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    • 1. 发明申请
    • FLUORESCENT WHITENINIG PIGMENTS
    • 荧光白色素
    • WO2005049682A1
    • 2005-06-02
    • PCT/EP2004/052869
    • 2004-11-08
    • CIBA SPECIALTY CHEMICALS HOLDING INC.DEISENROTH, TedFONDEKAR, Kamalesh, PaiROHRINGER, PeterCUESTA, FabienneJOSHI, Ramachandra, V.KAVISHWAR, Smita, G.SHADAKSHARI, Uma
    • DEISENROTH, TedFONDEKAR, Kamalesh, PaiROHRINGER, PeterCUESTA, FabienneJOSHI, Ramachandra, V.KAVISHWAR, Smita, G.SHADAKSHARI, Uma
    • C08G12/32
    • C08G12/38C08G12/32C09B23/148D21H17/51D21H21/18D21H21/30
    • A whitening pigment comprising the reaction product of (a) a melamine-formaldehyde and/or a melamine-urea polycondensation product and (b) a water-soluble fluorescent whitening agent of the formula (1), wherein each of the two R 1 groups, independent of the other, represents a C 1 -C 6 alkyl or C 1 -C 4 alkyl-O-C 1 -C 4 alkyl residue, which is substituted by one or two -CONH 2 , -CONHC 1 -C 4 alkyl, -COOH, -SO 2 NH 2 , -SO 2 NHC 1 -C 4 alkyl or -NH 2 groups, each of the two R 2 groups, independent of the other, represents hydrogen, C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl or C 1 -C 4 alkoxyC 1 -C 4 alkyl, or R 1 and R 2 together with the nitrogen atom complete a piperazine ring, each of the two X 1 groups, independently, represent -OH, -OC 1 -C 4 alkyl, -Oaryl or the group -NR 3 R 4 , wherein R 3 and R 4 each, independently, represent hydrogen, C 1 -C 4 alkyl, C 2 -C 4 hydroxyalky, C 1 -C 4 alkoxyC 1 -C 4 alkyl, a phenyl, phenyl mono- or disulphonic acid residue or, R 3 and R 4 , together with the nitrogen atom to which they are attached, complete a morpholino, piperidino or pyrrolidino ring or, alternatively, X 1 represents an amino acid residue from which a hydrogen atom has been abstracted from the amino group and M is hydrogen, an alkaline or alkaline earth metal ion, ammonium, mono- di-, tri- or tetra­-substituted C 1 -C 4 alkylammonium or C 2 -C 4 hydroxyalkylammonium or mixtures thereof, a process for preparation of the pigments and the use thereof for the fluorescent whitening of paper.
    • 一种增白颜料,其包含(a)三聚氰胺 - 甲醛和/或三聚氰胺 - 尿素缩聚产物的反应产物和(b)式(1)的水溶性荧光增白剂,其中两个R 1基团, 独立于另一个,表示被一个或两个-CONH 2,-CONHC 1 -C 4烷基,-COOH,-SO 2 NH 2,-SO 2 NHC 1 -C 4烷基或-NH 2取代的C 1 -C 6烷基或C 1 -C 4烷基-O-C 1 -C 4烷基 基团,独立于另一个的两个R 2基团中的每一个表示氢,C 1 -C 4烷基,C 2 -C 4羟烷基或C 1 -C 4烷氧基C 1 -C 4烷基,或者R 1和R 2与氮原子一起完成哌嗪环, 基团独立地表示-OH,-OC1-C4烷基, - 芳基或基团-NR3R4,其中R3和R4各自独立地表示氢,C1-C4烷基,C2-C4羟基,C1-C4烷氧基C1-C4烷基,苯基,苯基 单磺酸或二磺酸残基或R3和R4与它们所连接的氮原子一起形成吗啉代,管 或者X1表示从氨基取代氢原子并且M为氢的碱性氨基酸残基,碱金属或碱土金属离子,单 - ,三 - 或四 - 取代的C 1 -C 4烷基铵或C 2 -C 4羟烷基铵或其混合物,制备颜料的方法及其用于纸的荧光增白的用途。
    • 4. 发明申请
