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    • 1. 发明申请
    • HERBICIDAL COMPOSITIONS
    • 除草剂组合物
    • WO1996029870A1
    • 1996-10-03
    • PCT/EP1996001086
    • 1996-03-14
    • CIBA-GEIGY AGGLOCK, JuttaHUDETZ, ManfredKERBER, Elmar
    • CIBA-GEIGY AG
    • A01N43/54
    • A01N43/54A01N43/66A01N25/32A01N2300/00
    • A selective herbicidal composition comprising, in addition to conventional formulation assistants, a mixture of a) a herbicidally effective amount of a herbicide of formula (I), or a salt or a stereoisomer of the compounds of formula (I), and b) to antagonise the herbicide, an antidotally effective amount of a safener of formula (IIa) of a compound of formula (IIb1), of a compound of formula (IIb2), of a compound of formula (IIc), of a compound of formula (IId), of a compound of formula (IIe), of a compound of formula (IIf), of a compound of formula (IIg), or of a compound of formula (IIh), wherein the substituents have the meanings claimed in claim 1.
    • 一种选择性除草组合物,除了常规制剂助剂外还包含a)除草有效量的式(I)除草剂或式(I)化合物的盐或立体异构体的混合物,和b)至 拮抗除草剂,式(IIb1)化合物,式(IIb2)化合物,式(IIc)化合物,式(IId)化合物的式(IIa)化合物的安定剂 )式(IIe)化合物,式(IIf)化合物,式(IIg)化合物或式(IIh)化合物,其中取代基具有权利要求1所述的含义。
    • 2. 发明申请
    • HERBICIDAL COMPOSITIONS
    • 除草剂组合物
    • WO1996011574A1
    • 1996-04-25
    • PCT/EP1995003935
    • 1995-10-05
    • CIBA-GEIGY AGGLOCK, JuttaHUDETZ, ManfredKERBER, Elmar
    • CIBA-GEIGY AG
    • A01N43/90
    • A01N43/56A01N43/90A01N43/42A01N25/32A01N2300/00
    • Selective herbicidal compositions for controlling grasses and weeds in crops of cultivated plants, comprising: a) a herbicidally effective amount of a compound of formula (I), wherein R1 is the (i), (ii) or (iii) group; the substituents R4 are each independently of one another halogen, nitro, cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C10alkoxy, C1-C4haloalkoxy, C3-C6alkenyloxy, C1-C4alkoxy-C2-C4alkoxy, C3-C6alkynyloxy, C1-C4alkylcarbonyl, C1-C4alkoxycarbonyl, C1-C4alkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, amino, C1-C4alkylamino or di-C1-C4alkylamino; R5 is the (iv) or (v) group; n is 0, 1, 2, 3 or 4; m is 0 or 1, the sum of m and n being 0, 1, 2, 3 or 4; q is 0, 1, 2 or 3; X1 is oxygen, sulfur, -CH2- or -N(R7)-; the substituents R6 are each independently of one another C1-C4alkyl, halogen, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, nitro, cyano, C1-C4alkoxycarbonyl, amino, C1-C4alkylamino or di-C1-C4alkylamino; R7 is hydrogen, C1-C4alkyl, formyl or C1-C4alkylcarbonyl; A and B are each independently of one another hydrogen, alkyl, alkenyl, alkynyl, alkoxyalkyl, alkylthioalkyl or cycloalkyl, or substituted or unsubstituted aryl; or A and B, taken together, form the divalent radical of a saturated or unsaturated and unsubstituted or substituted mono-, bi-, tri- or polycyclic system; G is hydrogen or a group -CO-R18 (a), (b), -SO2-R20 (c), (d), (e) or X (f); L and M are each independently of the other oxygen or sulfur; R18 is halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl, which may contain hetero atoms; unsubstituted or substituted phenyl, unsubstituted or substituted phenylalkyl, substituted heteroaryl, substituted phenoxyalkyl, or substituted heteroaryloxyalkyl; R19 is halogen-substituted alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl, or unsubstituted or substituted phenyl or benzyl; R20, R21 and R22 are each independently of one another unsubstituted or halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, alkynylthio or cycloalkylthio, or unsubstituted or substituted phenyl, phenoxy or phenylthio; R23 and R24 are each independently of the other hydrogen, unsubstituted or halogen-substituted alkyl, alkenyl, alkoxy or alkoxyalkyl, unsubstituted or substituted phenyl or benzyl; or R23 and R24, taken together, form an alkenyl radical, which may contain oxygen as hetero atom; and X is a metal ion equivalent or an ammonium ion; as well as salts and diastereoisomers of the compounds of formula (I); and b) to antagonise the herbicide, an antidotally effective amount of either a quinoline derivative of formula (IIa), wherein R10 is hydrogen, C1-C8alkyl, or C1-C8alkyl which is substituted by C1-C6alkoxy or C3-C6alkenyloxy; and X2 is hydrogen or chloro; of a 1-phenylazole-3-carboxylic acid derivative of formula (IIb), wherein E is nitrogen or methine; R11 is -CCl3 or unsubstituted or halogen-substituted phenyl; R12 and R13 are each independently of the other hydrogen or halogen; and R14 is C1-C4alkyl, are particularly suitable for controlling weeds in crops of cultivated plants, in particular maize and cereals.
