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1. 发明申请

WO2004005617A8 TRIAZINYLAMINOSTILBENE DISULPHONIC ACID MIXTURES 审中-公开
标题翻译：三亚氨基磺酸不溶性混合物
公开(公告)号：WO2004005617A8
公开(公告)日：2004-12-29
申请号：PCT/EP0306789
申请日：2003-06-26
申请人： CIBA SC HOLDING AG , CUESTA FABIENNE , METZGER GEORGES , NAEF ROLAND , ROHRINGER PETER , TRABER RAINER HANS
发明人： CUESTA FABIENNE , METZGER GEORGES , NAEF ROLAND , ROHRINGER PETER , TRABER RAINER HANS
IPC分类号： C07D251/70 , C09B57/00 , C09K11/00 , C09K11/06 , C11D3/42 , D06L3/12 , D06M13/358 , D21H17/07 , D21H17/09 , D21H17/57 , D21H19/44 , D21H21/30 , D21H23/04
CPC分类号： D06M13/358 , C09K11/06 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C11D3/42 , D06L4/621 , D06L4/65 , D21H17/07 , D21H17/09 , D21H17/57 , D21H19/44 , D21H21/30 , D21H23/04
摘要： The present invention relates to a fluorescent whitening agent comprising a mixture of two symmetrically and one asymmetrically substituted triazinylaminostilbene disulphonic acids, novel asymmetrically substituted derivatives, a process for their preparations and use of the mixture for whitening synthetic or natural organic materials, especially paper and for the fluorescent whitening and improvement of sun protection factors of textile materials.
摘要翻译：本发明涉及一种荧光增白剂，其包含两种对称和一种不对称取代的三嗪基氨基芪二磺酸的混合物，新的不对称取代的衍生物，其制备方法和使用该混合物以增白合成或天然有机材料，特别是纸和荧光增白和改善纺织材料防晒因素。

2. 发明申请

WO2004046293A8 AMPHOTERIC FLUORESCENT WHITENING AGENTS 审中-公开
标题翻译： AMPHOTERIC荧光白剂
公开(公告)号：WO2004046293A8
公开(公告)日：2004-08-26
申请号：PCT/EP0312583
申请日：2003-11-11
申请人： CIBA SC HOLDING AG , SCHEFFLER GOETZ , ROHRINGER PETER , FLETCHER IAN JOHN
发明人： SCHEFFLER GOETZ , ROHRINGER PETER , FLETCHER IAN JOHN
IPC分类号： C07D251/50 , C07D251/52 , C07D251/54 , C07D251/70 , C09K11/06 , C11D3/42 , D06L3/12 , D21H21/30
CPC分类号： D21H21/30
摘要： The present invention provides novel bis-triazinylaminostilbene amphoteric fluorescent whitening agents, comprising both individual components and mixtures thereof, a process for their preparation, intermediates useful for their prepartion and use of the fluorescent whitening agents for the fluorescents whitening of paper.
摘要翻译：本发明提供了新颖的双 - 三嗪基氨基芪两性荧光增白剂，其包括单独组分及其混合物，其制备方法，可用于其制备的中间体和使用荧光增白剂用于荧光增白纸。

