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    • 10. 发明申请
    • PROCESS FOR MAKING HIGH PRESSURE FREE RADICAL ETHYLENE COPOLYMERS
    • 制备高压自由基乙烯共聚物的方法
    • WO2017223467A1
    • 2017-12-28
    • PCT/US2017/039026
    • 2017-06-23
    • DOW GLOBAL TECHNOLOGIES LLC
    • BERBEE, Otto J.HINRICHS, StefanBROWN, Hayley A.CHAUDHARY, Bharat I.OSBY, John O.KARJALA, Teresa P.
    • C08F2/00C08F210/02
    • A high pressure polymerization process to form an ethylene-based polymer, the process comprising at least the following step: polymerizing a reaction mixture comprising ethylene and at least one comonomer, using a reactor system comprising a reactor configuration, and the following: (A) at least two reaction zones, a zone (reaction zone 1) and an ith zone (reaction zone i where i ≥ 2), (B) at least two ethylene-based feed streams, each comprising a percentage of the total make-up ethylene fed to the polymerization process, and wherein a first stream is sent to reaction zone 1 and a second stream is sent to reaction zone i; (C) a control system to control the percentage of the total make-up ethylene in the stream sent to reaction zone 1, and the percentage of the total make-up ethylene in the stream sent to reaction zone i, and wherein the ratio (Q) of the molar concentration of the at least one comonomer fed to the first reaction zone, to the molar concentration of comonomer in the sum of all ethylene-based feeds to the reactor configuration, meets the following Equation 1: 0.231n(rl) - 2.16≤ Q ≤ -0.251n(rl) + 2.15 (Equation 1); and wherein the comonomer has a reactivity ratio (rl) as follow: 0.3 ≤ rl ≤ 5.0, and a boiling point (1 atm) ≤ 150°C.
    • 一种形成基于乙烯的聚合物的高压聚合方法,所述方法至少包括以下步骤:使用包含反应器构造的反应器系统使包含乙烯和至少一种共聚单体的反应混合物聚合 (A)至少两个反应区,区(反应区1)和第i区(反应区i,其中i≥2),(B)至少两种基于乙烯的进料流,每种包含 供给聚合过程的总补充乙烯的百分比,并且其中第一物流被送至反应区1并且第二物流被送至反应区i; (C)控制系统以控制送入反应区1的物流中总补充乙烯的百分比,以及送入反应区i的物流中总补充乙烯的百分比,并且其中( Q)进料到第一反应区的至少一种共聚单体的摩尔浓度与在所有基于乙烯的进料到反应器构造的总和中的共聚单体的摩尔浓度满足以下等式1:0.231n(r1) - 2.16≤Q≤-0.251n(r1)+ 2.15(等式1); 并且其中共聚单体具有如下的反应性比率(r1):0.3≤r1≤5.0,沸点(1atm)≤150℃。