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1. 发明申请

WO2003051894A1 PREPARATION OF IONIC LIQUIDS 审中-公开
标题翻译：离子液体的制备
公开(公告)号：WO2003051894A1
公开(公告)日：2003-06-26
申请号：PCT/CA2002/001919
申请日：2002-12-13
申请人： CYTEC CANADA INC. , REN, Rex, Xiaofeng , ROBERTSON, Allan, J.
发明人： REN, Rex, Xiaofeng , ROBERTSON, Allan, J.
IPC分类号： C07F9/54
CPC分类号： C07D213/20 , C07C209/68 , C07C303/22 , C07C303/40 , C07D233/56 , C07F9/54 , C10N2220/04 , C07C211/63 , C07C309/04 , C07C309/23 , C07C311/48
摘要： Provided is a method for preparation of non-halide based ionic liquids, comprising reacting a halide salt of an organic cation with a Bronsted acid in the presence of an alcohol or alkene or alkyne. The non-halide based ionic liquid product of the reaction can be purified by removing hydrocarbyl halide, and any unreacted starting materials and water if present, for example by distillation. The halide ion content of the ionic liquid product can be minimized by using an excess of alcohol or alkene or alkyne in the reaction and/or treating crude ionic liquid with a further quantity of alcohol or alkene or alkyne.
摘要翻译：提供了一种制备非卤化物基离子液体的方法，包括在醇或烯烃或炔烃的存在下使有机阳离子的卤化物盐与布朗斯台德酸反应。可以通过除去烃基卤化物和任何未反应的原料和水（如果存在的话），例如通过蒸馏来纯化反应的非卤化物基离子液体产物。离子液体产物的卤离子含量可以通过在反应中使用过量的醇或烯烃或炔烃和/或用另外的醇或烯烃或炔烃处理粗离子液体来最小化。

2. 发明申请

WO2002094883A3 ONE-STEP PROCESS FOR THE PREPARATION OF HALIDE-FREE HYDROPHOBIC SALTS 审中-公开
公开(公告)号：WO2002094883A3
公开(公告)日：2002-11-28
申请号：PCT/US2002/001766
申请日：2002-01-22
申请人： COVALENT ASSOCIATES, INC. , REN, Rex, Xiaofeng , KOCH, Victor, R.
发明人： REN, Rex, Xiaofeng , KOCH, Victor, R.
IPC分类号： C07D233/56 , C07D233/58
摘要： This invention describes a one pot, single-step process for the preparation of halide-free hydrophobic salts comprising polyalkylated imidazolium cations and various anions in accordance with the following structure, where R 1 and R 3 represent the either the same or different alkyl groups, and R 2 , R 4 , and R 5 represent either hydrogen atoms, or the same or different alkyl group substituents; X represents a polyatomic anion that is the conjugate base of an acid. By simply mixing aqueous formaldehyde with an alkyl amine such as methylamine, ethylamine, n -propyl or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine, or by mixing aqueous formaldehyde with two alkyl amines (preferably one being methylamine, ethylamine, n -propyl- or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine) and another being n -propyl- or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine), an acid (such as hexafluorophosphoric acid, trifluoroacetic acid, pentafluoropropionic, heptafluorobutyric acid, or the free acid of a bis (perfluoroalkylsulfony)imide or tris(perfluoroalkylsulfonyl)methide as the source of the anion) and aqueous glyoxal solution, the hydrophobic ionic salts or mixtures thereof thus formed may be conveniently separated directly from the aqueous byproduct layer. Like the single cation hydrophobic salts, these mixed hydrophobic ionic liquids are non-flammable and manifest no detectable vapor pressure up to their decomposition tempperature of greater than 300° C. We have also discovered that, surprisingly, ternary mixtures of dialkylated ionic liquids manifest higher ionic conductivities than a single ionic liquid of the mixture alone. This property benefits electrochemical power source applications such as batteries and capacitors. Furthermore, we have discovered that ternary mixtures of dialkylated ionic liquids absorb microwave radiation more efficiently than a single ionic liquid of the mixture alone. This property benefits microwave-induced synthetic reactions. Such physical and chemical properties make it possible to employ inexpensive mixtures of polyalkylated imidazolium cations in an advantageous manner as thermal transfer fluids, high temperature lubricants, and plasticizers, and as solvents in the areas of electrochemistry, synthetic chemistry, catalysis, and separations chemistry.

