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1. 发明申请

WO2013184476A3 PROCESSES TO PRODUCE CERTAIN 2-(PYRIDINE-3-YL)THIAZOLES 审中-公开
标题翻译：生产某些2-（吡啶-3-基）噻唑的方法
公开(公告)号：WO2013184476A3
公开(公告)日：2014-01-30
申请号：PCT/US2013043208
申请日：2013-05-30
申请人： DOW AGROSCIENCES LLC
发明人： ROSS RONALD , DEAMICIS CARL , ZHU YUANMING , NIYAZ NOORMOHAMED M , WEST SCOTT P , ROTH GARY , ARNDT KIM E
IPC分类号： C07D417/04
CPC分类号： C07D417/04 , C07D213/83
摘要： The invention disclosed in this document is related to the field of processes to produce certain 2-(pyridine-3-yl)thiazoles as intermediates for the synthesis of pesticidal thiazole amides. In step a, compounds (I) and (II) are reacted to produce compound (III). The reaction is conducted in a polar protic solvent. Examples of such solvents include, but are not limited to, formic acid, n-butanol, isopropanol, n-propanol, ethanol, methanol, acetic acid, and water. In step b, compound (III) is cyclized using a dehydrating agent. Examples of such dehydrating agents include, but are not limited to, POCI3, H2S04, SOCI2, P205, polyphosphoric acid, p-toluene sulfonic acid, and trifluoroacetic anhydride. One advantage of steps a and b over the art is that compound (III) and (IV) are generally produced as substantially pure solids that do not need additional purification procedures.
摘要翻译：本文公开的发明涉及产生某些2-（吡啶-3-基）噻唑作为合成杀虫噻唑酰胺的中间体的方法领域。在步骤a中，化合物（I）和（II）反应生成化合物（III）。反应在极性质子溶剂中进行。这些溶剂的实例包括但不限于甲酸，正丁醇，异丙醇，正丙醇，乙醇，甲醇，乙酸和水。在步骤b中，使用脱水剂使化合物（III）环化。这种脱水剂的实例包括但不限于POCI 3，H 2 SO 4，SOCl 2，P 2 O 5，多磷酸，对甲苯磺酸和三氟乙酸酐。步骤a和b在本领域中的一个优点是，化合物（III）和（IV）通常被生产为基本上纯的固体，其不需要额外的纯化程序。

2. 发明申请

WO2013162716A3 PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO 审中-公开
标题翻译：农药组合物及其相关方法
公开(公告)号：WO2013162716A3
公开(公告)日：2014-05-01
申请号：PCT/US2013029615
申请日：2013-03-07
申请人： DOW AGROSCIENCES LLC
发明人： BUYSSE ANN M , NIYAZ NOORMOHAMED M , DEMETER DAVID A , ZHANG YU , WALSH MARTIN J , KUBOTA ASAKO , HUNTER RICKY , TRULLINGER TONY K , LOWE CHRISTIAN T , KNUEPPEL DANIEL , PATNY AKSHAY , GARIZI NEGAR , LEPLAE PAUL RENEE , WESSELS FRANK , ROSS RONALD , DEAMICIS CARL , BORROMEO PETER
IPC分类号： A01N43/60
CPC分类号： A01N43/78 , A01N43/56 , A01N43/647 , A01N43/653 , A01N43/713 , A01N43/80 , A01N43/84 , A01N47/18 , A01N47/36 , A01N47/38 , A01N47/40 , A01N47/42 , A01N57/24 , C07D401/04 , C07D401/14 , C07D409/14 , C07D413/14 , C07D417/14
摘要： This document discloses molecules having the following formula ("Formula One"): and processes related thereto.
摘要翻译：该文献公开了具有下式（“一级方程式”）的分子及其相关的方法。

