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    • 2. 发明申请
    • COMPOSITE POLYAMIDE MEMBRANE POST-TREATED WITH NITROUS ACID
    • 复合聚酰胺膜后处理硝酸
    • WO2015167759A1
    • 2015-11-05
    • PCT/US2015/024617
    • 2015-04-07
    • DOW GLOBAL TECHNOLOGIES LLC
    • PAUL, MouROY, AbhishekTOMLINSON, Ian A.JANSMA, Matthew J.
    • B01D67/00B01D69/12B01D71/56
    • B01D67/0093B01D69/125B01D71/56
    • A method for making a composite polyamide membrane comprising a porous support and a polyamide layer, including the steps of: i) applying a polar solution comprising a polyiunctional amine monomer and a non-polar solution comprising a polyiunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a polyamide layer; and ii) exposing the thin film polyamide layer to nitrous acid; wherein the method is characterized by at least one of: conducting the interfacial polymerization of step i) in the presence of a subject amine- reactive compound, or applying a subject amine-reactive compound to the interfacially polymerized polyamide layer prior to step ii), wherein the subject amine-reactive compound is different from the polyiunctional acyl halide and polyiunctional amine monomers and is represented by the following formula:
    • 一种制备包括多孔载体和聚酰胺层的复合聚酰胺膜的方法,包括以下步骤:i)将包含多官能胺单体的极性溶液和包含多官能酰卤单体的非极性溶液施加到 多孔载体和界面聚合单体以形成聚酰胺层; 和ii)将薄膜聚酰胺层暴露于亚硝酸; 其特征在于以下至少一个:在主题胺反应性化合物的存在下进行步骤i)的界面聚合,或在步骤ii)之前将主题胺反应性化合物施加到界面聚合的聚酰胺层上, 其中主题胺反应性化合物不同于多官能酰基卤和多官能胺单体,并由下式表示: