX ALLEN , PRUETT WAYNE PAYTON , HILBERT SAMUEL DAVID
IPC分类号： C07C229/44 , C07C255/34 , C07C311/35 , C07C311/42 , C07C317/44 , C07C323/60 , C08G63/685 , C08G64/04 , C08K5/00 , C08K5/315 , C07C121/75 , C07C121/70 , C07D209/08 , C07D209/82 , C07D265/32 , C08G63/52 , C08G63/68
CPC分类号： C08K5/005 , C07C229/44 , C07C255/34 , C07C311/35 , C07C311/42 , C07C317/44 , C07C323/60 , C08G63/6858 , C08G64/045 , C08K5/315
摘要： A composition useful for incorporation into polymer compositions employed for food packaging or the like comprising a bis- or tris-methine compound having structural formula (I), wherein A is selected from the radicals (1), (2), (3), (4), (5), or (6), wherein R' and R'' are each selected from chlorine, bromine, fluorine, alkyl, alkoxy, aryl, aryloxy and arylthio; each n is independently 0, 1, 2; R1 is selected from a large variety of radicals such as cycloalkyl, phenyl, and straight or branched alkyl which may be substituted; R2 is alkylene or the like; R3, R4, and R5 are each selected from hydrogen and alkyl; and P and Q and P1 and Q1 are selected from cyano, carbalkoxy, carbaryloxy, carbaralkyloxy, or the like. The invention compositions are especially useful in combination with molding or fiber-grade condensation polymer; most preferably such polymer having copolymerized therein a total of from 1.0 to about 100,000 ppm, of the reactant residue moieties of one or more of such bis- or tris-methine compounds.
摘要翻译：（1），（2），（3），（3），（3），（3）或（3）的基团的双 - 或三 - 次甲基化合物的食品包装等用聚合物组合物中有用的组合物。（4），（5）或（6），其中R'和R“各自选自氯，溴，氟，烷基，烷氧基，芳基，芳氧基和芳硫基; 每个n独立地为0,1,2; R 1选自各种各样的基团，例如环烷基，苯基和可被取代的直链或支链烷基; R2是亚烷基等; R3，R4和R5各自选自氢和烷基; 并且P和Q以及P1和Q1选自氰基，烷氧羰基（carbalkoxy），羧甲氧基羰基氧基（carbaryloxy），carbaralkyloxy等。本发明组合物特别适用于与模制或纤维级缩聚物组合; 最优选这样的聚合物，其中共聚有总共1.0至约100,000ppm的一种或多种这样的双 - 或三 - 次甲基化合物的反应物残基部分。

4. 发明申请

WO8905832A2 CONDENSATION POLYMER CONTAINING THE RESIDUE OF A BENZODIOXYLMETHINE COMPOUND AND SHAPED ARTICLES PRODUCED THEREFROM 审中-公开
标题翻译：含有苯并咪唑化合物残留物的凝结聚合物及其生产的形状物品
公开(公告)号：WO8905832A2
公开(公告)日：1989-06-29
申请号：PCT/US8804554
申请日：1988-12-20
申请人： EASTMAN KODAK CO
发明人： WEAVER MAX ALLEN , PRUETT WAYNE PAYTON , HILBERT SAMUEL DAVID
IPC分类号： C08F299/04 , C08F283/01 , C08G63/54 , C08G63/685 , C08G63/688 , C08G64/00 , C08G64/04 , C08G63/62 , C08G63/68
CPC分类号： C08G63/6858 , C08G63/54 , C08G64/045
摘要： Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more benzodioxylmethine compounds having formula (I), wherein R1 is cyano, carboxy, alkenyloxycarbonyl or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; R2 is one of the groups specified for R1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or heterocyclic aryl radical; R3 is hydrogen or an unsubstitued or substituted alkyl, cycloalkyl or aryl radical; R4 is hydrogen, alkyl, alkoxy, or halogen; n is 1 or 2; and X is an unsubstituted or substituted methylene or ethylene radical; provided the benzodioxolylmethine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived, said benzodioxylmethine residue absorbing radiation in the range of about 250 nm to 390 nm and being nonextractable from said polymer and stable under polymer processing conditions. The benzodioxylmethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

5. 发明申请

WO8402136A3 POLYESTERS CONTAINING COPOLYMERIZED ANTHRAQUINONE COLORANT COMPOUNDS CONTAINING SULFONAMIDO GROUPS 审中-公开
标题翻译：含有磺酰胺基团的共聚合蒽醌颜料组合物的聚酯
公开(公告)号：WO8402136A3
公开(公告)日：1984-08-02
申请号：PCT/US8301834
申请日：1983-11-21
申请人： EASTMAN KODAK CO
发明人： DAVIS THOMAS GLENN , GILES RALPH RAE , WEAVER MAX ALLEN
IPC分类号： C08G63/46 , C08G63/52 , C08G63/68 , C08G63/688 , C08L67/00 , C08L67/02 , C09B1/00 , C09B69/10 , C09B69/00
CPC分类号： C08G63/6884 , C08G63/68
摘要： Colored polyesters having copolymerized therein anthraquinone derivative colorants containing one or more sulfonamido groups. The colored polymers are fast to light and the colorant moieties are not extractable therefrom, rendering from the colored polymers particularly suitable for use in food containers such as molded beverage bottles. The inherent viscosities of these polymers can be varied widely as is well known in the art for different applications. The copolymerizable colorants have the formula (I), wherein R1 and R2 are each hydrogen or 1-3 substituents independently selected from alkyl, alkoxy, and the like; and T represents 1-4 independently selected radicals of the formula (II), wherein R3 is hydrogen or 1-3 substituents such as alkyl, alkoxy and the like; Z is a divalent linking group such as -NH-, -S-, -O-, and alkoxycarbonyl; and Q is hydroxy, carboxy or alkoxycarbonyl.

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