3. 发明申请

WO03078406A8 AMPHOTERIC AND CATIONIC FLUORESCENT WHITENING AGENTS 审中-公开
标题翻译： AMPHOTERIC和阳离子荧光白剂
公开(公告)号：WO03078406A8
公开(公告)日：2004-01-15
申请号：PCT/EP0302620
申请日：2003-03-13
申请人： CIBA SC HOLDING AG , SCHEFFLER GOETZ , ROHRINGER PETER , SCHLATTER RENE , DEISENROTH TED
发明人： SCHEFFLER GOETZ , ROHRINGER PETER , SCHLATTER RENE , DEISENROTH TED
IPC分类号： C07D251/70 , C07D251/50 , C07D251/68 , D21H21/30
CPC分类号： C07D251/50 , B41M5/5227 , C07D251/68 , D21H21/30
摘要： Abstract A compound of the formula wherein A1 and A2 each, independently of one another, represent -S03 or -S03M, where M represents hydrogen, an alkaline or alkaline earth metal, ammonium or alkylammonium, B1 and B2 each, independently of one another, represent the moiety in which R1 represents hydrogen, a straight-chain C1-C12alkyl or branched C3-C12alkyl group which C2-C12alkyl and C3-C12alkyl group, respectively, may be interrupted by one or two heteroatoms and is unsubstituted or substituted by one or two -OH, -OC1-C4alkyl, -NH2, -NHC1-C4alkyl, -N(C1-C4alkyl)2, -N-pyrrolidino, -N-piperidino, -N-morpholino or -N (ClC4alkyl)3 groups and R2 represents C1-C4alkyl, C2-C4hydroxyalkyl, -CH2CONH2, -CH2000H or -CH2000 C1C4alkyl or, alternatively, B1 and B2 each, independently of one another, represent a group of the formula in which R3, R4 and R5 each, independently of each other, represent hydrogen, C1-C4alkyl, C2-C4hydroxyalkyl, the group -X'-NR6R7 or the group -X'-N R3R6R7, whereby at least one of the substituents R4 and/or R5 represents -X'-NR6R7 or -X'-N R3R6R7, X and X'each, independently of each other, represent a straight-chain C2-C8alkylene or branched C3-Cealkylene chain, which is unsubstituted or substituted by one or two -0H or -C(=0)- groups, R6 and R7 each, independently of each other, represent hydrogen, C1-C4alkyl or, together with the nitrogen atom to which they are bound, complete a pyrrolidino, piperidino or morpholino ring and R2 is as previously defined and each D1 and D2, independently of one another, are either defined as for B1 and B2 or represent halogen, -NH2, C1-C4monoalkyl- or dialkylamino, said alkyl groups being unsubstituted or substituted by C1-C4alkoxy, amino, mono- or di-C1-C4alkylamino or tri-C1-C4alkylammonium; C2-C4hydroxyalkylamino, C2 C4di (hydroxyalkyl)amino, anilino, an aniline monosulphonic acid or sulphonamide residue or a 5- or 6-membered, saturated heterocyclic ring or, alternatively, mixtures of compounds of formula (1), a process for their preparation and the use thereof as fluorescent whitening agents, especially for paper.
摘要翻译：摘要一种下式的化合物，其中A1和A2各自独立地表示-SO 3或-SO 3 M，其中M表示氢，碱金属或碱土金属，铵或烷基铵，各自独立地为B1和B2，代表其中R 1表示氢的部分，分别为C 2 -C 12烷基和C 3 -C 12烷基的直链C 1 -C 12烷基或支链C 3 -C 12烷基可被一个或两个杂原子中断并且未被取代或被一个或多个两个-OH，-OC1-C4烷基，-NH2，-NHC1-C4烷基，-N（C1-C4烷基）2，-N-吡咯烷子基，-N-哌啶子基，-N-吗啉代或-N +（C 1-4烷基）3 基团，R 2表示C1-C4烷基，C2-C4羟烷基，-CH2CONH2，-CH2000H或-CH2000 C1C4烷基，或者B1和B2各自独立地表示下式的基团，其中R3，R4和R5各自，独立地表示氢，C1-C4烷基，C2-C4羟烷基，-X'-NR6R7基团或-X'-N + R3R6R7基团通过至少一个取代基R 4和/或R 5表示-X'-NR 6 R 7或-X'-N + R 3 R 6 R 7，X和X'each，彼此独立地表示直链C 2 -C 8亚烷基或支链未被取代或被一个或两个-OH或-C（= O） - 基团取代的C 3 -C 6亚烷基链，R 6和R 7各自独立地表示氢，C 1 -C 4烷基或与氮原子它们被结合，完成吡咯烷子基，哌啶子基或吗啉代环，R2如前所定义，并且每个D1和D2彼此独立地被定义为对于B1和B2或表示卤素，-NH2，C1-C4单烷基 - 或所述烷基是未取代的或被C1-C4烷氧基，氨基，单或二C1-C4烷基氨基或三C1-C4烷基铵取代; C 2 -C 4羟烷基氨基，C 2 -C 4二（羟基烷基）氨基，苯胺基，苯胺单磺酸或磺酰胺残基或5-或6-元饱和杂环，或者式（1）化合物的混合物，其制备方法并且其用作荧光增白剂，特别是用于纸。

