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1. 发明申请

WO2005087876A1 CURABLE LIQUID COMPOSITION, CURED FILM, AND ANTISTATIC LAMINATE 审中-公开
标题翻译：可固化液体组合物，固化膜和抗静电层压板
公开(公告)号：WO2005087876A1
公开(公告)日：2005-09-22
申请号：PCT/NL2005/000197
申请日：2005-03-15
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , ITAI, Shingo , YAMAGUCHI, Yoshikazu , KOMIYA, Zen
发明人： ITAI, Shingo , YAMAGUCHI, Yoshikazu , KOMIYA, Zen
IPC分类号： C09D5/00
CPC分类号： C08K3/22 , C08F222/1006 , C08K3/20 , C08K9/06 , C09D4/00 , C09D5/006 , C09D5/24 , C09D7/62 , Y10T428/265 , Y10T428/31931
摘要： The object of the invention is to provide a curate liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an antistatic laminate. This object is achieved by providing a curate liquid composition comprising the following components (A), (B), (C), and (D): (A) particles comprising an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a silicon-containing surfactant, and (D) a solvent.
摘要翻译：本发明的目的是提供一种在储存稳定性和固化性方面优异且能够形成在各种基材表面上具有优异的抗静电性，硬度，耐擦伤性和透明性的涂膜（膜）的凝固液组合物，固化膜的组合物，以及抗静电层压材料。该目的通过提供一种包含以下组分（A），（B），（C）和（D））的凝固液组合物来实现：（A）包含选自铟的至少一种元素的氧化物的颗粒，锑，锌和锡作为主要成分，（B）分子中具有2个以上聚合性不饱和基团的化合物，（C）含硅表面活性剂和（D）溶剂。

2. 发明申请

WO2005090507A1 CURABLE LIQUID RESIN ADHESIVE COMPOSITION 审中-公开
标题翻译：可固化液体粘合剂组合物
公开(公告)号：WO2005090507A1
公开(公告)日：2005-09-29
申请号：PCT/NL2005/000188
申请日：2005-03-14
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , YAMAMOTO, Keiichi , TONSHO, Shinji , KOMIYA, Zen
发明人： YAMAMOTO, Keiichi , TONSHO, Shinji , KOMIYA, Zen
IPC分类号： C09J151/08
CPC分类号： C08G18/672 , C08K5/005 , C08K5/13 , C08K5/526 , C08L2666/28 , C09J175/16 , C08G18/48 , C08L75/14
摘要： To provide a curable liquid resin adhesive composition, which exhibits excellent adhesiveness and shows only a small degree of yellowing. A curable liquid resin adhesive composition, comprising (A) a urethane (met) acrylate obtained from at least one diol component selected from the group consisting of polypropylene glycol, polybutylene glycol, a copolymer of 1, 2-butylene oxide and ethylene oxide, and a copolymer of propylene oxide and ethylene oxide, a diisocyanate, and a hydroxyl group-containing (meth) acrylate, (B) a radically polymerizable compound, (C) a compound including a phosphite group and a phenolic hydroxyl group, and (D) a phenolic compound including a partial structure shown by the formula (1). Formula (1) wherein R 1 represents a hydrocarbon group having 1 to 8 carbon atoms.
摘要翻译：为了提供显示出优异的粘附性并且仅显示少量黄化的可固化液体树脂粘合剂组合物。一种可固化液体树脂粘合剂组合物，其包含（A）由至少一种选自聚丙二醇，聚丁二醇，1,2-环氧丁烷和环氧乙烷的共聚物中的至少一种二醇组分得到的聚氨酯（met）丙烯酸酯和环氧丙烷与环氧乙烷的共聚物，二异氰酸酯，含羟基的（甲基）丙烯酸酯，（B）自由基聚合性化合物，（C）含有亚磷酸酯基和酚性羟基的化合物，（D）包括由式（1）表示的部分结构的酚类化合物。式（1）其中R 1表示具有1至8个碳原子的烃基。

