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1. 发明申请

WO2010060569A1 IMPROVED OPTICAL BRIGHTENING COMPOSITIONS FOR HIGH QUALITY INK JET PRINTING 审中-公开
标题翻译：改进的高性能喷墨打印机的光学强化组合物
公开(公告)号：WO2010060569A1
公开(公告)日：2010-06-03
申请号：PCT/EP2009/008258
申请日：2009-11-20
申请人： CLARIANT INTERNATIONAL LTD , JACKSON, Andrew Clive , KLEIN, Cédric , PUDDIPHATT, David
发明人： JACKSON, Andrew Clive , KLEIN, Cédric , PUDDIPHATT, David
IPC分类号： D21H21/30 , C09D11/00 , B41M5/52
CPC分类号： D21H17/09 , B41J2/01 , B41M5/5227 , B41M5/5236 , B41M5/5245 , B41M5/5254 , C07D251/54 , C07D251/70 , C09D11/322 , D21H17/28 , D21H17/66 , D21H21/16 , D21H21/30
摘要： The instant invention relates to improved liquid sizing compositions comprising derivatives of diaminostilbene, binders, protective polymers and divalent metal salts for the optical brightening of substrates suitable for high quality ink jet printing.
摘要翻译：本发明涉及改进的液体施胶组合物，其包含二氨基芪的衍生物，粘合剂，保护性聚合物和二价金属盐，用于适合于高质量喷墨印刷的基材的光学增白。

2. 发明申请

WO2010060570A1 OPTICAL BRIGHTENING COMPOSITIONS FOR HIGH QUALITY INK JET PRINTING 审中-公开
标题翻译：用于高品质喷墨打印的光学组合物
公开(公告)号：WO2010060570A1
公开(公告)日：2010-06-03
申请号：PCT/EP2009/008259
申请日：2009-11-20
申请人： CLARIANT INTERNATIONAL LTD. , INTERNATIONAL PAPER COMPANY , JACKSON, Andrew Clive , KLEIN, Cédric , PUDDIPHATT, David , SKAGGS, Benny, J.
发明人： JACKSON, Andrew Clive , KLEIN, Cédric , PUDDIPHATT, David , SKAGGS, Benny, J.
IPC分类号： D21H21/30 , B41M5/52 , C09D11/00
CPC分类号： B41M5/5227 , B41J2/01 , B41M5/52 , B41M5/5218 , D21H17/00 , D21H17/09 , D21H17/72 , D21H19/12 , D21H21/16 , D21H21/30
摘要： The instant invention relates to liquid compositions comprising derivatives of diaminostilbene, binders and ink fixing agents such as divalent metal salts for the optical brightening of substrates suitable for high quality ink jet printing.
摘要翻译：本发明涉及包含二氨基芪的衍生物，粘合剂和油墨固定剂如二价金属盐的液体组合物，用于适于高质量喷墨印刷的基材的光学增白。

3. 发明申请

WO2009118247A1 IMPROVED OPTICAL BRIGHTENING COMPOSITIONS 审中-公开
标题翻译：改进的光学强化组合物
公开(公告)号：WO2009118247A1
公开(公告)日：2009-10-01
申请号：PCT/EP2009/052919
申请日：2009-03-12
申请人： CLARIANT INTERNATIONAL LTD , JACKSON, Andrew Clive , PUDDIPHATT, David , KLEIN, Cédric
发明人： JACKSON, Andrew Clive , PUDDIPHATT, David , KLEIN, Cédric
IPC分类号： D21H17/66 , D21H21/16 , D21H21/30 , D21H17/63
CPC分类号： D21H17/63 , D21H17/66 , D21H21/16 , D21H21/30
摘要： The instant invention relates to mixed salts of optical brighteners of formula (1), wherein M represents a mixture of Mg 2+ with another cation, which provide for superior optical brightening effects when applied to the surface of paper.
摘要翻译：本发明涉及式（1）的荧光增白剂的混合盐，其中M表示Mg 2+与另一种阳离子的混合物，当施加到纸表面时提供优异的光学增亮效果。

