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    • 6. 发明申请
    • PROCESS FOR MAKING AND USING FOAM CONTROL COMPOSITIONS
    • 制造和使用泡沫控制组合物的方法
    • WO2007137948A1
    • 2007-12-06
    • PCT/EP2007/054799
    • 2007-05-17
    • DOW CORNING CORPORATIONHILBERER, AlainNAVET, EmilieVERMEIRE, Laurent
    • HILBERER, AlainNAVET, EmilieVERMEIRE, Laurent
    • B01D19/04D21H21/12
    • D21C11/00B01D19/04D21H21/12B01D19/0409
    • A process for making a foam control composition comprising a cross-linked polyorganosiloxane in which is dispersed a filler, with hydrophobic surface, comprising step (A) mixing (i) a finely divided filler, (ii) a polyorganosiloxane having on at least two reactive substituents, for example on average two reactive substituents, and (iii) a polyorganosiloxane having at least three reactive substituents, capable of addition reaction via hydrosilylation; (B) hydrosilylation reaction of components (ii) and (iii) until the mixture at least partially gels, followed by applying shearing forces to this at least partially gelled mixture. Optionally step (A) comprises a diluent or solvent and after step (B) an emulsification step is carried out to make the foam control composition into an O/W emulsion. Also a process for controlling foam in an aqueous environment by using a foam control composition according to the invention, selected from inks, coatings, paints, detergents, black liquor of from those encountered during pulp and paper manufacture, waste water treatment, textile dyeing processes or the scrubbing of natural gas.
    • 一种制备泡沫控制组合物的方法,其包含交联的聚有机硅氧烷,其中分散有疏水表面的填料,所述方法包括步骤(A)将(i)细碎填料,(ii)至少两个反应性的聚有机硅氧烷 取代基,例如平均两个反应性取代基,和(iii)具有至少三个反应性取代基的聚有机硅氧烷,能够通过氢化硅烷化进行加成反应; (B)组分(ii)和(iii)的氢化硅烷化反应,直到混合物至少部分凝胶化,然后对该至少部分胶凝的混合物施加剪切力。 任选地,步骤(A)包括稀释剂或溶剂,并且在步骤(B)之后,进行乳化步骤以使泡沫控制组合物成为O / W乳液。 还有一种通过使用根据本发明的泡沫控制组合物来控制泡沫的方法,该组合物选自油墨,涂料,油漆,洗涤剂,在纸浆和造纸过程中遇到的黑液,废水处理,纺织染色方法 或擦洗天然气。
    • 7. 发明申请
    • DISILOXANE COMPOUNDS AND THEIR USES
    • 邻苯二甲酸酯化合物及其用途
    • WO2014071026A1
    • 2014-05-08
    • PCT/US2013/067786
    • 2013-10-31
    • DOW CORNING CORPORATION
    • CHAO, Sung-HsuenHILBERER, AlainKLEYER, Don, LeeZIMMERMAN, KennethZIOLKOWSKI, Nicolas
    • C07F7/18C04B28/04C04B40/00C04B40/06
    • B01F17/0071C04B16/00C04B24/42C04B28/02C04B2103/40C04B2103/65C04B2111/27C07F7/0852C07F7/0867C07F7/0879C04B40/0608
    • A disiloxane having the following structure. Formula (I), Where R 1 , R 3 , R 4 and R 5 are each independently selected from monovalent hydrocarbon radicals having 1 to 4 carbon atoms, aryl, and a hydrocarbon group of 6 to 20 carbon atoms containing an aryl group; R 2 is selected from a branched or linear hydrocarbon group of 7 to 15 carbons, a substituted branched or substituted linear hydrocarbon group of 7 to 15 carbons an optionally substituted aryl group, and an alkyl hydrocarbon chain of 4 to 9 carbons having one or more aryl substituents of 6 to 20 carbon atoms or a branched or linear hydrocarbon group of 1 to 6 carbons when R 1 and R 3 are independently an aryl group, or a hydrocarbon group of 6 to 20 carbon atoms containing an aryl group; Z is a linear or branched divalent hydrocarbon radical of from 2 to 10 (inclusive) carbon atoms and R 8 is selected from OH, H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl and each of the subscripts a, b and c are zero or positive provided that a + b + c ≥ 1.
    • 具有以下结构的二硅氧烷。 式(I)其中R 1,R 3,R 4和R 5各自独立地选自具有1至4个碳原子的一价烃基,芳基和含有芳基的6至20个碳原子的烃基; R 2选自7至15个碳的支链或直链烃基,7至15个碳的取代的支链或取代的直链烃基,任选取代的芳基和具有一个或多个芳基的4至9个碳的烷基烃链 当R 1和R 3独立地为芳基或含有芳基的6至20个碳原子的烃基时,具有6至20个碳原子的取代基或1至6个碳的支链或直链烃基; Z是2〜10个(含)碳原子的直链或支链二价烃基,R 8选自OH,H,1〜6个碳原子的一价烃基,乙酰基和下标a,b和c 如果a + b + c≥1,则为零或正数。