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    • 3. 发明申请
    • SEEDING PROCESS FOR THE MANUFACTURE OF POLYMER MODIFIED POLYOLS
    • 聚合物改性聚烯烃的制备方法
    • WO2012154820A1
    • 2012-11-15
    • PCT/US2012/037077
    • 2012-05-09
    • DOW GLOBAL TECHNOLOGIES LLCCASATI, Francois M.COOKSON, PaulVAN DER WAL, Hanno R.
    • CASATI, Francois M.COOKSON, PaulVAN DER WAL, Hanno R.
    • C08G18/08C08G18/40
    • C08G18/409C08G18/0838C08G18/0876C08G18/7621C08G2101/0008
    • Embodiments of the invention provide for polymer polyols and methods of producing polymer polyols. Methods include providing at least one first composition which includes at least one polyol, at least one isocyanate non-reactive seed population, and at least one of a co-reactant having an equivalent weight of up to 400 and at least one active hydrogen attached to a nitrogen or oxygen atom. The at least one isocyanate non-reactive seed population includes less than about 5% by weight of the total weight of the first composition, and the seed population has a maximum particle diameter of less than 10 µm. The first composition is combined with at least one polyisocyanate under mixing to form at least one of a polyurea, polyurethane, and a polyurethane-urea particle population dispersed in the first composition, wherein at least 90% by weight of the particle population has a particle diameter of less than 100 µm.
    • 本发明的实施方案提供聚合物多元醇和制备聚合物多元醇的方法。 方法包括提供至少一种第一组合物,其包含至少一种多元醇,至少一种异氰酸酯非反应性种子群体和至少一种当量重量至多为400的共反应物和至少一种活性氢附着于 氮或氧原子。 所述至少一种异氰酸酯非反应性种子群包含小于所述第一组合物总重量的约5重量%,并且所述种子群体具有小于10μm的最大粒径。 将第一组合物与至少一种多异氰酸酯混合以形成分散在第一组合物中的聚脲,聚氨酯和聚氨酯 - 尿素颗粒群中的至少一种,其中至少90重量%的颗粒群具有颗粒 直径小于100μm。
    • 9. 发明申请
    • REDUCED FLAMMABILITY FLEXIBLE POLYURETHANE FOAM
    • 减少可燃性柔性聚氨酯泡沫
    • WO2018063959A1
    • 2018-04-05
    • PCT/US2017/053167
    • 2017-09-25
    • DOW GLOBAL TECHNOLOGIES LLC
    • PORCELLI, LucieCASATI, Francois M.COOKSON, Paul
    • C08K5/3492C08K5/54C08G18/18C08G18/22C08G18/24C08G18/34C08G18/08C08G18/40C08G18/48C08G18/76C08G18/66C08G101/00
    • A method of forming a flexible polyurethane foam that passes BS 5852:2006 source V (Crib 5) test. The method includes providing a modified polyisocyanate polyaddition (PIPA) 5 polyol formed by contacting a PIPA polyol dispersion with at least one carboxylic acid having a melting point above zero degree Celsius and present in a carrier solvent. The PIPA polyol dispersion has a polyol liquid phase content of 60 wt.% to 90 wt.% and a solid particle phase content of 10 wt.% to 40 wt.% based on a total weight of the PIPA polyol dispersion. From 10 weight percent (wt.%) to 80 wt.% of the modified PIPA polyol is combined with 90 wt.% to 20 10 wt.% of at least another polyether polyol based on a total weight of a polyol blend of the PIPA polyol and the at least another polyether polyol, where the polyether polyol is formed with propylene oxide and ethylene oxide and has an equivalent weight of 1,000 to 2,000 and a functionality of 3 to 6. The combination of the modified PIPA polyol and the polyether polyol are reacted with a polyisocyanate and a blowing agent to form the flexible polyurethane foam.
    • 一种形成通过BS 5852:2006源V(Crib 5)测试的软质聚氨酯泡沫的方法。 该方法包括提供通过使PIPA多元醇分散体与至少一种熔点高于零摄氏度且存在于载体溶剂中的羧酸接触而形成的改性多异氰酸酯加聚(PIPA)多元醇。 基于PIPA多元醇分散体的总重量,PIPA多元醇分散体具有60重量%至90重量%的多元醇液相含量和10重量%至40重量%的固体颗粒相含量。 基于PIPA的多元醇共混物的总重量,将10重量%(wt。%)至80重量%的改性PIPA多元醇与90重量%至20 10重量%的至少另一种聚醚多元醇组合 多元醇和至少另一种聚醚多元醇,其中聚醚多元醇与环氧丙烷和环氧乙烷一起形成并且具有1,000-2,000的当量重量和3-6的官能度。改性的PIPA多元醇和聚醚多元醇的组合是 与多异氰酸酯和发泡剂反应以形成柔性聚氨酯泡沫。