4. 发明申请

WO0192217A3 PROCESS FOR THE PREPARATION OF AMIDOSTYRYLSTILBENE-DISULPHONIC ACID COMPOUNDS AND NOVEL AMIDOSTYRYLSTILBENE-DISULPHONIC ACID COMPOUNDS AND THEIR USE AS FLUORESCENT WHITENING AGENTS 审中-公开
标题翻译：制备氨基磺酸盐 - 非水性酸化合物和新型氨基磺酸盐 - 非水性酸化合物的方法及其作为荧光白剂的用途
公开(公告)号：WO0192217A3
公开(公告)日：2002-05-16
申请号：PCT/EP0105866
申请日：2001-05-22
申请人： CIBA SC HOLDING AG , ELIU VICTOR PAUL , ROHRINGER PETER , HAUSER JULIA
发明人： ELIU VICTOR PAUL , ROHRINGER PETER , HAUSER JULIA
IPC分类号： C07C303/22 , C07C303/32 , C07C303/40 , C07C309/51 , C07C311/21 , C07D209/94 , C11D3/42 , D06L3/12 , D21H21/30 , C07C309/32 , C07D207/40 , C07D209/48 , C07D209/76 , C11D3/34
CPC分类号： C11D3/42 , C07C303/22 , C07C303/32 , C07C303/40 , C07D209/94 , D06L4/621 , D21H21/30 , C07C311/21 , C07C309/51
摘要： The present invention relates to a process for the preparation of amidostyrylstilbene-disulphonic acid derivatives represented by formula (1) in which X represents a group of formula (2), (3) or (4), whereby, in formula (2), R1 is hydrogen, C1-C4-alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms, C1-C4-alkyl-C1-C4-alkoxy, phenyl which is unsubstituted or substituted by C1-C4-alkyl, nitro, halogen, SO3M or COOM, amino, mono- C1-C4-alkylamino or phenylamino, whereby the phenyl group is unsubstituted or substituted by C1-C4-alkyl, nitro, halogen, SO3M or COOM; in formula (3), R2 and R3 are hydrogen or together form a 6-membered unsaturated or saturated condensed ring, unbridged or bridged by 1 or 2 carbon atoms, the bond between these substituents being of single- or double-bond character; in formula (4), R4 represents hydrogen, C1-C4-alkyl, nitro, halogen, SO3M or COOM; in formula (1), Y represents phenyl which is unsubstituted or substituted by C1-C4-alkyl, nitro, halogen, SO3M or COOM or represents a heteroaromatic residue and, in any of the above formulae, M represents hydrogen, an alkaline- or alkaline earth-metal cation, or a cation formed from an amine, some of which are new, and use of the novel compounds as fluorescent whitening agents for synthetic or natural organic materials.
摘要翻译：本发明涉及一种制备由式（1）表示的酰氨基苯乙烯基茋 - 二磺酸衍生物的方法，其中X代表式（2），（3）或（4）的基团，其中在式（2）中， R 1是氢，未被取代或被1至3个卤素原子取代的C 1 -C 4烷基，C 1 -C 4烷基-C 1 -C 4烷氧基，未被取代或被C 1 -C 4 - 烷基，硝基，卤素， SO 3 M或COOM，氨基，单C 1 -C 4 - 烷基氨基或苯基氨基，由此苯基未被取代或被C 1 -C 4 - 烷基，硝基，卤素，SO 3 M或COOM取代; 在式（3）中，R 2和R 3是氢或一起形成未被1或2个碳原子未桥连或桥接的6元不饱和或饱和稠环，这些取代基之间的键是单键或双键的; 在式（4）中，R 4表示氢，C 1 -C 4烷基，硝基，卤素，SO 3 M或COOM; 在式（1）中，Y表示未被取代或被C 1 -C 4 - 烷基，硝基，卤素，SO 3 M或COOM取代的苯基，或表示杂芳族残基，并且在上述任一式中，M表示氢，碱或碱土金属阳离子或由胺形成的阳离子，其中一些是新的，并且使用新化合物作为合成或天然有机材料的荧光增白剂。