3. 发明申请

WO2002094883A2 ONE-STEP PROCESS FOR THE PREPARATION OF HALIDE-FREE HYDROPHOBIC SALTS 审中-公开
标题翻译：制备无卤素疏水盐的一步法
公开(公告)号：WO2002094883A2
公开(公告)日：2002-11-28
申请号：PCT/US2002/001766
申请日：2002-01-22
申请人： COVALENT ASSOCIATES, INC. , REN, Rex, Xiaofeng , KOCH, Victor, R.
发明人： REN, Rex, Xiaofeng , KOCH, Victor, R.
IPC分类号： C08F
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08 , C07F9/28
摘要： This invention describes a one pot, single-step process for the preparation of halide-free hydrophobic salts comprising polyalkylated imidazolium cations and various anions in accordance with the following structure, where R 1 and R 3 represent the either the same or different alkyl groups, and R 2 , R 4 , and R 5 represent either hydrogen atoms, or the same or different alkyl group substituents; X represents a polyatomic anion that is the conjugate base of an acid. By simply mixing aqueous formaldehyde with an alkyl amine such as methylamine, ethylamine, n -propyl or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine, or by mixing aqueous formaldehyde with two alkyl amines (preferably one being methylamine, ethylamine, n -propyl- or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine) and another being n -propyl- or iso -propylamine, or n -butyl-, iso -butyl, or t -butylamine), an acid (such as hexafluorophosphoric acid, trifluoroacetic acid, pentafluoropropionic, heptafluorobutyric acid, or the free acid of a bis (perfluoroalkylsulfony)imide or tris(perfluoroalkylsulfonyl)methide as the source of the anion) and aqueous glyoxal solution, the hydrophobic ionic salts or mixtures thereof thus formed may be conveniently separated directly from the aqueous byproduct layer. Like the single cation hydrophobic salts, these mixed hydrophobic ionic liquids are non-flammable and manifest no detectable vapor pressure up to their decomposition tempperature of greater than 300° C. We have also discovered that, surprisingly, ternary mixtures of dialkylated ionic liquids manifest higher ionic conductivities than a single ionic liquid of the mixture alone. This property benefits electrochemical power source applications such as batteries and capacitors. Furthermore, we have discovered that ternary mixtures of dialkylated ionic liquids absorb microwave radiation more efficiently than a single ionic liquid of the mixture alone. This property benefits microwave-induced synthetic reactions. Such physical and chemical properties make it possible to employ inexpensive mixtures of polyalkylated imidazolium cations in an advantageous manner as thermal transfer fluids, high temperature lubricants, and plasticizers, and as solvents in the areas of electrochemistry, synthetic chemistry, catalysis, and separations chemistry.
摘要翻译：本发明描述了根据以下结构制备包含多烷基化咪唑鎓阳离子和各种阴离子的不含卤化物的疏水盐的一锅一步法，其中R 1和R 3表示相同或不同的烷基，R 2，R 4和R 5表示氢原子或相同或不同的烷基取代基; X表示作为酸的共轭碱的多原子阴离子。通过简单地将含水甲醛与烷基胺如甲胺，乙胺，正丙基或异丙胺或正丁基，异丁基或叔丁胺混合，或通过混合甲醛水溶液与两种烷基胺（优选一种甲胺，乙胺，正丙基或异丙胺或正丁基 - ，异丁基或叔丁胺），另一种是正丙基或异丙胺或正丁基 - 异丁基，或叔丁胺），酸（例如六氟磷酸，三氟乙酸，五氟丙酸，七氟丁酸或作为阴离子源的双（全氟烷基磺酰基）酰亚胺或三（全氟烷基磺酰基）甲基化物的游离酸）和乙二醛水溶液溶液，由此形成的疏水性离子盐或其混合物可以方便地从水性副产物层直接分离。像单一的阳离子疏水盐一样，这些混合的疏水性离子液体是不易燃的，并且在大于300℃的分解温度下不显示可检测的蒸气压。我们还发现令人惊讶的是，二烷基化离子液体的三元混合物表现出更高的离子电导率比单独的混合物的单一离子液体。这种性能有利于电化学电源应用，如电池和电容器。此外，我们已经发现，二烷基化离子液体的三元混合物比单独的混合物的单一离子液体更有效地吸收微波辐射。这种性质有利于微波诱导的合成反应。这种物理和化学性质使得可以以有利的方式使用廉价的多烷基化咪唑鎓阳离子混合物作为热传递流体，高温润滑剂和增塑剂，以及在电化学，合成化学，催化和分离化学领域中的溶剂。

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