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1. 发明申请

WO9809999A3 ALPHA-OLEFIN/VINYLIDENE AROMATIC MONOMER AND/OR HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYLIDENE MONOMER INTERPOLYMERS 审中-公开
标题翻译： ALPHA-OLEFIN / VINYLIDENE AROMATIC MONOMER和/或HINDERED ALIPHATIC或CYCLOALIPHATIC VINYLIDENE MONOMER INTERPOLYMERS
公开(公告)号：WO9809999A3
公开(公告)日：1998-04-30
申请号：PCT/US9715559
申请日：1997-09-04
申请人： DOW CHEMICAL CO , CAMPBELL RICHARD E JR , MCADON MARK H , NICKIAS PETER N , PATTON JASSON T , REDWINE OSCAR D , TIMMERS FRANCIS J
发明人： CAMPBELL RICHARD E JR , MCADON MARK H , NICKIAS PETER N , PATTON JASSON T , REDWINE OSCAR D , TIMMERS FRANCIS J
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F212/00 , C08F212/04 , C08F12/04 , C08F12/08 , C08F210/18
CPC分类号： C08F212/04 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F210/02 , C08F2500/12
摘要： The present invention relates to alpha -olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70 - 44.25 ppm, preferably from 43.75 - 44.25 ppm and 38.0 - 38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention possess increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels. 00000
摘要翻译：本发明涉及在其碳13 NMR谱中具有特征信号的α-烯烃/乙烯基芳族单体互聚物。特别地，本发明的乙烯/苯乙烯共聚物在碳13 NMR谱中具有峰值，其出现在化学位移范围43.70-44.25ppm，优选43.75-44.25ppm和38.0-38.5ppm，所述峰为至少三次峰值到峰值噪声。通过在催化剂如外消旋 - （二甲基硅烷二基（2-甲基-4-苯基茚基））二氯化锆存在下聚合合适的单体混合物来制备互聚物。本发明的聚合物具有增加的模量，其由相应的乙烯基芳族单体水平下的拉伸应力/应变和动态机械数据两者确定。 00000

2. 发明申请

WO0242313A2 CATALYSTS FOR OLIGOMERIZATION OF ETHYLENE 审中-公开
标题翻译：乙烯低聚催化剂
公开(公告)号：WO0242313A2
公开(公告)日：2002-05-30
申请号：PCT/US0144248
申请日：2001-11-13
申请人： DOW CHEMICAL CO , BOONE HAROLD W , MULLINS MICHAEL J , NICKIAS PETER N , SNELGROVE VERNON
发明人： BOONE HAROLD W , MULLINS MICHAEL J , NICKIAS PETER N , SNELGROVE VERNON
IPC分类号： C07C2/88 , C07F5/06
CPC分类号： C07F5/062 , C07C2/88 , C07C11/02
摘要： A process for the preparation of an aluminum alkyl chain growth product by the chain growth reaction of an alpha -olefin on an aluminum alkyl, optionally followed by displacement and recovery of the oligomeric alpha-olefin employing as a catalyst for the chain growth reaction a compositon comprising a Group 6 metal trisazacycloalkane complex and an activating cocatalyst.
摘要翻译：通过在烷基铝上的α-烯烃的链增长反应制备烷基链烷基铝生长产物的方法，任选地随后用链增长反应的催化剂置换和回收低聚α-烯烃组合物包括6族金属三氮杂环烷烃络合物和活化助催化剂。

3. 发明申请

WO2011014553A3 IMPROVED PROCESS FOR THE SULFOCHLORINATION OF HYDROCARBONS 审中-公开
标题翻译：改进的烃类磺基氯化法
公开(公告)号：WO2011014553A3
公开(公告)日：2011-03-24
申请号：PCT/US2010043527
申请日：2010-07-28
申请人： DOW GLOBAL TECHNOLOGIES LLC , HIRSEKORN KURT F , TENN WILLIAM , NICKIAS PETER N
发明人： HIRSEKORN KURT F , TENN WILLIAM , NICKIAS PETER N
IPC分类号： C07C303/10 , C07C309/80
CPC分类号： C07C303/10 , C07C309/80
摘要： Produce a sulfo-chlorinated hydrocarbon using liquid sulfur dioxide, a chlorinating agent such as chlorine or sulfuryl chloride, and a metal complex catalyst, the catalyst being represented as LnM where L is at least one of an amine, phosphine, chloride or oxide, n is an integer within a range of from 1 to 6, and M is a metal selected from a group consisting of copper (Cu), ruthenium (Ru), iron (Fe), chromium (Cr), lanthanum (La), nickel (Ni), palladium (Pd), rhodium (Rh), rhenium (Re), molybdenum (Mo) and manganese (Mn).
摘要翻译：使用液体二氧化硫，氯化剂如氯或磺酰氯和金属络合物催化剂生产磺基氯化烃，催化剂表示为LnM，其中L是胺，膦，氯化物或氧化物中的至少一种，n M是选自铜（Cu），钌（Ru），铁（Fe），铬（Cr），镧（La），镍（ Ni），钯（Pd），铑（Rh），铼（Re），钼（Mo）和锰（Mn）。