5. 发明申请

WO2004046293A3 AMPHOTERIC FLUORESCENT WHITENING AGENTS 审中-公开
标题翻译：两性荧光增白剂
公开(公告)号：WO2004046293A3
公开(公告)日：2004-10-14
申请号：PCT/EP0312583
申请日：2003-11-11
申请人： CIBA SC HOLDING AG , SCHEFFLER GOETZ , ROHRINGER PETER , FLETCHER IAN JOHN
发明人： SCHEFFLER GOETZ , ROHRINGER PETER , FLETCHER IAN JOHN
IPC分类号： C07D251/50 , C07D251/52 , C07D251/54 , C07D251/70 , C09K11/06 , C11D3/42 , D06L3/12 , D21H21/30 , C07D251/68 , D06M13/358
CPC分类号： D21H21/30
摘要： The present invention provides novel bis-triazinylaminostilbene amphoteric fluorescent whitening agents, comprising both individual components and mixtures thereof, a process for their preparation, intermediates useful for their prepartion and use of the fluorescent whitening agents for the fluorescents whitening of paper.
摘要翻译：本发明提供新的双 - 三嗪基氨基均二苯乙烯两性荧光增白剂，其包含单独的组分及其混合物，它们的制备方法，用于其制备的中间体和荧光增白剂用于荧光增白纸的用途。

6. 发明申请

WO9746541A3 USE OF TRIAZINE-BASED UVAS FOR USE AS QUENCHERS IN PAPER-MAKING PROCESSES 审中-公开
标题翻译：在纸制造过程中使用基于紫外线的UVAS作为检测器的使用
公开(公告)号：WO9746541A3
公开(公告)日：1998-02-19
申请号：PCT/EP9702606
申请日：1997-05-22
申请人： CIBA GEIGY AG , ROHRINGER PETER , REINEHR DIETER , HOCHBERG ROBERT , METZGER GEORGES
发明人： ROHRINGER PETER , REINEHR DIETER , HOCHBERG ROBERT , METZGER GEORGES
IPC分类号： C07D251/18 , C07D251/14 , C07D251/22 , C07D251/42 , C07D251/48 , C07D251/54 , C07D251/68 , C08K5/3492 , C09B67/00 , C09K3/00 , D06L3/12 , D06M13/358 , D21H21/28 , D21H21/30 , C07D251/40 , C08K5/42
CPC分类号： D21H21/30 , C07D251/42 , C07D251/48 , C07D251/54 , D06L4/614 , D06L4/621 , D06L4/657 , D06M13/358
摘要： The present invention provides a process for the inhibition (quenching) of the effect of anionic fluorescent whitening agents on a substrate, comprising treating the substrate with a triazine UVA compound, some of which are new compounds.
摘要翻译： PCT No.PCT / EP97 / 02606 Sec。 371日期1998年12月2日第 102（e）日期1998年12月2日PCT提交1997年5月22日PCT公布。第WO97 / 46541号公报日期1997年12月11日本发明提供了抑制（淬灭）阴离子荧光增白剂对底物的作用的方法，其包括用三嗪UVA化合物处理底物，其中一些是新化合物。

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