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1. 发明申请

WO1998006762A1 FINE POWDER OF MODIFIED POLYTETRAFLUOROETHYLENE AND PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：改性聚四氟乙烯的精细粉末及其制备方法
公开(公告)号：WO1998006762A1
公开(公告)日：1998-02-19
申请号：PCT/JP1997002742
申请日：1997-08-07
申请人： DAIKIN INDUSTRIES LTD. , HOSOKAWA, Kazutaka , NANBA, Yoshinori , AOYAMA, Takahisa , SHIMIZU, Tetsuo
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08F214/26
CPC分类号： C08F214/262
摘要： A fine powder of a modified polytetrafluoroethylene comprising a copolymer of tetrafluoroethylene with X(CF2)nOCF=CF2 (wherein X represents a hydrogen or fluorine atom and n is an integer of 1 to 6) and/or C3F7(OCF2CF2CF2)m[OCF(CF3)CF2]pOCF=CF2 (wherein m and p are ach an integer of 0 to 4, provided that the sum of m and p is not 0), wherein the copolymer has an olefinic monomer content of 0.02 to 0.3 % by weight, is in the form of an agglomerate of colloidal particles having a number average particle diameter of 0.05 to 0.5 mu m, and has an Mw/Mn value of 1.5 to 4.5 and a standard specific gravity of 2.135 to 2.175. This modified polytetrafluoroethylene has good paste extrudability and can yield molded articles possessing excellent mechanical properties, particularly excellent pressure resistance.
摘要翻译：包含四氟乙烯与X（CF 2）n OCF = CF 2（其中X表示氢或氟原子，n为1〜6的整数）的共聚物和/或C 3 F 7（OCF 2 CF 2 CF 2）m [OCF（ CF 3）CF 2] pOCF = CF 2（其中m和p为ach，0〜4的整数，条件是m和p的和不为0），其中所述共聚物的烯属单体含量为0.02〜0.3重量％为数均粒径为0.05〜0.5μm的胶体粒子团聚体，Mw / Mn为1.5〜4.5，标准比重为2.135〜2.175。该改性聚四氟乙烯具有良好的糊料挤出性，并且可以得到具有优异的机械性能，特别优异的耐压性的模塑制品。

2. 发明申请

WO1998007056A1 ANTIREFLECTION ARTICLE 审中-公开
标题翻译：反选文章
公开(公告)号：WO1998007056A1
公开(公告)日：1998-02-19
申请号：PCT/JP1997002811
申请日：1997-08-12
申请人： DAIKIN INDUSTRIES LTD. , AOYAMA, Takahisa , SHIMIZU, Tetsuo , OTSUKI, Norihito , NAGAHAMA, Norio
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： G02B01/10
CPC分类号： G02B1/14 , G02B1/105 , G02B1/111 , Y10T428/24942 , Y10T428/265 , Y10T428/3154 , Y10T428/31935
摘要： An antireflection article, comprising an acrylic resin substrate and a fluoropolymer film provided on the surface of the substrate, wherein the film has a thickness of 0.03 to 0.5 mu m and the fluoropolymer has a refractive index of 1.30 to 1.40 and comprises a block compatible with an acrylic resin and a block of a fluoroelastomer. This article possesses scratch resistance and antireflection effect comparable with the conventional articles and, in addition, can be stably prepared at a low cost, or possesses an antireflection effect superior to that of the conventional antireflection film while maintaining the scratch resistance.
摘要翻译：一种防反射制品，其包括设置在基材表面上的丙烯酸树脂基材和含氟聚合物膜，其中所述膜的厚度为0.03至0.5μm，并且所述含氟聚合物的折射率为1.30至1.40，并且包含与丙烯酸树脂和含氟弹性体的块。本发明具有与常规制品相当的耐刮擦性和抗反射效果，并且可以以低成本稳定地制备，或者具有优于常规防反射膜的抗反射效果，同时保持耐刮擦性。