    • 选择性除草组合物,用于控制栽培植物作物中的草和杂草,包括:a)除草有效量的式(I)化合物,其中R1是(i),(ii)或(iii)基团; 取代基R 4各自独立地为卤素,硝基,氰基,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 10烷氧基,C 1 -C 4卤代烷氧基,C 3 -C 6烯氧基,C 1 -C 4烷氧基-C 2 -C 4烷氧基,C 3 -C 6炔氧基,C 1 -C 4烷基羰基 C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基,氨基,C1-C4烷基氨基或二C1-C4烷基氨基; R5是(iv)或(v)组; n为0,1,2,3或4; m为0或1,m和n的和为0,1,2,3或4; q为0,1,2或3; X1是氧,硫,-CH2-或-N(R7) - ; 取代基R6各自独立地为C1-C4烷基,卤素,C1-C4卤代烷基,C1-C4烷氧基,C1-C4卤代烷氧基,硝基,氰基,C1-C4烷氧基羰基,氨基,C1-C4烷基氨基或二C1-C4烷基氨基; R 7是氢,C 1 -C 4烷基,甲酰基或C 1 -C 4烷基羰基; A和B各自独立地为氢,烷基,烯基,炔基,烷氧基烷基,烷硫基烷基或环烷基,或取代或未取代的芳基; 或A和B一起形成饱和或不饱和和未取代或取代的单,双,三或多环体系的二价基团; G是氢或-CO-R18(a),(b),-SO2-R20(c),(d),(e)或X(f) L和M各自独立地为其它氧或硫; R18是可以含有杂原子的卤素取代的烷基,烯基,烷氧基烷基,烷硫基烷基,聚烷氧基烷基或环烷基; 未取代或取代的苯基,未取代或取代的苯基烷基,取代的杂芳基,取代的苯氧基烷基或取代的杂芳基烷基; R19是卤素取代的烷基,烯基,烷氧基烷基或聚烷氧基烷基,或未取代或取代的苯基或苄基; R20,R21和R22各自独立地为未取代的或卤素取代的烷基,烷氧基,烷基氨基,二烷基氨基,烷硫基,烯硫基,炔硫基或环烷硫基,或未取代或取代的苯基,苯氧基或苯硫基; R 23和R 24各自独立地为氢,未取代或卤素取代的烷基,烯基,烷氧基或烷氧基烷基,未取代或取代的苯基或苄基; 或R 23和R 24一起形成可以含有氧作为杂原子的烯基; X为金属离子当量或铵离子; 以及式(I)化合物的盐和非对映异构体; 和b)拮抗除草剂,一种解药有效量的式(IIa)的喹啉衍生物,其中R 10是氢,C 1 -C 8烷基或被C 1 -C 6烷氧基或C 3 -C 6烯氧基取代的C 1 -C 8烷基; X2是氢或氯; 的式(IIb)的1-苯基唑-3-羧酸衍生物,其中E是氮或次甲基; R 11是-CCl 3或未取代的或卤素取代的苯基; R 12和R 13各自独立地为氢或卤素; 和R14是C1-C4烷基,特别适用于控制栽培植物,特别是玉米和谷类作物的杂草。
    • 5. 发明申请
    • SELECTIVE HERBICIDAL COMPOSITION
    • 选择性除草剂组合物
    • WO1994000987A2
    • 1994-01-20
    • PCT/EP1993001683
    • 1993-06-30
    • CIBA-GEIGY AGGLOCK, JuttaKERBER, Elmar
    • CIBA-GEIGY AG
    • A01N43/54
    • A01N43/54A01N47/30A01N43/80A01N43/84A01N43/76A01N43/42A01N43/28A01N37/18A01N25/32A01N2300/00
    • A selective herbicidal composition for the control of grasses and weeds in crops of useful plants comprises (a) a herbicidally effective amount of a pyrimidine of formula (I), wherein the substituents are defined in claim 1 and (b) as safener a herbicide-antagonistically effective amount of a quinoline derivative of formula (IIa), wherein R24 is hydrogen or C1-C8alkyl and X2 is hydrogen or chlorine; or of an N-acylsulfamoylphenylurea of formula (IIb), wherein the substituents are defined in claim 1, or of a 1-phenylazole-3-carboxylic acid derivative of formula (IIc), wherein the substituents are defined in claim 1, or of a chloroacetamide of formula (IId), wherein the substituents are defined in claim 1, or of an oxime of formula (IIh), wherein the substituents are defined in claim 1, or of a phenylpyrimidine of formula (IIi), wherein the substituents are defined in claim 1.
