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1. 发明申请

WO2010080491A1 FLAME RETARDANT COMBINATIONS FOR POLYESTERS AND FLAME RETARDED POLYESTER MOULDING COMPOSITIONS THEREFROM 审中-公开
标题翻译：聚酯和阻燃聚酯模塑组合物的阻燃组合
公开(公告)号：WO2010080491A1
公开(公告)日：2010-07-15
申请号：PCT/US2009/068452
申请日：2009-12-17
申请人： CLARIANT INTERNATIONAL LTD , FRX POLYMERS, INC. , WANZKE, Wolfgang , HOEROLD, Sebastian , LEBEL, Marc-andre , FREITAG, Karl, Dieter
发明人： WANZKE, Wolfgang , HOEROLD, Sebastian , LEBEL, Marc-andre , FREITAG, Karl, Dieter
IPC分类号： C08K5/53 , C08K3/32
CPC分类号： C08K5/0066 , C08K5/34924 , C08K5/53 , C08L67/02
摘要： Disclosed are new compositions consisting of mixtures of flame retardants for thermoplastic polyesters based on a phosphinate salt, phosphonate oligomers, polymers or copolymers and a melamine derivative. The compositions exhibit an excellent combination of processing characteristics, thermal and mechanical properties, and are flame retardant. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.
摘要翻译：公开了由基于次膦酸盐，膦酸盐低聚物，聚合物或共聚物和三聚氰胺衍生物的热塑性聚酯的阻燃剂的混合物组成的新组合物。组合物表现出加工特性，热和机械性能的优异组合，并且是阻燃剂。进一步公开的是由这些材料制成的制品，例如纤维，薄膜，涂覆的基材，模制品，泡沫，纤维增强制品或其任何组合。

2. 发明申请

WO2004022640A1 FLAMMSCHUTZMITTEL-STABILISATOR-KOMBINATION FÜR THERMOPLASTISCHE POLYMERE 审中-公开
标题翻译：阻燃稳定剂组合物用于热塑性聚合物
公开(公告)号：WO2004022640A1
公开(公告)日：2004-03-18
申请号：PCT/EP2003/009434
申请日：2003-08-26
申请人： CLARIANT GMBH , HOEROLD, Sebastian , WANZKE, Wolfgang , SCHACKER, Ottmar , NASS, Bernd , SICKEN, Martin
发明人： HOEROLD, Sebastian , WANZKE, Wolfgang , SCHACKER, Ottmar , NASS, Bernd , SICKEN, Martin
IPC分类号： C08K13/02
CPC分类号： C08K5/5313 , C08K3/22
摘要： Die Erfindung betrifft eine neue Flammschutzmittel-Stabilisator-Kombination für thermoplastische Polymere, enthaltend als Komponente A 25 bis 99,9 Gew-%.eines Phosphinsäuresalzes der Formel (I) und/oder eines Diphosphinsäuresalzes der Formel (II) und/oder deren Polymere, worin R 1 , R 2 : gleich oder verschieden sind und C 1 -C 6 -Alkyl, linear oder verzweigt und/oder Aryl; R 3 : C 1 -C 10 -Alkylen, linear oder verzweigt, C 6 -C 10 -Arylen, -Alkylarylen oder -Arylalkylen; M: Mg, Ca, AI, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K und/oder eine protonierte Stickstoffbase; m: 1bis 4; n: 1 bis 4; x: 1 bis 4 bedeuten, als Komponente B 0 bis 75 Gew.-% eines stickstoffhaltigen Synergisten oder eines Phosphor/Stickstoff Flammschutzmittels und als Komponente C 0,1 bis 50 Gew.-% eines basischen oder amphoteren Oxides, Hydroxides, Carbonates, Silikates, Borates, Stannates, gemischten Oxid-Hydroxides, Oxid-Hydroxid-Carbonates, Hydroxid-Silikates oder Hydroxid-Borates oder Mischungen dieser Stoffe, wobei die Summe der Komponenten immer 100 Gew.-% beträgt.
摘要翻译：本发明涉及一种新颖的阻燃剂 - 稳定剂组合用于热塑性聚合物，其包括，按重量计作为组分A，25至99.9 - 。％的式（I）和/或式（II）和/或聚合物的二次膦酸盐的膦酸盐中，其中R <1>，R <2>：相同或不同，和C1-C6烷基，直链或支链的和/或芳基; [R <3>：C1-C10亚烷基，直链或支链的，C 6 -C 10亚芳基，烷基亚芳烷基或亚芳; L：镁，钙，铝，锑，锡，锗，钛，锌，铁，锆，铈，铋，锶，锰，锂，钠，钾和/或质子化的氮基; 米：1至4; N：1〜4; X：1〜4中，作为组分B，0至75重量的含氮增效剂％或磷/氮阻燃剂和，作为组分C的0.1％至50重量的碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐盐，硼酸盐，锡酸盐，混杂的氧化物 - 氢氧化物，氧化物 - 氢氧化物 - 碳酸盐，硅酸盐氢氧化物或氢氧化物的硼酸盐，或这些物质的混合物，所述组分的总和总是达100重量％。

