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2. 发明申请

WO2015040440A2 CATALYST AND PROCESS FOR THE PREPARATION OF HYDROGEN GAS FROM FORMATE AND HYDROGENATION OF HYDROGEN CARBONATE, AND HYDROGEN STORAGE SYSTEM USING THEM 审中-公开
标题翻译：用于制氢和氢化氢碳氢化合物的催化剂和方法以及使用它们的氢储存系统
公开(公告)号：WO2015040440A2
公开(公告)日：2015-03-26
申请号：PCT/HU2014/000083
申请日：2014-09-17
申请人： DEBRECENI EGYETEM
发明人： GYŐRVÁRINÉ HORVÁTH, Henrietta , PAPP, Gábor , JOÓ, Ferenc , KATHÓ, Ágnes
IPC分类号： B01J23/46
CPC分类号： B01J31/2457 , B01J31/2273 , B01J31/2295 , B01J31/2404 , B01J31/2409 , B01J31/2485 , B01J37/04 , B01J2231/62 , B01J2231/70 , B01J2231/763 , B01J2531/827 , B01J2531/96 , B01J2540/32 , C01B3/0073 , C01B3/042 , C01B3/326 , C01B2203/1047 , H01M8/04089 , H01M8/0618 , Y02E60/321 , Y02E60/324 , Y02E60/364 , Y02P20/52
摘要： The invention relates to a catalyst according to the formula lrCI(cod)(NHC)] + nP (n = 2, 3 or 4), or [lr(cod)(NHC)(P)] + nP (n = 1, 2 or 3), which is suitable to decompose formates in an aqueous reaction system, and for the production of hydrogen gas or hydrogenation of carbonates, wherein Ir means irydium; CI means chlorine; cod means 1,5-cyclooctadiene; NHC means N-heterocyclic carbene, preferably 1-R-3-methylimidasolium chloride, wherein R means C 1-5 alkyl es P means 1,3,5-triaza-7-phosphaadamantane (pta), monosulphonated triphenilphosphine ( m tppms), trisulphonated triphenylphosphine ( m tppts), or four times sulphonated diphenylphosphynopropane (dpppts). Furthermore, the invention relates to a process for the preparation of the catalyst accoring to the invention. Further, the invention relates to a process for the decomposition of formate in aqueous reaction system, and for the production of hydrogen gas free of CO x , still further, a process for the hydrogenation of hydrogen carbonate in an aqueous reaction system, as well as the production of the respective formate. Further, the invention relates to a process for the decomposition of formate accoring to the invention, and the hydrogenation of the carbonate generated in the same reaction system. The invention relates to a hydrogen storage system based on the process according to the invention, preferably battery or fuel cell, and the use thereof.
摘要翻译：本发明涉及根据式IrCI（cod）（NHC）] + nP（n = 2,3或4）或[lr（cod）（NHC）（P）] + nP（n = 2或3），其适于在水性反应体系中分解甲酸盐，以及用于生产氢气或碳酸氢盐的氢化，其中Ir表示卤素; CI表示氯; 鳕鱼是指1,5-环辛二烯; NHC表示N-杂环卡宾，优选1-R-3-甲基亚氨基二氯化锡，其中R表示C 1-5烷基，P表示1,3,5-三氮杂-7-磷杂金刚烷（pta），单磺化三苯基膦（mtppms），三磺化三苯基膦（mtppts）或四次磺化二苯基膦酰丙烷（dpppts）。此外，本发明涉及根据本发明制备催化剂的方法。此外，本发明涉及一种在水性反应体系中分解甲酸盐的方法，以及用于生产不含COx的氢气的方法，此外还涉及在含水反应体系中氢化碳酸氢盐的方法，以及生产各自的甲酸盐。此外，本发明涉及一种依照本发明分解甲酸盐的方法以及在同一反应体系中生成的碳酸氢盐。本发明涉及一种基于本发明方法的储氢系统，优选电池或燃料电池及其用途。

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