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1. 发明申请

WO2010027819A2 METHODS FOR PRODUCING SODIUM HYPOCHLORITE WITH A THREE-COMPARTMENT APPARATUS CONTAINING A BASIC ANOLYTE 审中-公开
标题翻译：含有碱性抗坏血酸的三室装置生产次氯酸钠的方法
公开(公告)号：WO2010027819A2
公开(公告)日：2010-03-11
申请号：PCT/US2009054953
申请日：2009-08-25
申请人： CERAMATEC INC , PENDELTON JUSTIN , BALAGOPAL SHEKAR , JOSHI ASHOK
发明人： PENDELTON JUSTIN , BALAGOPAL SHEKAR , JOSHI ASHOK
IPC分类号： C25B1/34 , C25B1/26 , C25B9/08
CPC分类号： C25B1/46 , C25B9/08 , C25B15/02
摘要： An electrochemical method for the production of a chlorine-based oxidant product, such as sodium hypochlorite, is disclosed. The method may potentially be used to produce sodium hypochlorite from sea water or low purity un-softened or NaCl-based salt solutions. The method utilizes alkali cation-conductive ceramic membranes, such as membranes based on NaSICON-type materials, and organic polymer membranes in electrochemical cells to produce sodium hypochlorite. Generally, the electrochemical cell includes three compartments and the first compartment contains an anolyte having a basic pH.
摘要翻译：公开了用于生产氯基氧化剂产品如次氯酸钠的电化学方法。该方法可潜在地用于从海水或低纯度未软化或NaCl基盐溶液生产次氯酸钠。该方法使用碱性阳离子导电陶瓷膜，例如基于NaSICON型材料的膜和电化学电池中的有机聚合物膜来生产次氯酸钠。通常，电化学电池包括三个隔室，并且第一隔室包含具有碱性pH的阳极电解液。

2. 发明申请

WO2007082092A2 SYNTHESIS OF BIODIESEL USING ALKALI ION CONDUCTIVE CERAMIC MEMBRANES 审中-公开
标题翻译：使用碱性离子导电陶瓷膜生物降解的合成
公开(公告)号：WO2007082092A2
公开(公告)日：2007-07-19
申请号：PCT/US2007000968
申请日：2007-01-11
申请人： CERAMATEC INC , BALAGOPAL SHEKAR , JOSHI ASHOK , PENDELTON JUSTIN
发明人： BALAGOPAL SHEKAR , JOSHI ASHOK , PENDELTON JUSTIN
IPC分类号： C25B3/00 , C25B9/00
CPC分类号： C25B3/04 , C04B35/16 , C04B35/447 , C04B35/481 , C04B2235/3201 , C04B2235/3224 , C04B2235/3225 , C04B2235/3244 , C04B2235/3286 , C04B2235/3418 , C04B2235/447 , C04B2235/79 , C10G2300/1014 , C10G2300/1018 , C10G2300/805 , C10L1/026 , C25B1/02 , C25B1/04 , C25B9/18 , C25B13/04 , H01M8/1053 , Y02E50/13 , Y02E60/366 , Y02P30/20 , Y02P70/56
摘要： Methods and apparatus for synthesizing biodiesel (40) using alkali alkoxide (30) generated on-site using an electrochemical process are disclosed. The apparatus and methods are disclosed to converting alkali salts of glycerine into glycerine and thereby facilitate the separation of clean glycerine (72) from biodiesel (70). These methods are enabled by the use of alkali ion conductive ceramic membranes (16 and 42) in electrolytic cells (12 and 14).
摘要翻译：公开了使用电化学方法在现场产生的碱性醇盐（30）合成生物柴油（40）的方法和装置。公开了将甘油的碱金属盐转化为甘油，从而促进从生物柴油（70）中分离清洁的甘油（72）的装置和方法。这些方法通过在电解槽（12和14）中使用碱离子传导陶瓷膜（16和42）来实现。