4. 发明申请

WO2011066955A1 CONCENTRATED STORAGE-STABLE AQUEOUS OPTICAL BRIGHTENING SOLUTIONS 审中-公开
标题翻译：浓缩储存稳定的水性光亮解决方案
公开(公告)号：WO2011066955A1
公开(公告)日：2011-06-09
申请号：PCT/EP2010/007287
申请日：2010-12-01
申请人： CLARIANT INTERNATIONAL LTD , KLEIN, Cedric , REVEAUD, Frederic , PUDDIPHATT, David , JACKSON, Andrew, Clive
发明人： KLEIN, Cedric , REVEAUD, Frederic , PUDDIPHATT, David , JACKSON, Andrew, Clive
IPC分类号： C07D251/54
CPC分类号： C07D251/54 , D21H21/30 , Y10T428/249921 , Y10T442/2582 , Y10T442/60
摘要： Concentrated storage-stable aqueous solutions (S) comprising components (a), (b) and (C), wherein component (a) is at least one optical brightening agent of formula (1), in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more cations selected from the group consisting of hydrogen, alkali metal cation, alkaline earth metal cation, ammonium, ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched alkyl radical and ammonium which is mono-, di- or trisubstituted by a C 1-4 linear or branched hydroxyalkyl radical, and the concentration of component (a) is 0.08 to 0.3 mol per kg, based on the total weight of the concentrated storage-stable aqueous solutions (S), component (b) is at least one inorganic salt (SA), in a concentration of 2 to 15 % by weight, based on the total weight of the concentrated storage-stable aqueous solutions (S), and component (c) is water, in a concentration of 10 % to 88 % by weight, based on the total weight of the concentrated storage-stable aqueous solutions (S).
摘要翻译：包含组分（a），（b）和（C）的浓缩储存稳定的水溶液（S），其中组分（a）是至少一种式（1）的荧光增白剂，其中增白剂上的阴离子电荷是通过由一个或多个选自氢，碱金属阳离子，碱土金属阳离子，铵，铵，C 1-4直链或支链烷基单，二或三取代的阳离子组成的阳离子电荷平衡和由C1-4直链或支链羟烷基单取代，二取代或三取代的铵，组分（a）的浓度为每千克浓度为0.08至0.3mol，基于浓缩储存稳定水溶液溶液（S），组分（b）为至少一种无机盐（SA），浓度为2至15重量％，基于浓缩储存稳定水溶液（S）的总重量和组分（ c）为基于总重量的浓度为10％至88％重量的水 l重量的储存稳定的水溶液（S）。

5. 发明申请

WO2009118248A2 IMPROVED OPTICAL BRIGHTENING COMPOSITIONS 审中-公开
标题翻译：改进的光学增白组合物
公开(公告)号：WO2009118248A2
公开(公告)日：2009-10-01
申请号：PCT/EP2009/052921
申请日：2009-03-12
申请人： CLARIANT INTERNATIONAL LTD , JACKSON, Andrew, Clive , PUDDIPHATT, David
发明人： JACKSON, Andrew, Clive , PUDDIPHATT, David
IPC分类号： D21H17/66 , D21H21/16 , D21H21/30
CPC分类号： D21H17/63 , D21H17/66 , D21H21/16 , D21H21/30
摘要： A sizing composition for paper, characterised in that the sizing composition comprises (a) at least one optical brightener of formula (1), (b) a magnesium salt; and (c) a binding agent, which is selected from the group consisting of native starch, enzymatically modified starch and chemically modified starch; 0.1 to 15 parts of component (b) being present per part of component (a).
摘要翻译：（a）至少一种式（1）的荧光增白剂，（b）镁盐; 和（c）粘合剂，其选自天然淀粉，酶改性淀粉和化学改性淀粉; 每部分组分（a）存在0.1至15份的组分（b）。

6. 发明申请

WO2012000625A1 AQUEOUS COMPOSITIONS FOR SHADING IN COATING APPLICATIONS 审中-公开
标题翻译：涂料应用中的水性组合物
公开(公告)号：WO2012000625A1
公开(公告)日：2012-01-05
申请号：PCT/EP2011/003048
申请日：2011-06-21
申请人： CLARIANT INTERNATIONAL LTD , GRETHER-SCHENE, Heidrun , PUDDIPHATT, David
发明人： GRETHER-SCHENE, Heidrun , PUDDIPHATT, David
IPC分类号： D21H21/28 , D21H21/30 , D21H21/32
CPC分类号： D21H19/44 , D21H21/28 , D21H21/30 , D21H21/32 , Y10T428/31971 , Y10T428/31982 , Y10T428/31986 , Y10T428/31993
摘要： Aqueous coating composition for shading substrates, preferably paper, comprising (a) at least one shading dye of formula (I) in which R 1 signifies H, methyl or ethyl, R 2 signifies paramethoxyphenyl, methyl or ethyl, M signifies a cation selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched hydroxyalkyl radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C 1 -C 4 linear or branched alkylradical and linear or branched hydroxyalkyl radical or mixtures of said compounds, (b) at least one white pigment, (c) at least one primary binder, (d) optionally one or more secondary binders and (e) water.
摘要翻译：用于遮蔽底物（优选纸）的水性涂料组合物，其包含（a）至少一种式（I）的着色染料，其中R 1表示H，甲基或乙基，R 2表示对甲氧基苯基，甲基或乙基，M表示选自由氢，碱金属阳离子，碱土金属，铵，由C 1 -C 4直链或支链烷基单，二，三或四取代的铵组成的铵，其是单 - ，二 - ，三 - 或被C1-C4直链或支链羟烷基自由基取代，被C1-C4直链或支链烷基和直链或支链羟烷基的混合物或所述化合物的混合物二，三或四取代的铵，（b）至少一种白色颜料，（c）至少一种主要粘合剂，（d）任选的一种或多种次级粘合剂和（e）水。

