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    • 2. 发明申请
    • ADHESION PROMOTER SYSTEM, AND METHOD OF PRODUCING THE SAME
    • 粘合促进剂系统及其生产方法
    • WO2011142949A4
    • 2012-01-12
    • PCT/US2011033249
    • 2011-04-20
    • DOW GLOBAL TECHNOLOGIES LLCHOFMANN SANDRADIEHL CHARLES FMALOTKY DAVID LREAD MICHAEL D
    • HOFMANN SANDRADIEHL CHARLES FMALOTKY DAVID LREAD MICHAEL D
    • C08L23/14C09J123/14
    • C08L23/142B32B7/12B32B27/20B32B2255/26B32B2307/704B32B2419/06B32B2457/00B32B2479/00B32B2605/003B32B2605/08B32B2605/12C08F285/00C08K5/0008C08L51/00C08L51/06C08L2666/24C09J123/142Y10T428/31938C08F222/06
    • The instant invention is an adhesion promoter system, and method of producing the same. The adhesion promoter system comprises an aqueous dispersion comprising the melt kneading product of: (a) at least 60 percent by weight of a base polymer, based on the total weight of the solid content, wherein said base polymer comprises a propylene/ethylene copolymer composition, wherein said propylene/ethylene copolymer has a crystallinity in the range of from 1 percent by weight to 30 percent by weight, a heat of fusion in the range of from 2 Joules/gram to 50 Joules/gram), and a DSC melting point in the range of 25° C to 110° C; (b) from 0.5 to less than 30 percent by weight of a functionalized polymer composition, based on the total weight of the solid content, wherein said functionalized polymer composition comprises homopolymers of propylene or copolymers of propylene with hexene, octene and/or other like alpha-olefins, the homopolymers or copolymers having a single unsaturation, a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone, where the succinic anhydride substitution ranges from about 5 to about 45 weight percent of functionalized polymer composition; (c) from 0.1 to less than 20 percent by weight of a stabilizing agent, based on the total weight of the solid content; and (d) in the presence of water and optionally one or more neutralizing agents, for example, at a temperature in the range of 25° C to 200° C.
    • 本发明是一种粘合促进剂体系及其制造方法。 粘合促进剂体系包含水分散体,其包含熔融捏合产物,该熔融捏合产物为:(a)至少60重量%的基础聚合物,基于固体含量的总重量,其中所述基础聚合物包含丙烯/乙烯共聚物组合物 ,其中所述丙烯/乙烯共聚物的结晶度为1重量%至30重量%,熔融热为2焦耳/克至50焦耳/克)和DSC熔点 在25℃至110℃的范围内; (b)官能化聚合物组合物的0.5至少于30重量%,基于固体含量的总重量,其中所述官能化聚合物组合物包含丙烯的均聚物或丙烯与己烯,辛烯和/或其它类似物的共聚物 α-烯烃,具有单一不饱和键的均聚物或共聚物,末端琥珀酸酐部分和在聚丙烯主链上的另外的琥珀酸酐取代,其中琥珀酸酐取代范围为约5至约45重量%的官能化聚合物组合物; (c)基于固体含量的总重量,0.1至小于20重量%的稳定剂; 和(d)在水和任选的一种或多种中和剂的存在下,例如在25℃至200℃的温度范围内。
    • 4. 发明申请
    • ADHESION PROMOTER SYSTEM, AND METHOD OF PRODUCING THE SAME
    • 粘合促进剂系统及其生产方法
    • WO2011142947A4
    • 2011-12-29
    • PCT/US2011033238
    • 2011-04-20
    • DOW GLOBAL TECHNOLOGIES LLCMALOTKY DAVID LHOFMANN SANDRADIEHL CHARLES FREAD MICHAEL DBATISTINI ANTONIOSILVIS H CRAIGBETTE CRISTIANO
    • MALOTKY DAVID LHOFMANN SANDRADIEHL CHARLES FREAD MICHAEL DBATISTINI ANTONIOSILVIS H CRAIGBETTE CRISTIANO
    • C08L51/00C09J151/00
    • C08L51/00C08F2438/02C08L51/003C08L2205/02Y10T428/31938C08L2666/24
    • The instant invention is an adhesion promoter system, and method of producing the same. The adhesion promoter system according to the present invention comprises an aqueous dispersion comprising the melt kneading product of: (a) at least 60 percent by weight of a first functionalized polyolefin, based on the total weight of the solid content; (b) optionally from 0.5 to less than 40 percent by weight of a second functionalized polyolefin, based on the total weight of the solid content, wherein said second functionalized polyolefin comprises homopolymers of propylene or copolymers of propylene with hexene, octene and/or other like alpha-olefins, the homopolymers or copolymers having a single unsaturation, a terminal succinic anhydride moiety, and additional succinic anhydride substitutions on the polypropylene backbone, where the succinic anhydride substitution ranges from about 5 to about 45 weight percent of second functionalized polyolefin; (c) from 0.1 to less than 20 percent by weight of a stabilizing agent, based on the total weight of the solid content; and (d) in the presence of water and optionally one or more neutralizing agents, for example, at a temperature in the range of 25° C to 200° C.