    • WHITENING PIGMENTS
    • 白色颜料
    • WO2003104560A1
    • 2003-12-18
    • PCT/EP2003/005803
    • 2003-06-03
    • CIBA SPECIALTY CHEMICALS HOLDING INC.CUESTA, FabienneNAEF, RolandDEISENROTH, TedROHRINGER, PeterGRIENENBERGER, Marc, RogerSCHROEDER, Serge
    • CUESTA, FabienneNAEF, RolandDEISENROTH, TedROHRINGER, PeterGRIENENBERGER, Marc, RogerSCHROEDER, Serge
    • D21H21/30
    • D06P1/44D06L4/60D06M13/355D21H19/42D21H21/30
    • The present invention relates to novel whitening pigments comprising the reaction product of (a) a melamine-formaldehyde and/or a melamine-urea polycondensation product and (b) a water-soluble fluorescent whitening agent of the formula (1) wherein R 1 represents -OH, -OC 1 -C 4 alkyl, -Oaryl, -NH 2 , -NHC 1 -C 4 alkyl, -N(C 1 -C 4 alkyl) 2 , -NHC 2 -C 4 hydroxyalkyl, -N(C 2 -C 4 hydroxyalkyl)2, -N(C l -C4alkyl)( C 2 -C 4 hydroxyalkyl), -NHC 1 -C 4 alkoxy-C 1 -C 4 alkyl, -N(C 1 -C 4 alkoxy-C 1 -C 4 alkyl) 2 , morpholino, piperidino, pyrrolidino or the residue of an amino acid from which a hydrogen atom has been abstracted from the amino group, R 2 represents -CONH 2 , -CONHC 1 -C 4 alkyl, -COOM, -SO 2 NH 2 or -SO 2 NHC 1 -C 4 alkyl and M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-di-, tri- or tetra-substituted C 1 -C 4 alkylammonium or C 2 -C 4 hydroxyalkylammonium or mixtures thereof, a process for preparation of the whitening pigments and their use for the fluorescent whitening of paper, especially in coating, for the fluorescent whitening and improvement of sun protection factors of textile materials and for improving the aspect of solid detergent compositions. Further disclosed are certain novel fluorescent whitening agents suitable for preparation of the whitening pigments and a process for their preparation.
    • 本发明涉及包含(a)三聚氰胺 - 甲醛和/或三聚氰胺 - 尿素缩聚产物的反应产物和(b)式(1)的水溶性荧光增白剂的新型增白颜料,其中R1表示 - OH,-OC 1 -C 4烷基, - 芳基,-NH 2,-NHC 1 -C 4烷基,-N(C 1 -C 4烷基)2,-NHC 2 -C 4羟烷基,-N(C 2 -C 4羟烷基)2,-N(C 1 -C 4烷基) -C 1-4羟烷基),-NHC 1 -C 4烷氧基-C 1 -C 4烷基,-N(C 1 -C 4烷氧基-C 1 -C 4烷基)2,吗啉代,哌啶子基,吡咯烷子基或从氨基取代氢原子的氨基酸残基 ,R2代表-CON​​H2,-CONHC1-C4烷基,-COOM,-SO2NH2或-SO2NHC1-C4烷基,M为氢,钠,钾,钙,镁,铵,单 - ,三 - 或四 - 取代的C1-C4烷基铵 或C 2 -C 4羟烷基铵或其混合物,制备增白颜料的方法及其用于荧光增白的用途,特别是在涂料中用于荧光灯 改善纺织材料防晒因子,改善固体洗涤​​剂组合物的方面。 还公开了适用于制备增白颜料的某些新型荧光增白剂及其制备方法。
    • 6. 发明申请
    • AMPHOTERIC AND CATIONIC FLUORESCENT WHITENING AGENTS
    • AMPHOTERIC和阳离子荧光白剂
    • WO2003078406A1
    • 2003-09-25
    • PCT/EP2003/002620
    • 2003-03-13
    • CIBA SPECIALTY CHEMICALS HOLDING INC.SCHEFFLER, GoetzROHRINGER, PeterSCHLATTER, RenéDEISENTOTH, Ted
    • SCHEFFLER, GoetzROHRINGER, PeterSCHLATTER, RenéDEISENTOTH, Ted
    • C07D251/68
    • C07D251/50B41M5/5227C07D251/68D21H21/30