3. 发明申请

WO2009073062A3 ELECTROLYTIC CELL FOR PRODUCING ALKALI ALCOHOLATES 审中-公开
标题翻译：用于生产烷基醇的电解槽
公开(公告)号：WO2009073062A3
公开(公告)日：2009-12-23
申请号：PCT/US2008011382
申请日：2008-10-01
申请人： CERAMATEC INC , JOSHI ASHOK , BALAGOPAL SHEKAR , PENDELTON JUSTIN
发明人： JOSHI ASHOK , BALAGOPAL SHEKAR , PENDELTON JUSTIN
IPC分类号： C25B3/12
CPC分类号： C25B3/04
摘要： Alkali alcoholates are produced from alkali metal salt solutions and alcohol using a three-compartment electrolyte cell (I0) that includes an anolyte compartment (22) configured with an anode (26), a buffer compartment (24), and a catholyte compartment (20) configured with a cathode (28) First and second separators (14 and 16), permeable to alkali ions, are positioned between the anolyte compartment (22) and the catholyte compartment (20) to define a buffer compartment (24) They may be fabpcated of the same or different matenals including, but not limited to, an alkali ion conducting solid electrolyte configured to selectively transport alkali ions, a porous ceramic, or a porous polymer separator matepal The catholyte solution may include an alkali alcoholate and alcohol The anolyte solution may include at least one alkali salt The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.
摘要翻译：碱金属醇盐由碱金属盐溶液和醇使用三室电解质电池（I0）制备，所述三室电解质电池（I0）包括由阳极（26），缓冲隔间（24）和阴极电解液隔室（20）构成的阳极电解液室（22））配置有阴极（28）可透过碱离子的第一和第二分离器（14和16）位于阳极电解液室（22）和阴极电解液室（20）之间，以限定缓冲室（24）。它们可以是制造相同或不同的面膜，包括但不限于配置成选择性输送碱性离子的碱性离子导电固体电解质，多孔陶瓷或多孔聚合物隔膜材料阴极电解液可以包括碱性醇盐和醇阳极电解液可以包括至少一种碱金属盐缓冲溶液可以包括可溶性碱金属盐和醇中的碱金属盐。

4. 发明申请

WO2010027825A3 METHODS FOR PRODUCING SODIUM HYPOCHLORITE WITH A THREE-COMPORTMENT APPARATUS CONTAINING AN ACIDIC ANOLYTE 审中-公开
标题翻译：用含有酸性溶剂的三元装置生产钠盐的方法
公开(公告)号：WO2010027825A3
公开(公告)日：2010-05-20
申请号：PCT/US2009054966
申请日：2009-08-25
申请人： CERAMATEC INC , BHAVARAJU SAI , BALAGOPAL SHEKAR , PENDELTON JUSTIN , JOSHI ASHOK
发明人： BHAVARAJU SAI , BALAGOPAL SHEKAR , PENDELTON JUSTIN , JOSHI ASHOK
IPC分类号： C25B1/34 , C02F1/467
CPC分类号： C25B1/46 , C25B9/08 , C25B15/02
摘要： An electrochemical method for the production of a chlorine-based oxidant product, such as sodium hypochlorite, is disclosed. The method may potentially be used to produce sodium hypochlorite from sea water or low purity un-softened or NaCl-based salt solutions. The method utilizes alkali cation-conductive ceramic membranes, such as membranes based on NaSICON-type materials, and organic polymer membranes in electrochemical cells to produce sodium hypochlorite. Generally, the electrochemical cell includes three compartments and the first compartment contains an anolyte having an acidic pH.
摘要翻译：公开了用于生产氯基氧化剂产物如次氯酸钠的电化学方法。该方法可能潜在地用于从海水或低纯度未软化或NaCl基盐溶液中产生次氯酸钠。该方法利用碱性阳离子导电陶瓷膜，例如基于NaSICON型材料的膜和电化学电池中的有机聚合物膜来产生次氯酸钠。通常，电化学电池包括三个隔室，第一隔室含有具有酸性pH的阳极电解液。