7. 发明申请

WO2012000624A1 AQUEOUS COMPOSITIONS FOR WHITENING AND SHADING IN COATING APPLICATIONS 审中-公开
标题翻译：涂料应用中的白色和灰色组合物
公开(公告)号：WO2012000624A1
公开(公告)日：2012-01-05
申请号：PCT/EP2011/003047
申请日：2011-06-21
申请人： CLARIANT INTERNATIONAL LTD , GRETHER-SCHENE, Heidrun , KLEIN, Cedric , PUDDIPHATT, David
发明人： GRETHER-SCHENE, Heidrun , KLEIN, Cedric , PUDDIPHATT, David
IPC分类号： D21H21/28 , D21H21/30 , D21H21/32
CPC分类号： D21H19/44 , C09B11/12 , C09B23/148 , C09B67/0033 , D21H21/28 , D21H21/30 , D21H21/32 , Y10T428/25 , Y10T428/2982 , Y10T428/31971 , Y10T428/31986 , Y10T428/31993
摘要： Aqueous coating composition for optical brightening and shading of substrates comprising (a) at least one optical brightener of formula (I) in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more identical or different cations selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched hydroxyalkyi radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C 1 -C 4 linear or branched alkylradical and linear or branched hydroxyalkyi radical or mixtures of said compounds, R 1 and R 1 ´ may be the same or different, and each is hydrogen, C 1 -C 4 linear or branched alkyl, C2-C4 linear or branched hydroxyalkyi, CH 2 CO 2 - , CH 2 CH 2 CONH 2 or CH 2 CH 2 CN, R 2 and R 2 ´may be the same or different, and each is C 1 -C 4 linear or branched alkyl, C 2 -C 4 linear or branched hydroxyalkyl, CH 2 CO 2 - , CH(CO 2 - )CH 2 CO 2 - , CH(CO 2 - )CH 2 CH 2 CO 2 - , CH 2 CH 2 SO 3 - , CH 2 CH 2 CO 2 - , CH 2 CH(CH 3 )CO 2 - , benzyl, or R 1 and R 2 and/or R 1 ´ and R 2 ´, together with the neighboring nitrogen atom signify a morpholine ring and p is 0, 1 or 2, (b) at least one shading dye of formula (II) in which R 3 signifies H, methyl or ethyl, R 4 signifies paramethoxyphenyl, methyl or ethyl, M signifies a cation selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C 1 -C 4 linear or branched hydroxyalkyl radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C 1 -C 4 linear or branched alkylradical and linear or branched hydroxyalkyl radical or mixtures of said compounds, (c) at least one white pigment, (d) at least one primary binder, (e) optionally one or more secondary binders and (f) water.
摘要翻译：用于基材的光学增白和遮蔽的水性涂料组合物，其包含（a）至少一种式（I）的荧光增白剂，其中增亮剂上的阴离子电荷由阳离子电荷平衡，所述阳离子电荷由一种或多种相同或不同的阳离子平衡，所述阳离子选自由C1-C4直链或支链烷基单，二，三或四取代的氢，碱金属阳离子，碱土金属，铵，铵，由单，二，三 - 或被C 1 -C 4直链或支链羟基烷基自由基四取代的铵，其是由C 1 -C 4直链或支链烷基和直链或支链羟基烷基自由基的混合物二或三或四取代或所述化合物的混合物R1和 R 1可以相同或不同，各自为氢，C 1 -C 4直链或支链烷基，C 2 -C 4直链或支链羟基烷基，CH 2 CO 2 - ，CH 2 CH 2 CONH 2或CH 2 CH 2 CN，R 2和R 2可以相同或不同， C1-C4线性或支链烷基，C 2 -C 4直链或支链羟烷基，CH 2 CO 2 - ，CH（CO 2 - ）CH 2 CO 2 - ，CH（CO 2 - ）CH 2 CH 2 CO 2 - ，CH 2 CH 2 SO 3 - ，CH 2 CH 2 CO 2 - ，CH 2 CH（CH 3）CO 2 - ，苄基或R 1和R 2和 /或R1'和R2'与相邻的氮原子一起表示一个吗啉环，p是0,1或2，（b）至少一种式（II）的着色染料，其中R 3表示H，甲基或乙基， R 4表示对甲氧基苯基，甲基或乙基，M表示选自氢，碱金属阳离子，碱土金属，铵，铵的单体，二，三或四取代的C 1 -C 4直链或支链烷基，其是被C 1 -C 4直链或支链羟烷基单，二，三或四取代的铵，其是由C 1 -C 4直链或支链羟基烷基的混合物二，三或四取代的铵烷基和直链或支链羟烷基或所述化合物的混合物，（c）至少一种白色颜料，（d）至少一种主要粘合剂，（e）op （f）水。

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