3. 发明申请

WO1994001475A1 MINUTE COMPOSITE FLUORORESIN PARTICLE 审中-公开
标题翻译：分钟复合荧光素颗粒
公开(公告)号：WO1994001475A1
公开(公告)日：1994-01-20
申请号：PCT/JP1993000950
申请日：1993-07-09
申请人： DAIKIN INDUSTRIES LTD. , SHIMIZU, Tetsuo , YAMAGUCHI, Seitaro , YAMAMOTO, Yoshihisa
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08F214/26
CPC分类号： C08J3/12 , C08F259/08 , C08J3/126 , C08J2327/18 , C08J2427/16 , Y10S525/902 , Y10T428/2998 , Y10T428/3154 , Y10T428/31544 , C08F214/22 , C08F214/18
摘要： A minute composite fluororesin particle having a multilayered or inclined structure and a mean particle diameter of 0.05-1.0 (my)m and composed of a core and a shell, wherein the core comprises a perfluororesin which is prepared by emulsion polymerization, has a monomer composition substantially composed of 85-100 wt.% of tetrafluoroethylene and 0-15 wt.% of a fluoroolefin copolymerizable therewith, is crystalline and has a melting point of 250 C or above, while the shell comprises a vinylidene fluoride resin which is substantially composed of 30-100 mol% of vinylidene fluoride and 0-70 mol% of another fluoroolefin copolymerizable therewith (except for hexafluoroisobutene), is crystalline and has a melting point of 70 C or above. This particle is excellent in the blendability with other resins and elastomers and the dispersibility in coating materials.
摘要翻译：具有多层或倾斜结构且平均粒径为0.05-1.0（my）m并由芯和壳组成的微小复合氟树脂颗粒，其中芯包含通过乳液聚合制备的全氟树脂，其具有单体组成基本上由85-100重量％的四氟乙烯和0-15重量％的可与其共聚的氟代烯烃组成，是结晶的，熔点为250℃或更高，而壳包含偏二氟乙烯树脂，其基本上由 30-100摩尔％的偏二氟乙烯和0-70摩尔％的可与其共聚的氟代烯烃（除六氟异丁烯之外）是结晶的，熔点为70℃或更高。该颗粒与其它树脂和弹性体的共混性和涂料中的分散性优异。

4. 发明申请

WO1996029200A1 THERMOPLASTIC RESIN LAMINATE 审中-公开
标题翻译：热塑性树脂层压板
公开(公告)号：WO1996029200A1
公开(公告)日：1996-09-26
申请号：PCT/JP1996000662
申请日：1996-03-15
申请人： DAIKIN INDUSTRIES LTD. , SHIMIZU, Tetsuo , NISHIBAYASHI, Hirofumi , INABA, Takeshi , YAMAMOTO, Yoshihisa , YAMATO, Takafumi , KITANO, Masakatsu
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： B32B07/14
CPC分类号： B32B27/08 , B32B1/08 , B32B7/10 , B32B27/30 , B32B27/304 , B32B27/322 , B32B27/34 , B32B37/0076 , B32B2597/00 , F16L9/12 , Y10T428/139 , Y10T428/31536 , Y10T428/3154
摘要： A thermoplastic resin laminate composed of at least three thermoplastic resin layers, i.e., first and second layers respectively formed of a thermoplastic resin (A1) and a thermoplastic resin (B1), which do not adhere to each other, and an intermediate layer sandwiched between the first and second layers, wherein the intermediate layer is formed of a thermoplastic resin composition which forms an islands-sea structure composed mainly of a thermoplastic resin (A2) which adheres to the thrermoplastic resin (A1) and a thermoplastic resin (B2) which adheres to the thermoplastic resin (B1), and in the vicinity of the interface between the intermediate layer and the first layer, the thermoplastic resin (A2) constitutes the sea phase with the thermoplastic resin (B2) constituting the islands phase, while in the vicinity of the interface between the intermediate layer and the second layer, the thermoplastic resin (B2) constitutes the sea phase with the thermoplastic resin (A2) constituting the islands phase, the first layer and the second layer adhering firmly to each other through the intermediate layer.
摘要翻译：由热塑性树脂层（A1）和热塑性树脂（B1）形成的第一层和第二层至少分别形成三层热塑性树脂层的热塑性树脂层叠体和夹在两层之间的中间层第一层和第二层，其中中间层由热塑性树脂组合物形成，该热塑性树脂组合物形成主要由附着于热塑性树脂（A1）的热塑性树脂（A2）和热塑性树脂（B2）组成的岛 - 海结构，粘附到热塑性树脂（B1）上，并且在中间层和第一层之间的界面附近，热塑性树脂（A2）与构成岛相的热塑性树脂（B2）构成海相，而在在中间层和第二层之间的界面附近，热塑性树脂（B2）构成海相，热塑性树脂（A2）构成岛相，第一层和第二层通过中间层彼此牢固地粘合。