    • 本发明是一种粘合促进剂体系及其制造方法。 根据本发明的粘合促进剂体系包含水分散体,其包含熔融捏合产物,其基于固体含量的总重量:(a)至少60重量%的第一官能化聚烯烃; (b)基于固体含量的总重量,任选地0.5至小于40重量%的第二官能化聚烯烃,其中所述第二官能化聚烯烃包括丙烯均聚物或丙烯与己烯,辛烯和/或其它物质的共聚物 类似α-烯烃,具有单一不饱和键的均聚物或共聚物,末端琥珀酸酐部分和在聚丙烯主链上的另外的琥珀酸酐取代基,其中琥珀酸酐取代为约5至约45重量%的第二官能化聚烯烃; (c)基于固体含量的总重量,0.1至小于20重量%的稳定剂; 和(d)在水和任选的一种或多种中和剂的存在下,例如在25℃至200℃的温度范围内。
    • 7. 发明申请
    • METHOD TO PRODUCE FUNCTIONALIZED, LOW VISCOSITY ETHYLENE-BASED POLYMERS
    • 生产功能化的低粘度乙烯基聚合物的方法
    • WO2015102886A3
    • 2015-10-08
    • PCT/US2014070647
    • 2014-12-16
    • DOW GLOBAL TECHNOLOGIES LLC
    • READ MICHAEL DBAWISKAR SANTOSH S
    • C08F8/00C08F10/02C08F222/06C08F255/02C08K5/00C08K5/14C08L23/04C08L23/08C08L23/26
    • C08F255/02C08K5/092C08K5/14C08F222/06C08L23/08
    • The invention provides a process to form a "functionalized ethylene-based polymer" from an ethylene-based polymer and at least one polar compound, said process comprising thermally treating a composition comprising the ethylene-based polymer, the at least one polar compound, and at least one peroxide, in at least one extruder comprising at least one barrel, to form a polymer melt; and wherein the at least one peroxide has a half life, at the maximum barrel temperature of the at least one extruder, of less than of the minimum residence time of the polymer melt in the at least one extruder. The invention further provides a composition comprising at least the following: a) an ethylene-based polymer comprising a melt viscosity, at 350°F (177°C), less than 50.000 cP, and b) at least one peroxide comprising a half-life from 0.10 to 2.00 minutes, at a temperature from 160°C to 190°C.
    • 本发明提供由乙烯基聚合物和至少一种极性化合物形成“官能化的基于乙烯的聚合物”的方法,所述方法包括热处理包含基于乙烯的聚合物,至少一种极性化合物和 至少一种过氧化物在至少一个包含至少一个桶的挤出机中混合以形成聚合物熔体; 并且其中所述至少一种过氧化物在所述至少一个挤出机的最大机筒温度下具有小于所述至少一个挤出机中聚合物熔体的最小停留时间的半衰期。 本发明进一步提供一种组合物,其至少包含以下组分:a)在350°F(177℃)下熔体粘度小于50,000cP的基于乙烯的聚合物,和b)至少一种含有半衰期 寿命从0.10到2.00分钟,温度从160°C到190°C。