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    • 1. 发明申请
    • PROCESS FOR PRODUCING HIGH QUALITY IONOMERS
    • 生产高质量离子的方法
    • WO2008057979A3
    • 2008-07-31
    • PCT/US2007083407
    • 2007-11-02
    • DOW GLOBAL TECHNOLOGIES INCWALTHER BRIANNEUBAUER ANTHONYKIM EUNGPAVLICEK CALVINDIEHL CHARLES
    • WALTHER BRIANNEUBAUER ANTHONYKIM EUNGPAVLICEK CALVINDIEHL CHARLES
    • C08F8/44
    • C08F8/44B29C47/6025B29C47/6031B29C47/6037B29C47/6056C08F210/02C08F2800/20C08F8/12C08F220/06
    • A reactive extrusion process for producing an ionomer is disclosed. The process comprising adding a polymer containing a carboxyl functionality to an extruder, then homogenously melting the polymer in a melting zone of the extruder. A first melt seal zone of the extruder is formed to separate the melting zone from an injection zone where an aqueous solution of metallic ions are added to the molten polymer. The first melt seal zone is formed by increasing the pressure in the melt seal zone to a pressure which is higher than the vapor pressure of the water at any point in the injection zone and the reaction zone. The aqueous solution of metallic ions is then mixed with the polymer containing the carboxyl functionality in a reaction zone of the extruder under conditions such that the metallic ions are substantially reacted with the carboxyl functionality. A pressure build-up zone is formed in the extruder, wherein the pressure build-up zone is located no earlier than at the end of the reaction zone wherein the pressure build-up zone is formed by increasing the pressure to a level such that the aqueous solution of metallic ions remains in the liquid phase for a time sufficient to allow for the desired reaction between the metallic ions and the carboxyl functionality of the polymer.
    • 公开了用于制备离聚物的反应挤出方法。 该方法包括向挤出机中加入含有羧基官能团的聚合物,然后在挤出机的熔融区域中均匀熔融聚合物。 形成挤出机的第一熔体密封区,以将熔融区与将金属离子水溶液加入到熔融聚合物中的注入区分离。 通过将熔融密封区域中的压力增加到高于注入区域和反应区域中的任何点处的水的蒸汽压力的压力来形成第一熔融密封区域。 然后将金属离子水溶液与含有羧基官能团的聚合物在挤出机的反应区中混合,使得金属离子基本上与羧基官能团反应。 在挤出机中形成压力增加区,其中压力积聚区的位置不早于反应区的末端,其中通过将压力增加到一定水平而形成压力积聚区, 金属离子的水溶液在液相中保持足以允许金属离子和聚合物的羧基官能团之间所需的反应的时间。
    • 2. 发明申请
    • A POLYPROPYLENE COMPOSITION, A METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM
    • 聚丙烯组合物,其制造方法及其制造方法
    • WO2008121464A8
    • 2010-08-19
    • PCT/US2008055057
    • 2008-02-27
    • DOW GLOBAL TECHNOLOGIES INCFINLAYSON MALCOLMWALTHER BRIANHOGAN TODDHOENIG STEPHENWALTON KIM
    • FINLAYSON MALCOLMWALTHER BRIANHOGAN TODDHOENIG STEPHENWALTON KIM
    • C08L23/10C08K5/43
    • C08L23/10C08K3/013C08K5/0083C08K5/43C08L21/00C08L23/0815C08L2023/44C08L2666/06C08L2666/04
    • The instant invention is a polypropylene composition, a method of producing the same, and articles made therefrom. The polypropylene composition according to instant invention includes the reactive melt blending product of a high crystalline polypropylene having a crystallinity of at least 64 percent, an elastomer, a coupling agent, and optionally a filler. The polypropylene composition according to instant invention has a melt flow rate in the range of less than 1 g/10 minutes measured at 230 °C under a load of 2.16 kg in accordance with ASTM-D 1238. The method of producing a polypropylene composition according to instant invention includes the following steps: (1) reactive melt blending a high crystalline polypropylene having a crystallinity of at least 64 percent, an elastomer, and optionally a filler in the presence of a coupling agent; and (2) thereby producing the polypropylene composition having a melt flow rate in the range of less than 1 g/10 minutes measured at 230 °C under a load of 2.16 kg in accordance with ASTM-D 1238. The articles according to instant invention include the inventive polypropylene composition including the reactive melt blending product of a high crystalline polypropylene having a crystallinity of at least 64 percent, an elastomer, a coupling agent, and optionally a filler.
    • 本发明是聚丙烯组合物,其制造方法和由其制成的制品。 根据本发明的聚丙烯组合物包括具有至少64%的结晶度的高结晶聚丙烯的反应性熔融共混产物,弹性体,偶联剂和任选的填料。 根据本发明的聚丙烯组合物,根据ASTM-D 1238,在230℃,2.16kg负荷下测定的熔体流动速率在小于1g / 10分钟的范围内。 本发明包括以下步骤:(1)在偶联剂存在下,将结晶度为至少64%的高结晶聚丙烯,弹性体和任选的填料进行反应性熔体共混; 和(2),根据ASTM-D 1238,在230℃,2.16kg负荷下测定熔体流动速率在小于1g / 10分钟范围内的聚丙烯组合物。本发明的制品 包括本发明的聚丙烯组合物,其包括具有至少64%的结晶度的高结晶聚丙烯的反应性熔融共混产物,弹性体,偶联剂和任选的填料。