3. 发明申请

WO2005095527A1 PHOTOCURABLE COMPOSITION AND OPTICAL PART 审中-公开
标题翻译：光电组合物和光学部件
公开(公告)号：WO2005095527A1
公开(公告)日：2005-10-13
申请号：PCT/NL2005/000195
申请日：2005-03-15
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , FUTAMI, Satochi , KOMIYA, Zen
发明人： FUTAMI, Satochi , KOMIYA, Zen
IPC分类号： C09D4/00
CPC分类号： C08F220/18 , C08F220/22 , C09D4/00
摘要： Subject : To provide a photocurable composition capable of producing a cured product excelling in heat resistance, showing only a small amount of deformation, and producing cured products particularly useful as optical parts. Means for the Solution : A photocurable composition comprising the following components (A)-(D): (A) at least one of the (meth)acrylates having the structures shown by the formulas (1) and (2) (excluding the following component (C)), Chemical Formula (1), Chemical Formula (2) wherein R 1 represents a hydrogen atom or a halogen atom excluding a fluorine atom, R 2 is a hydrogen atom, a halogen atom excluding a fluorine atom, Ph-C(CH 3 ) 2 -, Ph-, or an alkyl group having 1-20 carbon atoms, and R 3 represents -CH 2 -, -S-, or -C(CH 3 ) 2 -, (B) a (meth)acrylate having three or more functional groups, (C) . a monofunctional monomer of which the homopolymer has a Tg of 150 ° C or more, and (D) a radical photoinitiator, wherein 5-50 wt% of the total acrylic components in the composition is a methacrylate compound and the component (C) is contained in an amount of 4-40 wt%.
摘要翻译：题目：提供能够生产耐热性优异的固化产物的光固化性组合物，仅显示少量变形，并且生产特别用作光学部件的固化产物。解决方案的方法：一种可光固化组合物，其包含以下组分（A） - （D）：（A）至少一种具有式（1）和（2）所示结构的（甲基）丙烯酸酯（不包括以下组分（C）），化学式（1），化学式（2）其中R 1表示氢原子或不包括氟原子的卤素原子，R 2是氢原子，不包括氟的卤素原子原子，Ph-C（CH 3）2 - ，Ph-或具有1-20个碳原子的烷基，R 3表示-CH 2 - ， - S-或-C（CH 3）2 - ，（B ）具有三个或更多个官能团的（甲基）丙烯酸酯，（C）单体官能单体，其均聚物的Tg为150℃以上，和（D）自由基光引发剂，其中5-50重量％的组合物中的总丙烯酸组分是甲基丙烯酸酯化合物，并且组分（C）的含量为4-40重量％。

4. 发明申请

WO2005087886A1 RADIATION-CURABLE COMPOSITION 审中-公开
标题翻译：辐射可固化组合物
公开(公告)号：WO2005087886A1
公开(公告)日：2005-09-22
申请号：PCT/NL2005/000185
申请日：2005-03-11
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , YAMAMOTO, Keiichi , TONSHO, Shinji , SHIGEMOTO, Takeo , KOMIYA, Zen
发明人： YAMAMOTO, Keiichi , TONSHO, Shinji , SHIGEMOTO, Takeo , KOMIYA, Zen
IPC分类号： C09J4/00
CPC分类号： C08G18/672 , C09J175/16 , C08G18/48
摘要： Subject: to provide a radiation-curable resin composition exhibiting excellent bond strength for PET, TAC, Arton, and the like, excellent processability, heat resistance, and water resistance, and high-speed curability. A radiation-curable resin composition, comprising: (A) 30-70 wt% of a urethane (meth) acrylate with a number average molecular weight of 10,000-40,000; and (B) 0.1-70 wt% of an ethylenically unsaturated monomer including a cyclic ether.
摘要翻译：题目：提供对PET，TAC，Arton等具有优异的粘合强度的可辐射固化树脂组合物，加工性，耐热性和耐水性优异，以及高速固化性。一种辐射固化树脂组合物，其包含：（A）30-70重量％的数均分子量为10,000-40,000的氨基甲酸酯（甲基）丙烯酸酯; 和（B）0.1-70重量％的包含环醚的烯属不饱和单体。

5. 发明申请

WO2003080755A3 RADIATION-CURABLE RESIN COMPOSITION FOR ADHESIVES 审中-公开
公开(公告)号：WO2003080755A3
公开(公告)日：2003-10-02
申请号：PCT/NL2003/000232
申请日：2003-03-27
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , YOSHIZAWA, Junji , TAKAHASHI, Atsuya , MASE, Masahito , KOMIYA, Zen
发明人： YOSHIZAWA, Junji , TAKAHASHI, Atsuya , MASE, Masahito , KOMIYA, Zen
IPC分类号： C09J4/06
摘要： A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt% or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.

