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    • 4. 发明申请
    • METHOD FOR PRODUCING LOW VOLATILE TUBULAR LOW DENSITY ETHYLENE-BASED POLYMERS FOR CLEAN EXTRUSION COATING PROCESSING
    • 生产用于清洁挤出涂布加工的低挥发性管低密度乙烯基聚合物的方法
    • WO2017184990A1
    • 2017-10-26
    • PCT/US2017/028864
    • 2017-04-21
    • DOW GLOBAL TECHNOLOGIES LLC
    • DEN DOELDER, Cornelis, FJHINRICHS, StefanKUPSCH, Eva-MariaBERBEE, Otto, J.PARADKAR, Rajesh, P.FEHR, Bernard, A.PEREZ, Carmelo, Declet
    • C08F2/00C08F2/01C08F2/34C08F10/02
    • A process for producing an ethylene-based polymer com prises polymerizing, by the presence of at least one free-radical initiator and using a high pressure tubular polymerization process, a reaction mixture containing ethylene and at least one CTA system comprising one or more CTA components to produce the ethylene-based polymer. The free-radical initiator is dissolved in a solvent com prising a saturated hydrocarbon to form an initiator solution which is added to the polymerization using an initiator feed line to an initiator injection pump. At least 50 wt% of the solvent has i) a dry point of less than or equal to 160°C and ii) an initial boiling point of greater than or equal to 100°C. The polymerization process has a ratio of in let pressure to first peak temperature of less than or equal to 9 Bar/°C. At least one CTA make-up stream is fed into the polymerization process, wherein less than or equal to 30 wt% of the at least one CTA make-up stream comprises one or more saturated hydrocarbon CTA(s) with a maximum carbon atom number of 6 per molecule.
    • 制备基于乙烯的聚合物的方法包括通过存在至少一种自由基引发剂并且使用高压管式聚合方法聚合包含乙烯和至少一种 CTA系统,其包含一种或多种CTA组分以生产基于乙烯的聚合物。 将自由基引发剂溶解在包含饱和烃的溶剂中以形成引发剂溶液,使用引发剂供给管线将引发剂溶液加入引发剂注入泵中进行聚合。 至少50重量%的溶剂具有i)小于或等于160℃的干点和ii)大于或等于100℃的初始沸点。 聚合过程具有小于或等于9巴/℃的进料压力与第一峰值温度的比率。 将至少一种CTA补充物流加入聚合过程中,其中少于或等于30wt%的至少一种CTA补充物流包含一种或多种具有最大碳原子数的饱和烃CTA 每分子6个。