3. 发明申请

WO2012061290A2 PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO 审中-公开
标题翻译：农药组合物及其相关方法
公开(公告)号：WO2012061290A2
公开(公告)日：2012-05-10
申请号：PCT/US2011058578
申请日：2011-10-31
申请人： DOW AGROSCIENCES LLC , YAP MAURICE C H , BUYSSE ANN M , KNUEPPEL DANIEL , ZHANG YU , GARIZI NEGAR , NIYAZ NOORMOHAMED M , LOWE CHRISTIAN T , HUNTER RICKY , TRULLINGER TONY K , DEMETER DAVID A , PERNICH DAN , DEAMICIS CARL , ROSS RONALD , JOHNSON TIMOTHY C
发明人： YAP MAURICE C H , BUYSSE ANN M , KNUEPPEL DANIEL , ZHANG YU , GARIZI NEGAR , NIYAZ NOORMOHAMED M , LOWE CHRISTIAN T , HUNTER RICKY , TRULLINGER TONY K , DEMETER DAVID A , PERNICH DAN , DEAMICIS CARL , ROSS RONALD , JOHNSON TIMOTHY C
IPC分类号： A61K31/4439 , A01H5/10 , A01N25/34 , A01P1/00 , A01P3/00 , A01P5/00 , A01P7/02 , A01P7/04 , A01P9/00 , A01P11/00 , A01P13/00 , A01P15/00 , A01P17/00 , A01P19/00 , A01P21/00 , A01P23/00 , A61K31/444 , C07D401/04 , C07D401/14 , C07D417/14
CPC分类号： C07D417/14 , A01N25/00 , A01N43/12 , A01N43/56 , A01N43/653 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , A01N47/18 , A01N47/36 , A01N47/40 , A01N51/00 , A61K31/4439 , A61K31/506 , A61K45/06 , C07D401/04 , C07D401/14 , C07D403/04 , C07D405/14 , C07D409/14 , C07D413/14
摘要： This document discloses molecules having the following formula (I): and processes related thereto.
摘要翻译：该文献公开了具有下式（I）的分子及其相关的方法。

4. 发明申请

WO2015058028A8 PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS 审中-公开
标题翻译：制备杀虫化合物的方法
公开(公告)号：WO2015058028A8
公开(公告)日：2015-12-30
申请号：PCT/US2014061027
申请日：2014-10-17
申请人： DOW AGROSCIENCES LLC
发明人： YANG QIANG , LORSBACH BETH , ROTH GARY , NIYAZ NOORMOHAMED M , NISSEN JEFFREY , ROSS RONALD JR , WHITEKER GREG , DEAMICIS CARL , GRAY KAITLYN , ZHANG YU
IPC分类号： A01N43/56 , A01N25/00 , A01N47/40 , C07D231/14 , C07D231/40
CPC分类号： C07D401/04 , A01N43/40 , A01N43/56 , C07D213/77
摘要： The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds. The present application further relates to an efficient and economical synthetic chemical processes for the preparation of pesticidal thioether and pesticidal sulfoxides in high yield from commercially available starting materials.
摘要翻译：本申请提供了用于制备杀虫化合物和化合物作为农药和制备杀虫化合物的方法。本申请还涉及从市售的起始原料以高产率制备杀虫硫醚和杀虫亚砜的有效和经济的合成化学方法。

5. 发明申请

WO2013184480A2 PROCESSES TO PRODUCE CERTAIN 2-(PYRIDINE-3-YL)THIAZOLES 审中-公开
标题翻译：生产某些2-（吡啶-3-基）噻唑的方法
公开(公告)号：WO2013184480A2
公开(公告)日：2013-12-12
申请号：PCT/US2013043260
申请日：2013-05-30
申请人： DOW AGROSCIENCES LLC
发明人： ROSS RONALD , DEAMICIS CARL , ZHU YUANMING , NIYAZ NOORMOHAMED M , WEST SCOTT P , ROTH GARY , ARNDT KIM E
IPC分类号： A01N43/78
CPC分类号： A01N43/78 , C07D417/04
摘要： The invention disclosed in this document is related to the field of processes to produce certain 2-(pyridine-3-yl)thiazoles as intermediates for the synthesis of pesticidal thiazole amides.
摘要翻译：本文公开的发明涉及产生某些2-（吡啶-3-基）噻唑作为合成杀虫噻唑酰胺的中间体的方法领域。

