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1. 发明申请

WO2002096555A1 PROCESS FOR RECOVERING HOMOGENEOUS METAL HYDRATE CATALYSTS 审中-公开
标题翻译：回收均质金属氢化物催化剂的方法
公开(公告)号：WO2002096555A1
公开(公告)日：2002-12-05
申请号：PCT/GB2002/002577
申请日：2002-05-29
申请人： DAVY PROCESS TECHNOLOGY LIMITED , CRABTREE, Simon, Peter , WILD, Robert , JACKSON, Simon, Wayne , BANISTER, James, Andrew
发明人： CRABTREE, Simon, Peter , WILD, Robert , JACKSON, Simon, Wayne , BANISTER, James, Andrew
IPC分类号： B01J31/40
CPC分类号： B01J31/121 , B01J21/08 , B01J31/08 , B01J31/20 , B01J31/2404 , B01J31/4038 , B01J31/4046 , B01J31/4069 , B01J31/4092 , B01J38/74 , B01J2231/321 , B01J2531/82 , B01J2531/822 , C07C45/50 , Y02P20/544 , Y02P20/584 , C07C47/02
摘要： The present invention relates to a process for recovery of homogeneous metal hydride catalyst from a reactor stream as catalyst suitable for recycle to a reactor comprising the steps of: removing a stream from a reactor, said stream comprising the homogeneous metal hydride catalyst; contacting the stream with a solid acidic absorbent under process conditions which allow at least some of the metal to become bound to the absorbent; subjecting the metal bound to the absorbent, under process conditions which allow desorption of the metal, to a fluid stripping medium comprising hydrogen and solvent; and recovering the active metal hydride catalyst.
摘要翻译：本发明涉及从反应器料流中回收均相金属氢化物催化剂的方法，该催化剂适于再循环到反应器中，所述催化剂包括以下步骤：从反应器中除去流，所述物流包含均相金属氢化物催化剂; 在工艺条件下使流与固体酸性吸收剂接触，这使得至少一些金属能够结合到吸收剂上; 在允许金属解吸的工艺条件下将结合到吸收剂上的金属经受包含氢和溶剂的流体汽提介质; 并回收活性金属氢化物催化剂。

2. 发明申请

WO2006037957A1 PROCESS FOR THE PURIFICATION OF 1, 4-BUTANEDIOL 审中-公开
标题翻译： 1,4-丁二醇的纯化方法
公开(公告)号：WO2006037957A1
公开(公告)日：2006-04-13
申请号：PCT/GB2005/003741
申请日：2005-09-29
申请人： DAVY PROCESS TECHNOLOGY LIMITED , WOOD, Michael, Anthony , WILD, Robert , JACKSON, Simon, Wayne
发明人： WOOD, Michael, Anthony , WILD, Robert , JACKSON, Simon, Wayne
IPC分类号： C07C31/20
CPC分类号： C07D307/33 , C07C29/90 , C07D307/20 , C07C31/207 , C07C35/06
摘要： A process for the purification of a crude liquid feed stream comprising 1,4-butanediol and a minor amount of 2-(4-hydroxybutoxy)-tetrahydrofuran and/or precursors thereof wherein the process comprises passing the crude feed in the presence of hydrogen in a reaction zone over a heterogeneous liquid tolerant copper catalyst in the liquid phase at hydrogenation conditions and recovering a purified stream of 1,4-butanediol having a lower amount of 2-(4-hydroxybutoxy)-tetrahydrofuran than the crude liquid feed stream.
摘要翻译：纯化含有1,4-丁二醇和少量2-（4-羟基丁氧基） - 四氢呋喃和/或其前体的粗液体进料流的方法，其中所述方法包括使粗制原料在氢气存在下进行在氢化条件下在液相中的非均相液体耐受铜催化剂上的反应区，并回收具有比粗液体进料流更少量的2-（4-羟基丁氧基）四氢呋喃的纯化的1,4-丁二醇流。

3. 发明申请

WO2009074821A1 PROCESS FOR THE PRODUCTION OF 1,2-PROPANEDIOL 审中-公开
标题翻译：生产1,2-丙二醇的方法
公开(公告)号：WO2009074821A1
公开(公告)日：2009-06-18
申请号：PCT/GB2008/051143
申请日：2008-12-02
申请人： DAVY PROCESS TECHNOLOGY LIMITED , TUCK, Michael, William, Marshall , WILD, Robert , TILLEY, Simon, Nicholas
发明人： TUCK, Michael, William, Marshall , WILD, Robert , TILLEY, Simon, Nicholas
IPC分类号： C07C29/60 , C07C29/90 , C07C31/20
CPC分类号： C07C29/145 , C07C29/60 , C07C29/90 , C07C31/205
摘要： A process for the removal of hydroxypropane from a crude product stream from the hydrogenation of glycerol, the crude product stream comprising 1,2-propanediol and hydroxypropanone as impurity, the process comprising: (a) where required condensing the crude product stream; and (b) contacting the crude product phase in the liquid phase with a stream of a hydrogen-containing gas in the presence of a heterogeneous catalyst at suitable temperatures and pressures such that hydroxypropanone present in the crude product stream is converted to the desired propanediol.
摘要翻译：从甘油氢化的粗产物流中除去羟丙烷的方法，粗产物流包含1,2-丙二醇和羟丙丙酮作为杂质，该方法包括：（a）在需要时冷凝粗产物流; 和（b）在合适的温度和压力下，在非均相催化剂存在下使液相中的粗产物相与含氢气体流接触，使得存在于粗产物流中的羟基丙酮转化为所需的丙二醇。