    • Abstract A compound of the formula wherein A 1 and A 2 each, independently of one another, represent -S0 3 or -S0 3 M, where M represents hydrogen, an alkaline or alkaline earth metal, ammonium or alkylammonium, B 1 and B 2 each, independently of one another, represent the moiety in which R 1 represents hydrogen, a straight-chain C 1 -C 12 alkyl or branched C 3 -C 12 alkyl group which C 2 -C 12 alkyl and C 3 -C 12 alkyl group, respectively, may be interrupted by one or two heteroatoms and is unsubstituted or substituted by one or two -OH, -OC 1 -C 4 alkyl, -NH 2 , -NHC 1 -C 4 alkyl, -N(C 1 -C 4 alkyl) 2 , -N-pyrrolidino, -N-piperidino, -N-morpholino or -N + (C l ­C 4 alkyl) 3 groups and R 2 represents C 1 -C4alkyl, C 2 -C 4 hydroxyalkyl, -CH 2 CONH 2 , -CH 2 000H or -CH 2 000 C 1 ­C 4 alkyl or, alternatively, B 1 and B 2 each, independently of one another, represent a group of the formula in which R 3 , R 4 and R 5 each, independently of each other, represent hydrogen, C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl, the group -X'-NR 6 R 7 or the group -X'-N + R 3 R 6 R 7 , whereby at least one of the substituents R 4 and/or R 5 represents -X'-NR 6 R 7 or -X'-N + R 3 R 6 R 7 , X and X’each, independently of each other, represent a straight-chain C 2 -C 8 alkylene or branched C 3 -Cealkylene chain, which is unsubstituted or substituted by one or two -0H or -C(=0)- groups, R 6 and R 7 each, independently of each other, represent hydrogen, C 1 -C 4 alkyl or, together with the nitrogen atom to which they are bound, complete a pyrrolidino, piperidino or morpholino ring and R 2 is as previously defined and each D 1 and D 2 , independently of one another, are either defined as for B 1 and B 2 or represent halogen, -NH 2 , C 1 -C 4 monoalkyl- or dialkylamino, said alkyl groups being unsubstituted or substituted by C 1 -C 4 alkoxy, amino, mono- or di-C 1 -C 4 alkylamino or tri-C 1 -C 4 alkylammonium; C 2 -C 4 hydroxyalkylamino, C 2 C 4 di (hydroxyalkyl)amino, anilino, an aniline monosulphonic acid or sulphonamide residue or a 5- or 6-membered, saturated heterocyclic ring or, alternatively, mixtures of compounds of formula (1), a process for their preparation and the use thereof as fluorescent whitening agents, especially for paper.