6. 发明申请

WO2003080755A2 RADIATION-CURABLE RESIN COMPOSITION FOR ADHESIVES 审中-公开
标题翻译：用于胶粘剂的可辐射固化树脂组合物
公开(公告)号：WO2003080755A2
公开(公告)日：2003-10-02
申请号：PCT/NL2003/000232
申请日：2003-03-27
申请人： DSM N.V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , YOSHIZAWA, Junji , TAKAHASHI, Atsuya , MASE, Masahito , KOMIYA, Zen
发明人： YOSHIZAWA, Junji , TAKAHASHI, Atsuya , MASE, Masahito , KOMIYA, Zen
IPC分类号： C09J4/06
CPC分类号： C08F290/061 , C08F289/00 , C08F290/06 , C09J4/06
摘要： A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt% or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.
摘要翻译：一种用于粘合剂的辐射固化树脂组合物，其包含（A）具有羟基的双酚型环氧（甲基）丙烯酸酯，（B）具有脂肪族环状结构的多官能（甲基）丙烯酸酯或除该成分 A）和（C）光引发剂，其中组分（A）的含量和组分（B）中组分的含量分别为30重量％或更多。本发明的粘合剂用辐射固化型树脂组合物对银，硅化合物和铝具有优异的粘合性，优异的耐湿热性和快速固化性，特别是在盘的边缘，因此在制造中非常有用与常规粘合剂相比。

7. 发明申请

WO2005092967A1 CURABLE LIQUID COMPOSITION, CURED FILM, AND ANTISTATIC LAMINATE 审中-公开
标题翻译：可固化液体组合物，固化膜和抗静电层压板
公开(公告)号：WO2005092967A1
公开(公告)日：2005-10-06
申请号：PCT/NL2005/000228
申请日：2005-03-25
申请人： DSM IP ASSETS B. V. , JSR CORPORATION , JAPAN FINE COATINGS CO., LTD. , SUZUKI, Yasunobu , IINUMA, Ryousuke , SHINOHARA, Noriyasu , KOMIYA, Zen
发明人： SUZUKI, Yasunobu , IINUMA, Ryousuke , SHINOHARA, Noriyasu , KOMIYA, Zen
IPC分类号： C08K9/04
CPC分类号： C08F292/00 , Y10T428/25 , Y10T428/31551
摘要： To provide a curable composition having excellent applicability and capable of forming a coat (film) having high hardness and high refractive index and excelling in scratch resistance and adhesion to a substrate and a low-refractive-index layer on the surface of various types of substrates, a cured product of the curable composition, and a laminate having a low reflectance and excelling in antistatic property. A curate e composition comprising particles (A) prepared by bonding oxide particles of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium with an organic compound having a polymerizable unsaturated group, a compound (B) having a urethane bond and two or more polymerizable unsaturated groups in the molecule, and a photoinitiator (C).
摘要翻译：为了提供具有优异适用性并且能够形成具有高硬度和高折射率并且耐划伤性优异且对基板和各种类型基材表面上的低折射率层的粘附性的涂层（膜）的可固化组合物，可固化组合物的固化产物和具有低反射率和优异抗静电性能的层压材料。包含通过将选自硅，铝，锆，钛，锌，锗，铟，锡，锑和铈中的至少一种元素的氧化物颗粒与具有有机化合物的有机化合物结合而制备的颗粒（A）可聚合不饱和基团，具有氨基甲酸酯键的化合物（B）和分子中的两个或更多个可聚合不饱和基团和光引发剂（C）。