4. 发明申请

WO2010065351A2 POLYMER PI-BOND-PHILIC FILLER COMPOSITES 审中-公开
标题翻译：聚合物PI-BOND-PHILIC FILLER复合材料
公开(公告)号：WO2010065351A2
公开(公告)日：2010-06-10
申请号：PCT/US2009065410
申请日：2009-11-20
申请人： DOW GLOBAL TECHNOLOGIES INC , MATTEUCCI SCOTT T , FEIST SHAWN D , NICKIAS PETER N , LOPEZ LEONARDO C , PAQUETTE MICHAEL S , MUNRO JEFFREY C
发明人： MATTEUCCI SCOTT T , FEIST SHAWN D , NICKIAS PETER N , LOPEZ LEONARDO C , PAQUETTE MICHAEL S , MUNRO JEFFREY C
IPC分类号： C08K9/04
CPC分类号： C08K3/08 , B01D53/02 , B01D2253/1122 , B01D2253/202 , B01D2257/7022 , C08K2003/0806 , C08L101/00
摘要： The instant invention generally provides polymer pi-bond-philic filler composite comprising a molecularly self-assembling material and a pi-bond-philic filler, and a process of making and an article comprising the polymer pi-bond-philic filler composite. The instant invention also generally provides a process of separating a pi-bond-philic gas from a separable gas mixture comprising the pi-bond-philic gas.
摘要翻译：本发明通常提供包含分子自组装材料和π-亲和填料的聚合物亲合性填料复合材料，以及制备方法和包含聚合物亲环键填料复合材料的制品。本发明还通常提供了一种从包含无亲性气体的可分离气体混合物中分离起始亲气体的方法。

5. 发明申请

WO9735894A2 ALLYL CONTAINING METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：含金属复合物和烯烃聚合方法
公开(公告)号：WO9735894A2
公开(公告)日：1997-10-02
申请号：PCT/US9712821
申请日：1997-03-11
申请人： DOW CHEMICAL CO
发明人： NICKIAS PETER N , DEVORE DAVID D , TIMMERS FRANCIS J
IPC分类号： C07F17/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/619 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , Y10S526/943 , C08F4/6592
摘要： Metal complexes useful as olefin polymerization ccatalysts corresponding to formula (I) or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein L is a cyclic group or Y, that is bound to M by means of a delocalized pi -bond, said group containing up to 50 non-hydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide serie of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula: -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of hydrocarbyl, hydrocarbyloxy, silyl, and germyl of up to 20 atoms other than hydrogen, and m is an integer from 1 to 3; Y is an allyl or hydrocarbyl-, silyl- or germyl-substituted allyl group containing up to 20 non-hydrogen atoms bonded to Z and bonded via an eta - pi bond to M; X' is a neutral ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：可用作对应于式（I）的烯烃聚合催化剂的金属络合物或二聚体，溶剂化加合物，螯合衍生物或其混合物，其中L是通过离域化的π键与M结合的环状基团或Y，所述该基团含有多达50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有下式的至多50个非氢原子的共价结合的二价取代基： - （ER 2）m - ，其中E独立地为碳，硅或锗，R各自独立地选自烃基，烃氧基，甲硅烷基和除氢以外的至多20个原子的甲锗烷基，m是1至3的整数; Y是烯基或烃基，甲硅烷基或甲锗烷基取代的烯丙基，其含有多达20个与Z结合的非氢原子并通过η3-π键与M键合; X'是具有至多20个非氢原子的中性配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X” 一起形成二价烃基基团; n是从0到3的数字; 并且p是0至2的整数。

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