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    • 1. 发明申请
    • CARBINOL FUNCTIONAL TRISILOXANE AND METHOD OF FORMING THE SAME
    • CARBINOL功能三硅氧烷及其制备方法
    • WO2017189704A1
    • 2017-11-02
    • PCT/US2017/029598
    • 2017-04-26
    • DOW CORNING CORPORATIONDOW CORNING TORAY CO., LTD.
    • JOFFRE, Eric J.PETROFF, Lenin J.SUGIURA, TsunehitoTAMURA, SeikiWENZLICK, Zachary R.
    • C07F7/08A01N25/30A61K8/89C08L83/10
    • A trisiloxane having at least one carbinol functional group comprises the reaction product of (A) an initial trisiloxane and (B) an organic compound. Component (A) has a pendant silicon-bonded functional group selected from a hydrogen atom, an epoxy-containing group, an ethylenically unsaturated group, and an amine group. Typically, component (A) is free of certain terminal silicon-bonded functional groups and is free of polyoxyalkylene groups. Component (B) has a functional group reactive with the pendant silicon-bonded functional group of component (A), and has at least one hydroxyl functional group. The trisiloxane is useful for a number of applications including use as a detergent additive. The trisiloxane may be of the following general formula (I): (R13SiO1/2)(R1R3SiO2/2)(R13SiO1/2) (I). In formula (I), each R1 is an independently selected hydrocarbyl group. R3 may be selected from the groups (i) to (iv) described herein. Typically, the trisiloxane has 1-6 carbinol groups.
    • 具有至少一个甲醇官能团的三硅氧烷包含(A)初始三硅氧烷和(B)有机化合物的反应产物。 组分(A)具有选自氢原子,含环氧基团,烯属不饱和基团和胺基的悬挂硅键合官能团。 典型地,组分(A)不含特定的末端硅键合官能团并且不含聚氧化烯基团。 组分(B)具有与组分(A)的侧基硅键合官能团反应的官能团,并且具有至少一个羟基官能团。 三硅氧烷可用于许多应用,包括用作洗涤剂添加剂。 三硅氧烷可以具有以下通式(I):(R 13 SiO 1/2)(R 1 R 3 SiO 2/2)(R 13 SiO 1/2)(I)。 在式(I)中,每个R 1是独立选择的烃基。 R3可以选自本文所述的组(i)至(iv)。 典型地,三硅氧烷具有1-6个甲醇基团。
    • 2. 发明申请
    • DETERGENT COMPOSITION COMPRISING A CARBINOL FUNCTIONAL TRISILOXANE
    • 包含碳醇官能三硅氧烷的洗涤剂组合物
    • WO2017189703A1
    • 2017-11-02
    • PCT/US2017/029597
    • 2017-04-26
    • DOW CORNING CORPORATIONDOW CORNING TORAY CO., LTD.
    • BAUER, Paula MicheleCAUVIN, SeverineJOFFRE, Eric J.PETROFF, Lenin J.SEVERANCE, Martin K.SUGIURA, TsunehitoTAMURA, SeikiWENZLICK, Zachary R.
    • C11D3/16
    • A detergent composition comprises a trisiloxane having at least one carbinol functional group. The trisiloxane comprises the reaction product of (A) an initial trisiloxane and (B) an organic compound. Component (A) has a pendant silicon-bonded functional group selected from a hydrogen atom, an epoxy-containing group, an ethylenically unsaturated group, and an amine group. Typically, component (A) is free of certain terminal silicon-bonded functional groups and is free of polyoxyalkylene groups. Component (B) has a functional group reactive with the pendant silicon-bonded functional group of component (A), and has at least one hydroxyl functional group. The trisiloxane may be of the following general formula (I): (R 1 3 SiO 1/2 )(R 1 R 3 SiO 2/2 )(R 1 3 SiO 1/2 ) (I). In formula (I), each R 1 is an independently selected hydrocarbyl group. R 3 may be selected from the groups (i) to (x) described herein, each of the groups having at least one carbinol group. Typically, the trisiloxane has 1-6 carbinol groups.
    • 洗涤剂组合物包含具有至少一个甲醇官能团的三硅氧烷。 三硅氧烷包含(A)初始三硅氧烷和(B)有机化合物的反应产物。 组分(A)具有选自氢原子,含环氧基团,烯属不饱和基团和胺基的悬挂硅键合官能团。 典型地,组分(A)不含特定的末端硅键合官能团并且不含聚氧化烯基团。 组分(B)具有与组分(A)的侧基硅键合官能团反应的官能团,并且具有至少一个羟基官能团。 三硅氧烷可以具有以下通式(I):(R 1 = 3 SiO 1/2)(R 1 = (R 1 2 SiO 1/2)2(R 1)3 SiO 1/2 1/2 / sub>)(I)。 在式(I)中,每个R 1是独立选择的烃基。 R 3可以选自本文所述的组(i)至(x),每个基团具有至少一个甲醇基。 典型地,三硅氧烷具有1-6个甲醇基团。