8. 发明申请

WO2005087845A1 CURABLE LIQUID RESIN COMPOSITION 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：WO2005087845A1
公开(公告)日：2005-09-22
申请号：PCT/NL2005/000196
申请日：2005-03-15
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , OHARA, Hiroki , FURUKAWA, Tsuyoshi? , SHIGEMOTO, Takeo , KOMIYA, Zen
发明人： OHARA, Hiroki , FURUKAWA, Tsuyoshi? , SHIGEMOTO, Takeo , KOMIYA, Zen
IPC分类号： C08G77/455
CPC分类号： C08G18/672 , C03C25/106 , C08L83/12 , C09D175/16 , C08G18/48 , C08L83/00
摘要： The invention aims to provide a curable liquid resin composition which produces a cured product having excellent surface slip characteristics and printability and has excellent liquid resin stability. This problem is solved by providing a curable liquid resin composition, comprising a silicone including an alkyl-modified siloxane unit and a polyether-modified siloxane unit.
摘要翻译：本发明的目的是提供一种固化液体树脂组合物，该组合物产生具有优异的表面滑动特性和可印刷性的固化产物，并且具有优异的液体树脂稳该问题通过提供一种可固化的液体树脂组合物来解决，该组合物包含含有烷基改性的硅氧烷单元和聚醚改性的硅氧烷单元的硅氧烷。

9. 发明申请

WO2005090488A1 CURABLE LIQUID RESIN COMPOSITION 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：WO2005090488A1
公开(公告)日：2005-09-29
申请号：PCT/NL2005/000220
申请日：2005-03-23
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , KOMIYA, Zen , BUIJSEN, Paulus, Franciscus, Anna , STEELMAN, Paulus, Antonius, Maria
发明人： SUGIMOTO, Masanobu , SHIGEMOTO, Takeo , KOMIYA, Zen , BUIJSEN, Paulus, Franciscus, Anna , STEELMAN, Paulus, Antonius, Maria
IPC分类号： C09D4/00
CPC分类号： C09D4/00 , C09D4/06
摘要： The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): 0.5-50 wt% of a urethane (meth)acrylate oligomer obtained from a polyol (a) having a branched structure comprising at least one branch point and at least three molecular chains extending from that branch point, said molecular chains having a molecular weight of 200 g/mol or more, including a hydroxyl group at the terminal of at least two molecular chains extending from the branch point, a polyisocyanate (b), and a hydroxyl group-containing (meth)acrylate (c); (B) 5-90 wt% of a polymerizable organic compound; and (C) 0.1-10 wt% of a polymerization initiator, wherein the cured product has a Young's modulus of 350 MPa or more at 23 ° C.
摘要翻译：本发明涉及一种包含以下组分（A），（B）和（C）的可固化液体树脂组合物：0.5-50重量％由具有支化结构的多元醇（a）得到的聚氨酯（甲基）丙烯酸酯低聚物包括至少一个分支点和从该分支点延伸的至少三个分子链，所述分子链的分子量为200g / mol以上，包括在从分支延伸的至少两个分子链末端的羟基点，多异氰酸酯（b）和含羟基的（甲基）丙烯酸酯（c）; （B）5-90重量％的可聚合有机化合物; 和（C）0.1-10重量％的聚合引发剂，其中固化产物在23℃下的杨氏模量为350MPa或更高。

10. 发明申请

WO2005087874A1 CURABLE LIQUID RESIN COMPOSITION 审中-公开
标题翻译：可固化液体树脂组合物
公开(公告)号：WO2005087874A1
公开(公告)日：2005-09-22
申请号：PCT/NL2005/000194
申请日：2005-03-15
申请人： DSM IP ASSETS B.V. , JSR CORPORATION , YAMAGUCHI, Hiroshi , KAMO, Satoshi , SHIGEMOTO, Takeo , KOMIYA, Zen
发明人： YAMAGUCHI, Hiroshi , KAMO, Satoshi , SHIGEMOTO, Takeo , KOMIYA, Zen
IPC分类号： C09D4/00
CPC分类号： C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要： The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH 2 =CR 1 COOR 2 (1) wherein R 1 represents a hydrogen atom or a methyl group and R 2 represents a monovalent organic group, 40 wt% or more of the total amount of the component (B) being a monomer in which the R 2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R 2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as "nonpolar (meth)acrylate containing monomer", and (C) a polymerization initiator.
摘要翻译：本发明涉及一种包含以下组分（A），（B）和（C）的可固化液体树脂组合物：（A）氨基甲酸酯（甲基）丙烯酸酯低聚物，（B）由下式（1），CH 2 = CR 1 COOR 2（1）其中R 1表示氢原子或甲基，R 2表示一价有机基团，40重量％以上的组分（B）为式（1）中的R 2为非极性有机基团的单体，式（1）中的R 2为基团的成分（B）中的单体为非极性有机基团以下称为“非极性（甲基）丙烯酸酯单体”）和（C）聚合引发剂。

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