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1. 发明申请

WO2008008351A2 CATALYTIC ISOMERIZATION BETWEEN E AND Z ISOMERS OF 1,2,3,3,3-PENTAFLUOROPROPENE 审中-公开
标题翻译： 1,2,3,3,3-三氟乙烯的E和Z异构体之间的催化异构体
公开(公告)号：WO2008008351A2
公开(公告)日：2008-01-17
申请号：PCT/US2007/015752
申请日：2007-07-11
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , NAPPA, Mario, Joseph , TOTON, Donald, J. , RAO, Velliyur, Nott, Mallikarjuna
发明人： NAPPA, Mario, Joseph , TOTON, Donald, J. , RAO, Velliyur, Nott, Mallikarjuna
IPC分类号： C07C17/358 , C07C21/18
CPC分类号： B01J27/12 , B01J27/135 , C07C17/358 , C07C21/18
摘要： A process is disclosed to increase the Z/E ratio of 1,2,3,3,3 pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3 pentafluoropropene with a catalyst on AlF 3 or carbon, wherein the catalyst is selected from the group consisting of SbCl w F 5-w , TiCl x F 4-x , SnCl y F 4-y and TaCl z F 5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3 pentafluoropropene is increased relative to the Z/E ratio of 1,2,3,3,3 pentafluoropropene in the starting material. A process is also disclosed to decrease the Z/E ratio of 1,2,3,3,3 pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3 pentafluoropropene with a catalyst on AlF 3 or carbon, wherein the catalyst is selected from the group consisting of SbCl w F 5-w , TiCl x F 4-x , SnCl y F 4-y and TaCl z F 5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3 pentafluoropropene is decreased relative to the Z/E ratio of 1,2,3,3,3 pentafluoropropene in the starting material.
摘要翻译：公开了提高1,2,3,3,3-五氟丙烯的Z / E比的方法。该方法包括使包含1,2,3,3,3-五氟丙烯的起始材料与AlF 3或碳上的催化剂接触，其中催化剂选自SbCl 3， 5-w，5-x，3-x，4-x，3，...，3，其中w为0〜4，x为0〜3，y为0〜3，z为0〜3，z为0〜为0〜4，得到其中1,2,3,3,3-五氟丙烯的Z / E比相对于起始时的1,2,3,3,3-五氟丙烯的Z / E比增加的产物材料。还公开了降低1,2,3,3,3-五氟丙烯的Z / E比的方法。该方法包括使包含1,2,3,3,3-五氟丙烯的起始材料与AlF 3或碳上的催化剂接触，其中催化剂选自SbCl 3， 5-w，5-x，3-x，4-x，3，...，3，其中w为0〜4，x为0〜3，y为0〜3，z为0〜3，z为0〜为0〜4，得到其中1,2,3,3,3-五氟丙烯的Z / E比相对于起始时的1,2,3,3,3-五氟丙烯的Z / E比降低的产物材料。

2. 发明申请

WO2008024508A1 PROCESSES FOR SEPARATION OF FLUOROOLEFINS FROM HYDROGEN FLUORIDE BY AZEOTROPIC DISTILLATION 审中-公开
标题翻译：通过AZOOTROPIC蒸馏从氟化氢中分离氟化物的方法
公开(公告)号：WO2008024508A1
公开(公告)日：2008-02-28
申请号：PCT/US2007/018837
申请日：2007-08-24
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , KNAPP, Jeffrey, P. , MAHLER, Barry, Asher , TOTON, Donald, J.
发明人： KNAPP, Jeffrey, P. , MAHLER, Barry, Asher , TOTON, Donald, J.
IPC分类号： C07C17/38 , C07C17/383 , C07C17/386
CPC分类号： C07C17/38 , C01B7/196 , C07C17/25 , C07C17/383 , C07C17/386 , C07C21/18 , C07C21/185 , C07C19/08
摘要： The present disclosure relates to a process for separating a fluoroolefin from a mixture comprising hydrogen fluoride and fluoroolefin, comprising azeotropic distillation both with and without an entrainer. In particular are disclosed processes for separating any of HFC-1225ye, HFC-1234ze, HFC-1234yf or HFC-1243zf from HF.
摘要翻译：本公开涉及一种从包含氟化氢和氟代烯烃的混合物中分离氟烯烃的方法，包括具有和不具有夹带剂的共沸蒸馏。特别公开了从HF分离HFC-1225ye，HFC-1234ze，HFC-1234yf或HFC-1243zf中的任何一种的方法。

3. 发明申请

WO2003037832A3 VAPOR PHASE PRODUCTION OF 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE FROM HYDROGEN FLUORIDE AND HEXAFLUOROPROPYLENE 审中-公开
公开(公告)号：WO2003037832A3
公开(公告)日：2003-05-08
申请号：PCT/US2002/035061
申请日：2002-10-31
申请人： E. I. DU PONT DE NEMOURS AND COMPANY
发明人： MILLER, Ralph, Newton , NAPPA, Mario, J. , TOTON, Donald, J.
IPC分类号： C07C17/00
摘要： A process for the production of HFC-227ea from HF and HFP is provided. This process takes advantage of an azeotropic composition of HF and HFC-227ea in order to produce HFC-227ea essentially free of HF and recycle unreacted HF back to the reactor. The recycle of said azeotropic composition, also allows the use of HFC-227ea as a diluent to aid in control of reactor temperature for a highly exothermic reaction.

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