    • 用于控制有用植物作物中的草和杂草的选择性除草组合物包括(a)除草有效量的式(I)嘧啶,其中取代基如权利要求1和(b)中定义为安全剂,除草剂 - 拮抗有效量的式(IIa)的喹啉衍生物,其中R24是氢或C1-C8烷基,X2是氢或氯; 或式(IIb)的N-酰基氨磺酰基苯基脲,其中取代基如权利要求1中所定义,或式(IIc)的1-苯基唑-3-羧酸衍生物,其中取代基如权利要求1所定义,或 式(IId)的氯乙酰胺,其中取代基如权利要求1所定义,或式(ⅱh)的肟(其中取代基如权利要求1所定义)或式(ⅱi)的苯基嘧啶,其中取代基是 权利要求1中限定。
    • 10. 发明申请
    • POLYMER-BOUND FLUOROPHORES AS OPTICAL ION SENSORS
    • 聚对苯二甲酸乙二醇酯作为光离子传感器
    • WO1997011067A1
    • 1997-03-27
    • PCT/EP1996003954
    • 1996-09-10
    • CIBA-GEIGY AGALDER, AlexBARNARD, Steven, MarkBECKELMANN, DirkBERGER, JosephWALDNER, Adrian
    • CIBA-GEIGY AG
    • C07D311/82
    • C07D493/10C07D219/08C07D311/82G01N33/533
    • The invention relates to compounds of formula (I), (IIa) or (IIb), wherein R1, R2, R5 and R6 are each independently of one another hydrogen, -SO2-(C1-C6)alkylphenyl, C1-C30alkyl, C1-C30alkyl-CO- or a radical of formula -(CnH2n-O-)m-R10; R3 is hydrogen or -SO2-(C1-C6)alkylphenyl; R4 and R7 are C1-C30 alkylene or a radical of formula -(CnH2n-O-)m-R10; Z is a functional group which is selected from the group consisting of -OH, -SH, -NH2, -COOH, -NCO, -CO-NR8YR9Y, -NH-CO-CH=CH2, -NH-CO-C(CH3)=CH2; R8 and R9 are each independently of the other C1-C30alkylene; R10 is a direct bond or C1-C12alkylene; n is a number from 2 to 6, and m is a number from 1 to 10, with the proviso that the total number of carbon atoms is at most 30; and Y is -OH or -SH. The compounds are used as comonomers for the preparation of copolymer membranes for plasticiser-free ion sensors.
    • 本发明涉及式(I),(IIa)或(IIb)的化合物,其中R 1,R 2,R 5和R 6各自独立地为氢,-SO 2 - (C 1 -C 6)烷基苯基,C 1 -C 30烷基, -C 30烷基-CO-或式 - (C n H 2n -O-)m -R 10的基团; R3是氢或-SO2-(C1-C6)烷基苯基; R4和R7是C1-C30亚烷基或式 - (CnH2n-O-)m -R10的基团; Z是选自-OH,-SH,-NH2,-COOH,-NCO,-CO-NR8YR9Y,-NH-CO-CH = CH2,-NH-CO-C(CH3 )= CH 2; R8和R9各自独立地为C 1 -C 30亚烷基; R10是直接键或C1-C12亚烷基; n为2〜6的数,m为1〜10的数,条件是碳原子数为30以下。 Y为-OH或-SH。 该化合物用作制备用于不含增塑剂的离子传感器的共聚物膜的共聚单体。