6. 发明申请

WO2013162716A9 PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO 审中-公开
标题翻译：与其相关的杀虫组合物和过程
公开(公告)号：WO2013162716A9
公开(公告)日：2014-11-06
申请号：PCT/US2013029615
申请日：2013-03-07
申请人： DOW AGROSCIENCES LLC
发明人： BUYSSE ANN M , NIYAZ NOORMOHAMED M , DEMETER DAVID A , ZHANG YU , WALSH MARTIN J , KUBOTA ASAKO , HUNTER RICKY , TRULLINGER TONY K , LOWE CHRISTIAN T , KNUEPPEL DANIEL , PATNY AKSHAY , GARIZI NEGAR , LEPLAE PAUL RENEE , WESSELS FRANK , ROSS RONALD , DEAMICIS CARL , BORROMEO PETER
IPC分类号： A01N43/60
CPC分类号： A01N43/78 , A01N43/56 , A01N43/647 , A01N43/653 , A01N43/713 , A01N43/80 , A01N43/84 , A01N47/18 , A01N47/36 , A01N47/38 , A01N47/40 , A01N47/42 , A01N57/24 , C07D401/04 , C07D401/14 , C07D409/14 , C07D413/14 , C07D417/14
摘要： This document discloses molecules having the following formula ("Formula One"): and processes related thereto.
摘要翻译：该文献公开了具有下式的分子（“式1”）：及其相关工艺。

7. 发明申请

WO2013184475A3 PROCESSES TO PRODUCE CERTAIN 2-(PYRIDINE-3-YL)THIAZOLES 审中-公开
标题翻译：生产某些2-（吡啶-3-基）噻唑的方法
公开(公告)号：WO2013184475A3
公开(公告)日：2014-02-27
申请号：PCT/US2013043204
申请日：2013-05-30
申请人： DOW AGROSCIENCES LLC
发明人： ROSS RONALD , DEAMICIS CARL , ZHU YUANMING
IPC分类号： C07D417/04
CPC分类号： C07D417/04
摘要： The invention disclosed in this document is related to the field of processes to produce certain 2-(pyridine-3-yl)thiazoles as intermediates for the synthesis of pesticidal thiazole amides. Compounds (I) and (II) are cyclized to produce compound (III). This step is conducted in the presence of a base when compound (II) is in the form of a salt. Suitable bases include, but are not limited to, sodium bicarbonate, potassium bicarbonate, sodium carbonate, cesium carbonate, potassium carbonate, sodium hydroxide, potassium hydroxide, sodium bisulfate, sodium acetate, potassium acetate, ammonium hydroxide, sodium methoxide, potassium methoxide, sodium ethoxide, potassium ethoxide, triethylamine and pyridine. The reaction can be conducted at ambient temperature and pressure, but higher or lower temperatures and pressures can be used, if desired. The reaction is conducted in a polar protic solvent. Examples of such solvents include, but are not limited to, n-butanol, isopropanol, n-propanol, ethandl, methanol, and water.
摘要翻译：本文公开的发明涉及产生某些2-（吡啶-3-基）噻唑作为合成杀虫噻唑酰胺的中间体的方法领域。化合物（I）和（II）被环化以产生化合物（III）。当化合物（II）为盐形式时，该步骤在碱的存在下进行。合适的碱包括但不限于碳酸氢钠，碳酸氢钾，碳酸钠，碳酸铯，碳酸钾，氢氧化钠，氢氧化钾，硫酸氢钠，乙酸钠，乙酸钾，氢氧化铵，甲醇钠，甲醇钾，乙醇盐，乙醇钾，三乙胺和吡啶。反应可以在环境温度和压力下进行，但是如果需要，可以使用更高或更低的温度和压力。反应在极性质子溶剂中进行。这种溶剂的实例包括但不限于正丁醇，异丙醇，正丙醇，乙二醇，甲醇和水。

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