5. 发明申请

WO1996014359A1 MOLTEN FLUORORESIN COMPOSITION 审中-公开
标题翻译： MOLTEN FLUORORESIN组合物
公开(公告)号：WO1996014359A1
公开(公告)日：1996-05-17
申请号：PCT/JP1995002212
申请日：1995-10-27
申请人： DAIKIN INDUSTRIES LTD. , MIYAMORI, Tsuyoshi , KOMORI, Masaji , KATOH, Masami , SHIMIZU, Tetsuo
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08L27/12
CPC分类号： F16H57/04 , B29C45/0001 , B29K2027/12 , B29K2027/14 , B29K2027/18 , C08K7/02 , C08K2201/016 , C09K3/1009 , C09K2200/0273 , Y10T428/215 , C08L27/12
摘要： An injection-moldable molten fluororesin composition comprising 70-98 wt.% of a molten fluororesin and 30-2 wt.% of an acicular substance having an average diameter of 3 mu m or less, an average aspect ratio of 10 to 100, and a Mohs hardness of 5 to 8, for example, borate whiskers. The composition has good slipperiness and sealability and is excellent in moldability, especially thin-wall moldability.
摘要翻译：一种可注射成型的熔融氟树脂组合物，其包含70-98重量％的熔融氟树脂和30-2重量％的平均直径为3μm以下，平均纵横比为10〜100的针状物，以及莫氏硬度为5至8，例如硼酸盐晶须。该组合物具有良好的滑爽性和密封性，并且成型性优异，特别是薄壁成型性。

6. 发明申请

WO1995011940A1 THERMOPLASTIC RESIN COMPOSITION AND LAMINATE MADE THEREFROM 审中-公开
标题翻译：热塑性树脂组合物和层压体
公开(公告)号：WO1995011940A1
公开(公告)日：1995-05-04
申请号：PCT/JP1994001806
申请日：1994-10-27
申请人： DAIKIN INDUSTRIES LTD. , YAMAMOTO, Yoshihisa , YAMATO, Takafumi , SHIMIZU, Tetsuo , HARADA, Takeshi
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08L27/12
CPC分类号： B32B1/08 , B32B27/08 , B32B27/34 , B32B2250/03 , B32B2307/718 , B32B2327/12 , B32B2597/00 , C08L27/12 , C08L27/18 , C08L77/00 , C08L2205/02 , Y10T428/139 , C08L2666/02 , C08L2666/06
摘要： A thermoplastic resin composition comprising (i) 5-80 wt. % of a polyamide resin, (ii) 15-90 wt. % of a fluororesin, and (iii) 1-80 wt. % of a fluororubber having a tensile modulus of 500 kg/cm or less at ordinary temperature. A molding having a layer formed from the above composition has an excellent chemical resistance.
摘要翻译：一种热塑性树脂组合物，其包含（i）5-80wt。％的聚酰胺树脂，（ii）15-90重量％％的氟树脂，和（iii）1-80wt。在常温下拉伸模量为500kg / cm 2以下的氟橡胶的％。具有由上述组合物形成的层的成型体具有优异的耐化学性。

7. 发明申请

WO1998001104A1 COSMETIC PREPARATIONS CONTAINING FLUORINATED OILS 审中-公开
标题翻译：含有氟化油的化妆品制剂
公开(公告)号：WO1998001104A1
公开(公告)日：1998-01-15
申请号：PCT/JP1997002343
申请日：1997-07-07
申请人： DAIKIN INDUSTRIES LTD. , MORITA, Masamichi , SEKI, Eiji , KUBO, Motonobu
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： A61K07/00
CPC分类号： A61Q19/00 , A61K8/70 , A61K8/86 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q5/00 , A61Q17/04
摘要： Cosmetic preparations which contain fluorinated oils of general formulae (I), (II), (III), do not impair the oil repellency of powdery materials treated with fluorine compounds, and are excellent in compatibility with the skin and inexpensive.
摘要翻译：含有通式（I），（II），（III）的氟化油的化妆品不会损害用氟化合物处理的粉末材料的拒油性，并且与皮肤的相容性优异且便宜。

