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    • 4. 发明申请
    • THERMOFORMABLE PACKAGING FILM
    • 耐热包装膜
    • WO2002078885A1
    • 2002-10-10
    • PCT/US2002/010043
    • 2002-03-28
    • E.I. DU PONT DE NEMOURS AND COMPANY
    • GLICK, William, J.LEE, I-Hwa
    • B23B27/32
    • B32B27/08B32B27/18B32B27/32B32B2323/04B32B2439/80C08L23/04C08L23/08C08L23/0815C08L23/0876C08L2203/12C08L2314/06Y10T428/13Y10T428/1352Y10T428/1355Y10T428/1359Y10T428/1362Y10T428/1379Y10T428/31855Y10T428/31909Y10T428/31913Y10T428/31928Y10T428/31935C08L2666/04
    • This invention is directed to a thermoformable film comprising a composite structure of at least three layers firmly adhered to one another, a top and bottom layer and an inner layer;wherein the top and bottom layer of the composite structure comprise a film layer of an ethylene vinyl acetate copolymer comprising 1 to 25% by weight, based on the weight of the copolymer, of a polymerized vinyl acetate and 75 to 99% by weight, based on the weight of the copolymer, of polymerized ethylene and the inner layer of the composite structure comprises a film of a polymer blend of the following: (a) 40 to 95% by weight, based on the weight of the polymer blend, of an ethylene based copolymer comprises repeating polymerized units of (1) at least 50% by weight, based on the weight of the copolymer, of ethylene,(2) 1 to 30% by weight, based on the weight of the copolymer, of acrylic acid or methacrylic acid; and (3) up to 40% by weight, based on the weight of the copolymer, of an alkyl acrylate or an alkyl methacrylate,wherein the copolymer has 5 to 100% of the acid groups neutralized with metal ion selected from the following group: zinc, magnesium, sodium and lithium; and (b) 5 to 60% by weight, based on the weight of the polymer blend, of a metallocene catalyzed polyethylene; other thermoformable film constructions, such as, a 2 layer construction and constructions greater than 3 layers, such as 5 layers, and a mono layer of the film of a blend of the ethylene based copolymer and the metallocene catalyzed polyethylene also are part of this invention.
    • 本发明涉及一种可热成型膜,其包含至少三层彼此牢固地粘合的复合结构,顶层和底层以及内层;其中复合结构的顶层和底层包括乙烯 乙酸乙烯酯共聚物,基于共聚物的重量,含有1至25重量%的聚合乙酸乙烯酯和基于共聚物重量的75至99重量%的聚合乙烯和复合材料的内层 结构包括以下聚合物共混物的膜:(a)40至95重量%,基于聚合物共混物的重量,基于乙烯的共聚物包含重复的聚合单元(1)至少50重量% 基于共聚物的重量计,乙烯,(2)1至30重量%,基于共聚物的重量,丙烯酸或甲基丙烯酸; 和(3)至多40重量%,基于共聚物的重量,丙烯酸烷基酯或甲基丙烯酸烷基酯,其中所述共聚物具有5至100%的酸金属中和的金属离子,所述金属离子选自以下组: 锌,镁,钠和锂; 和(b)5-60重量%,基于聚合物共混物的重量,茂金属催化的聚乙烯; 其它可热成膜的构造,例如2层结构和大于3层的构造,例如5层,以及乙烯基共聚物和茂金属催化聚乙烯的共混物膜的单层也是本发明的一部分 。