3. 发明申请

WO2009109318A1 VERFAHREN ZUR HERSTELLUNG FLAMMWIDRIGER, NICHT KORROSIVER UND GUT FLIESSFÄHIGER POLYAMID- UND POLYESTERFORMMASSEN 审中-公开
标题翻译：用于生产阻燃，无腐蚀性和良好和FLOWABLE尼龙聚酯模塑化合物
公开(公告)号：WO2009109318A1
公开(公告)日：2009-09-11
申请号：PCT/EP2009/001319
申请日：2009-02-25
申请人： CLARIANT INTERNATIONAL LTD , HOEROLD, Sebastian , SCHACKER, Ottmar , BAUER, Harald , KRAUSE, Werner , EISENHAUER, Daniela
发明人： HOEROLD, Sebastian , SCHACKER, Ottmar , BAUER, Harald , KRAUSE, Werner , EISENHAUER, Daniela
IPC分类号： C08K5/00 , C08K5/5313 , C09K21/12 , C08K3/10 , C08K5/098
CPC分类号： C09K21/12 , C08K5/0066 , C08K5/5313 , C08L77/00 , C08L67/02
摘要： Die Erfindung betrifft ein Verfahren zur Herstellung flammwidriger, nicht korrosiver, gut fließfähiger Polyamide und Polyester, dadurch gekennzeichnet, dass eine Flammschutzmittelmischung aus einem Phosphinsäuresalz der Formel (I) mit M = AI, Mg, Ca, Ti, Na (Komponente A) worin R 1 , R 2 gleich oder verschieden sind und C 1 -C 6 -Alkyl, linear oder verzweigt und/oder Aryl; n 1 bis 3 bedeuten, und als Komponente B ein Metallsalz einer organischen Säure und/oder eine anorganische Zink-, Calcium-, Magnesium-, Kalium-, Natrium-, Aluminium-, Titan-, Zinn-, Antimon-, Wismut- oder Bariumverbindung eingesetzt wird, wobei Komponente A in 70 - 99,5 Gew.-% und Komponente B in 0,5 - 30 Gew.-% in der Flammschutzmittelmischung enthalten ist.
摘要翻译：本发明涉及一种用于生产阻燃，无腐蚀性，良好的流动聚酰胺和聚酯的方法，其特征在于，所述式（I）的次膦酸盐的阻燃剂混合物，其中M在=铝，镁，钙，钛，钠（成分A），其中R1 中，R 2是相同的或不同的，C1-C6烷基，直链或支链的和/或芳基; n为1至3，和作为组分B，有机酸和/或无机锌的金属的盐，钙，镁，钾，钠，铝，钛，锡，锑，铋或钡化合物的情况下，其特征在于，组分A在70 - 0.5 99.5重量％，成分B - 30重量％被包含在阻燃剂混合物。