8. 发明申请

WO1997040089A1 FLUOROPOLYMER POWDER AND PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：氟聚合物粉末及其制备方法
公开(公告)号：WO1997040089A1
公开(公告)日：1997-10-30
申请号：PCT/JP1997001393
申请日：1997-04-23
申请人： DAIKIN INDUSTRIES LTD. , TOMIHASHI, Nobuyuki , MIYATANI, Toshio
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08J03/12
CPC分类号： C08J3/12 , C08J2327/12
摘要： A process for preparing a fluoropolymer powder characterized by densifying a fluoropolymer as a raw powder by means of rolls under such conditions as to give a specific gravity of at least 90 % of the true specific gravity, pulverizing the densified powder, removing fine particles in an amount of 3 to 40 % by weight of the whole particle size distribution of the pulverized product by air classification, and removing coarse particles in an amount of 1 to 20 % by weight of the whole particle size distribution of the pulverized product. The fluoropolymer powder prepared by the above process has a good producibility and a good powder fluidity and can be used as a powder coating which causes no contamination when thermally fused.
摘要翻译：一种制备含氟聚合物粉末的方法，其特征在于，在使比重至少为真比重的至少90％的条件下通过辊致密化作为原料粉末的含氟聚合物，粉碎致密粉末，除去细粉末粉碎产物的整体粒度分布的3〜40重量％，除去粉碎物的整体粒径分布的1〜20重量％的粗粒子。通过上述方法制备的含氟聚合物粉末具有良好的生产能力和良好的粉末流动性，并且可以用作当热熔融时不引起污染的粉末涂料。

9. 发明申请

WO1997036934A1 PROCESS FOR FLUORINATING CELLULOSIC MATERIALS AND FLUORINATED CELLULOSIC MATERIALS 审中-公开
标题翻译：氟化纤维素材料和氟化纤维素材料的方法
公开(公告)号：WO1997036934A1
公开(公告)日：1997-10-09
申请号：PCT/JP1997001061
申请日：1997-03-28
申请人： DAIKIN INDUSTRIES LTD. , YAMAGUCHI, Fumihiko , SAKAMOTO, Eiji
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C08B15/00
CPC分类号： C08H8/00 , C08B15/00 , D06M14/04 , D06M15/256 , D06M15/277 , D06M23/10 , D06M2101/06 , D06M2200/10 , D06M2200/11 , D06M2200/12 , D06M2200/45 , D21C9/005
摘要： Fluorinated cellulosic materials prepared by a process of reacting a cellulosic material selected from the group consisting of cellulose materials and lignocellulose materials with at least one fluorine compound selected from among fluorinated olefins, fluorinated acrylates and fluorinated methacrylates in the presence of a catalyst in an organic solvent, wherein not only the surface but also the inside are modified to thereby attain enhancement in the functions.
摘要翻译：氟化纤维素材料通过使选自纤维素材料和木质纤维素材料的纤维素材料与选自氟化烯烃，氟化丙烯酸酯和氟化甲基丙烯酸酯中的至少一种氟化合物在催化剂存在下在有机溶剂中反应的方法制备其中，不仅表面而且内部都被修改，从而实现功能的增强。

10. 发明申请

WO1997013737A1 PROCESS FOR PRODUCING 1,1,1,3,3-PENTAFLUOROPROPANE 审中-公开
标题翻译：生产1,1,1,3,3-三氟硼酸的方法
公开(公告)号：WO1997013737A1
公开(公告)日：1997-04-17
申请号：PCT/JP1996002943
申请日：1996-10-08
申请人： DAIKIN INDUSTRIES LTD. , AOYAMA, Hirokazu , NAKADA, Tatsuo , YAMAMOTO, Akinori
发明人： DAIKIN INDUSTRIES LTD.
IPC分类号： C07C19/08
CPC分类号： C07C17/206 , C07C19/08
摘要： A process for producing 1,1,1,3,3-pentafluoropropane (HFC-245fa) which comprises reacting a halogenated propane represented by the following general formula, such as 1,1,1,3,3-pentachloropropane: CX3CH2CHX2 wherein X represents fluoro (F) or chloro (C1), provided that not all Xs represent fluoro at the same time; with anhydrous hydrofluoric acid (HF) in the presence of an antimony catalyst to thereby give HFC-245fa. Thus HFC-245fa can be economically and efficiently obtained via simple steps.
摘要翻译： 1.一种生产1,1,1,3,3-五氟丙烷（HFC-245fa）的方法，其包括使由以下通式表示的卤代丙烷如1,1,1,3,3-五氯丙烷：CX3CH2CHX2反应，其中X 表示氟（F）或氯（C1），条件是并非所有X同时代表氟; 与无水氢氟酸（HF）在锑催化剂存在下反应，得到HFC-245fa。因此HFC-245fa可以通过简单的步骤经济有效地获得。

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