    • 摘要一种下式的化合物,其中A1和A2各自独立地表示-SO 3或-SO 3 M,其中M表示氢,碱金属或碱土金属,铵或烷基铵,各自独立地为B1和B2, 代表其中R 1表示氢的部分,分别为C 2 -C 12烷基和C 3 -C 12烷基的直链C 1 -C 12烷基或支链C 3 -C 12烷基可被一个或两个杂原子中断并且未被取代或被一个或多个 两个-OH,-OC1-C4烷基,-NH2,-NHC1-C4烷基,-N(C1-C4烷基)2,-N-吡咯烷子基,-N-哌啶子基,-N-吗啉代或-N +(C 1-4烷基)3 基团,R 2表示C1-C4烷基,C2-C4羟烷基,-CH2CONH2,-CH2000H或-CH2000 C1C4烷基,或者B1和B2各自独立地表示下式的基团,其中R3,R4和R5各自, 独立地表示氢,C1-C4烷基,C2-C4羟烷基,-X'-NR6R7基团或-X'-N + R3R6R7基团 通过至少一个取代基R 4和/或R 5表示-X'-NR 6 R 7或-X'-N + R 3 R 6 R 7,X和X'each,彼此独立地表示直链C 2 -C 8亚烷基或支链 未被取代或被一个或两个-OH或-C(= O) - 基团取代的C 3 -C 6亚烷基链,R 6和R 7各自独立地表示氢,C 1 -C 4烷基或与氮原子 它们被结合,完成吡咯烷子基,哌啶子基或吗啉代环,R2如前所定义,并且每个D1和D2彼此独立地被定义为对于B1和B2或表示卤素,-NH2,C1-C4单烷基 - 或 所述烷基是未取代的或被C1-C4烷氧基,氨基,单或二C1-C4烷基氨基或三C1-C4烷基铵取代; C 2 -C 4羟烷基氨基,C 2 -C 4二(羟基烷基)氨基,苯胺基,苯胺单磺酸或磺酰胺残基或5-或6-元饱和杂环,或者,式(1)化合物的混合物,其制备方法 并且其用作荧光增白剂,特别是用于纸。
    • 7. 发明申请
    • OPTICAL BRIGHTENERS FOR INKJETRINTING SUBSTRATES
    • 用于印刷基材的光学增亮剂
    • WO2005105469A1
    • 2005-11-10
    • PCT/EP2005/051827
    • 2005-04-25
    • CIBA SPECIALTY CHEMICALS HOLDING INC.ROHRINGER, PeterHOCHBERG, RobertBECHERER, OliverBIRY, Stéphane
    • ROHRINGER, PeterHOCHBERG, RobertBECHERER, OliverBIRY, Stéphane
    • B41M5/00
    • B41M5/52B41M5/5218B41M5/5227B41M5/5236B41M5/5245B41M5/5254
    • The invention relates to a composition for optical brightening of substrates suitable for ink jet printing, comprising a) a fluorescent whitening agent of the formula (1) : wherein X1, X 2 , X 3 and X 4 each, independent of the other, represent -NR 1 R 2 or -OR 3 , wherein R, and R 2 are, independently of each other, hydrogen, cyano, a C,-C4alkyl group, which is unsubstituted or substituted by one or two of the following residues selected from the group consisting of C,-C 4 alkoxy, hydroxy, carboxyl or a salt thereof (-C02M), cyano, carbonamido, thiol, guanidine, substituted or unsubstituted phenyl, unsubstituted or C,-C 4 alkyl-substituted C 5 ­C8cycloalkyl, halogen, a heterocycle and a sulphonic acid residue, and wherein the carbon chain of an alkyl group having two, three or four carbon atoms can be interrupted by oxygen, or, alternatively, a C5-C7cydoalkyl group or R, and R 2 , together with the nitrogen atom linking them, complete a 5- or 6-membered heterocyclic ring; R 3 represents C,-C 4 alkyl and M represents H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl and/or C 2 -C 4 hydroxyalkyl or mixtures of fluorescent whitening agents of formula (1); b) a cationic polymer; c) water and, optionally, d)at least one pigment and/or at least one further auxiliary, methods of use of the composition and substrates that have been treated therewith.
    • 本发明涉及适用于喷墨印刷的基材的光学增白组合物,其包含a)式(1)的荧光增白剂:其中X1,X2,X3和X4各自独立地表示-NR1R2 或-OR 3,其中R 1和R 2彼此独立地为氢,氰基,C 1 -C 4烷基,其未被取代或被一个或两个选自C 1 -C 4烷氧基的下列残基所取代 ,羟基,羧基或其盐(-CO 2 M),氰基,碳酰氨基,硫醇,胍,取代或未取代的苯基,未取代的或C 1 -C 4烷基取代的C 5 -C 8环烷基,卤素,杂环和磺酸残基, 具有两个,三个或四个碳原子的烷基的链可以被氧中断,或者可替代地,C5-C7环烷基或R和R2与连接它们的氮原子一起形成5-或6-元 杂环 R 3表示C 1〜C 4烷基,M表示被C 1 -C 4烷基和/或C 2 -C 4羟烷基单 - ,二 - ,三 - 或四取代的H,Na,Li,K,Ca,Mg,铵或铵 式(1)的荧光增白剂; b)阳离子聚合物; c)水和任选地d)至少一种颜料和/或至少一种另外的辅助方法,使用已经用其处理的组合物和底物。