4. 发明申请

WO2022233619A1 FLAME RETARDANT-STABILIZER COMBINATION FOR THERMOPLASTIC POLYMERS 审中-公开
公开(公告)号：WO2022233619A1
公开(公告)日：2022-11-10
申请号：PCT/EP2022/060835
申请日：2022-04-25
申请人： CLARIANT INTERNATIONAL LTD
发明人： HOEROLD, Sebastian , BAUER, Harald , LEUSCHNER, Eva Maria
IPC分类号： C08K5/00 , C08L67/02 , C08L77/06 , C08K3/32 , C08K5/5313 , C09K21/12
摘要： The invention relates to flame retardant-stabilizer mixtures comprising as component A 5% to 50% by weight of aluminium diethylphosphinate (DEPAL) or zinc diethylphosphinate (DEPZN), as component B 5% to 50% by weight of titanium phosphinates and/or titanyl phosphinates of the formula (I) (DEPTI), in which x is a number from 0 to 1.9, preferably 1 -1.05, which means that the ratio of Ti to diethylphosphinates is from 1.9 to 2, as component C 0% to 10% by weight of aluminium phosphite or zinc phosphite of the formula (II) and (III) as component D 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant, as component E 0% to 70% by weight of a filler and reinforcer, as component F 0% to 3% by weight of an organic phosphonite or an organic phosphite and mixtures with phenolic antioxidants and as component G 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of C14 to C40, where the sum total of the components is always 100% by weight.

5. 发明申请

WO2022023064A1 FLAME RETARDANT-STABILIZER COMBINATIONS FOR FLAME-RETARDANT POLYMERS HAVING IMPROVED HYDROLYSIS STABILITY AND USE THEREOF 审中-公开
公开(公告)号：WO2022023064A1
公开(公告)日：2022-02-03
申请号：PCT/EP2021/069839
申请日：2021-07-15
申请人： CLARIANT INTERNATIONAL LTD
发明人： HOEROLD, Sebastian , LEUSCHNER, Eva, Maria
IPC分类号： C08K5/5313 , C08K3/013 , C08K3/34 , C08K5/134 , C08K5/29 , C08K5/3492 , C08K5/5393 , C08L67/00 , C08L75/04 , C08L77/00 , C08L67/02 , C08L77/02
摘要： What are described are mixtures comprising selected phosphinic salts as component A, polymeric carbodiimide compounds as component B, and at least two of components C, D and/or G, where component C is a sterically hindered phenol, component D is an organic phosphite or phosphonite, and component G is a lubricant or demoulding agent. The mixtures may be used for production of flame-retardant compositions of thermoplastic polymers. These compositions feature enhanced hydrolysis stability.

6. 发明申请

WO2021254907A1 FLAME RETARDANT-STABILIZER COMBINATION FOR THERMOPLASTIC POLYMERS 审中-公开
公开(公告)号：WO2021254907A1
公开(公告)日：2021-12-23
申请号：PCT/EP2021/065802
申请日：2021-06-11
申请人： CLARIANT INTERNATIONAL LTD
发明人： HOEROLD, Sebastian , BAUER, Harald
IPC分类号： C08K3/013 , C08K3/016 , C08K3/32 , C08K5/00 , C08K5/098 , C08K5/3492 , C08K5/5313 , C08K5/5317 , C08K7/14 , C08K3/22 , C08K3/38 , C08K2003/2234 , C08K2003/322 , C08K2003/323 , C08K2003/387 , C08K2201/014 , C08K5/0066 , C08K5/34922 , C08K5/34924 , C08K5/34928
摘要： The invention provides a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20% to 99.7% by weight of phosphinic salt of the formula (I), (I), in which R1 and R2 are each ethyl, M is Al and m is 3; as component B 0.2% to 16% by weight of aluminium salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid; as component C 0.1 % to 80% by weight of a salt of phosphorous acid having the general formula (II) [HP(=O)O2]2- M m+ (II) in which M is Zn and m is 2; as component D 0% to 80% by weight of a salt of phosphorous acid having the general formula (III) [HP(=O)O2]2-3 Mm+2 (III) in which M is Al and m is 3; as component E 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as component F 0% to 10% by weight of an inorganic synergist selected from zinc borate, zinc stannate, boehmite and/or hydrotalcite; as component G 0% to 3% by weight of an organic phosphonite and/or a mixture of an organic phosphonite and an organic phosphite and as component H 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of C14 to C40, where the sum total of the components is always 100% by weight.

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