4. 发明申请

WO2013072664A1 PROCESS FOR PRODUCING FATTY ALCOHOLS FROM FATTY ACIDS 审中-公开
标题翻译：从脂肪酸生产脂肪醇的方法
公开(公告)号：WO2013072664A1
公开(公告)日：2013-05-23
申请号：PCT/GB2012/052726
申请日：2012-11-01
申请人： DAVY PROCESS TECHNOLOGY LIMITED
发明人： APPLETON, Paul , WOOD, Michael Anthony , WILD, Robert
IPC分类号： C07C29/149 , C07C31/125 , C07C67/03 , C07C67/08
CPC分类号： C07C29/1285 , C07C29/128 , C07C29/149 , C07C31/125 , C07C67/03 , C07C67/08 , C07C69/26 , C07C69/24
摘要： A process for the production of fatty alcohol or alcohols comprising: subjecting a fatty acid or fatty acid mixture to esterification with a lower alkanol in an esterification reactor maintained under esterification conditions to form a stream comprising the corresponding lower alkyl ester or esters; vaporising the stream from step (a); subjecting the vaporised stream of step (b) to hydrogenation in a first hydrogenation zone operated under hydrogenation conditions to form a stream comprising fatty alcohol or alcohols and an amount of unconverted lower alkyl ester or esters; subjecting the stream from step (c) to transesterification in a wax ester reactor maintained under transesterification conditions in the presence of a solid transesterification catalyst thereby to convert at least a portion of the lower alkyl fatty acid ester by ester interchange with a corresponding amount of fatty alcohol or alcohols to lower alkanol and to a wax ester or esters derived from a fatty alcohol and a fatty acid; separating fatty alcohol or fatty alcohols and wax ester or wax esters of step (d) by distillation to yield a fatty alcohol or alcohols product and a stream comprising wax ester or esters; passing said stream comprising wax ester or esters to a second hydrogenation zone operating under conditions to effect hydrogenation in the liquid phase to revert the wax ester or esters to fatty alcohol or alcohols; and returning the fatty alcohol or alcohols to the separation step (e).
摘要翻译：一种生产脂肪醇或醇的方法，包括：在酯化反应器中，在酯化反应器中，用脂肪酸或脂肪酸混合物与低级链烷醇酯化，形成含有相应的低级烷基酯或酯的物流; 蒸发来自步骤（a）的物流; 使步骤（b）的汽化物流在氢化条件下操作的第一氢化区中氢化形成包含脂肪醇或醇的一定量的未转化的低级烷基酯或酯; 将来自步骤（c）的料流在固体酯交换催化剂存在下在酯酯化反应器中维持的蜡酯反应器中进行酯交换，从而通过酯交换将至少一部分低级烷基脂肪酸酯与相应量的脂肪醇或醇以降低链烷醇和衍生自脂肪醇和脂肪酸的蜡酯或酯; 通过蒸馏分离步骤（d）的脂肪醇或脂肪醇和蜡酯或蜡酯以产生脂肪醇或醇产物和包含蜡酯或酯的料流; 将包含蜡酯或酯的所述物流传递到在液相中进行氢化的条件下操作的第二氢化区，以将蜡酯或酯还原成脂肪醇或醇; 并将脂肪醇或醇返回到分离步骤（e）。

5. 发明申请

WO2013186526A1 PROCESS FOR THE PRODUCTION OF FATTY ACID ESTERS 审中-公开
标题翻译：生产脂肪酸酯的方法
公开(公告)号：WO2013186526A1
公开(公告)日：2013-12-19
申请号：PCT/GB2013/051351
申请日：2013-05-23
申请人： DAVY PROCESS TECHNOLOGY LIMITED
发明人： WILD, Robert , ANDERSSON, Rickard, Umberto
IPC分类号： C11C3/00 , C11C1/00
CPC分类号： C11C3/003 , C11C1/00 , Y02E50/13
摘要： A process for the production of fatty acid esters comprising; (a) subjecting a fatty acid or fatty acid mixture to esterification with a lower alkanol in an esterification reactor maintained under esterification conditions to form a stream comprising the corresponding lower alkyl ester or esters and recovering same; (b) recovering an overhead stream from the esterification reactor comprising unreacted lower alkanol, water, and a heavy organic content comprising one or more of lower alkyl ester and/or acids; (c) subjecting the recovered overhead stream to distillation in a first distillation column operating under first distillation conditions to separate a portion of the lower alkanol from a stream comprising the water, the remaining lower alkanol and the heavy organic content; (d) recovering the stream comprising the water, the remaining lower alkanol and the heavy organic content; and (e) subjecting the stream comprising the water, the remaining lower alkanol and the heavy organic content to distillation in a second distillation column operating under second distillation conditions to provide an overhead stream comprising lower alkanol and at least a major portion of the heavy organic content and a water stream having a reduced heavy organic and alkanol content.
摘要翻译：一种生产脂肪酸酯的方法，包括：（a）在维持在酯化条件下的酯化反应器中使脂肪酸或脂肪酸混合物与低级烷醇进行酯化，形成包含相应的低级烷基酯或酯的物流并回收; （b）从包含未反应的低级链烷醇，水和包含一种或多种低级烷基酯和/或酸的重的有机物含量的酯化反应器回收塔顶物流; （c）在第一蒸馏条件下操作的第一蒸馏塔中对回收的塔顶馏出物进行蒸馏以从包含水，剩余的低级链烷醇和重的有机物含量的物流中分离一部分低级链烷醇; （d）回收包含水，剩余的低级链烷醇和重的有机物含量的物流; 和（e）使包含水，剩余的低级链烷醇和重的有机物含量的物流在第二蒸馏条件下运行的第二蒸馏塔中进行蒸馏以提供包含低级链烷醇和至少大部分重质有机物含量和具有降低的重的有机和烷醇含量的水流。

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