5. 发明申请

WO2007075865A2 ELECTROLYTIC PROCESS TO PRODUCE SODIUM HYPOCHLORITE USING SODIUM ION CONDUCTIVE CERAMIC MEMBRANES 审中-公开
标题翻译：使用钠离子导电陶瓷膜制备钠磷酸盐的电解工艺
公开(公告)号：WO2007075865A2
公开(公告)日：2007-07-05
申请号：PCT/US2006048746
申请日：2006-12-20
申请人： CERAMATEC INC , BALAGOPAL SHEKAR , MALHOTRA VINOD , PENDELTON JUSTIN , REID KATHY JO
发明人： BALAGOPAL SHEKAR , MALHOTRA VINOD , PENDELTON JUSTIN , REID KATHY JO
IPC分类号： C25B1/26
CPC分类号： C25B1/26 , C02F1/4674 , C02F2001/46138 , C02F2201/46115 , C02F2201/46155 , C02F2209/02 , C02F2209/06 , C25B13/04
摘要： An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane (12), such as membranes based on NASICON-type materials, in an electrolytic cell (10). In the process, water is reduced at a cathode (20) to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution (26) are oxidized in the anolyte compartment (14) to produce chlorine gas which reacts with water (28) to produce hypochlorous and hydrochloric acid. Sodium ions (22) are transported from the anolyte compartment (14) to the catholyte compartment (16) across the sodium ion conductive ceramic membrane (12). Sodium hydroxide is transported from the catholyte compartment (16) to the anolyte compartment (14) to produce sodium hypochlorite within the anolyte compartment (14).
摘要翻译：公开了用于生产次氯酸钠的电化学方法。该方法可能潜在地用于从海水或低纯度未软化或NaCl基盐溶液中产生次氯酸钠。该方法在电解槽（10）中使用钠离子传导陶瓷膜（12），例如基于NASICON型材料的膜。在此过程中，阴极（20）的水减少，形成羟基离子和氢气。来自氯化钠溶液（26）的氯离子在阳极电解液室（14）中被氧化以产生与水（28）反应产生次氯酸和盐酸的氯气。钠离子（22）通过钠离子导电陶瓷膜（12）从阳极电解液室（14）输送到阴极电解液隔室（16）。氢氧化钠从阴极电解液室（16）输送到阳极电解液室（14），以在阳极电解液室（14）内产生次氯酸钠。

6. 发明申请

WO2007087423A2 ENVIRONMENTAL AND THERMAL BARRIER COATING TO PROVIDE PROTECTION IN VARIOUS ENVIRONMENTS 审中-公开
标题翻译：环境和热障碍涂层在各种环境中提供保护
公开(公告)号：WO2007087423A2
公开(公告)日：2007-08-02
申请号：PCT/US2007002113
申请日：2007-01-25
申请人： CERAMATEC INC , BALAGOPAL SHEKAR , AKASH AKASH , PENDELTON JUSTIN , KENNEDY KEVIN
发明人： BALAGOPAL SHEKAR , AKASH AKASH , PENDELTON JUSTIN , KENNEDY KEVIN
IPC分类号： B05D1/36
CPC分类号： C23C2/02 , C23C4/02 , C23C8/02 , C23C26/00 , C23C28/042 , C23C28/322 , C23C28/3225 , C23C28/345 , C23C28/3455 , Y02T50/67
摘要： An article (100) and method to provide protection in various environments. The article (100) may include a solid substrate (102) having a first coefficient of thermal expansion, a magnesium oxide-based layer (106) having a second coefficient of thermal expansion, and a bond layer (104) disposed between the solid substrate (102) and the magnesium oxide-based layer (106). The bond layer (104) may include a third coefficient of thermal expansion substantially intermediate the first and second coefficients of thermal expansion to facilitate thermal compatibility between the solid substrate (102) and the magnesium oxide-based layer (106). Further, the magnesium oxide-based layer (106) may be substantially non-porous, thereby providing a hermetic seal limiting gases, particulates, steam and fluid access to the solid substrate (102).
摘要翻译：一种在各种环境中提供保护的文章（100）和方法。制品（100）可以包括具有第一热膨胀系数的固体基材（102），具有第二热膨胀系数的氧化镁基层（106）和设置在固体基材之间的粘合层（104）（102）和氧化镁基层（106）。接合层（104）可以包括基本上介于第一和第二热膨胀系数之间的第三热膨胀系数，以促进固体基底（102）和氧化镁基层（106）之间的热相容性。此外，氧化镁基层（106）可以是基本上无孔的，从而提供限制气体，微粒，蒸汽和流体进入固体基质（102）的气密密封。

7. 发明申请

WO2007087426A2 ENVIRONMENTAL AND THERMAL BARRIER COATING TO PROTECT A PRE-COATED SUBSTRATE 审中-公开
标题翻译：用于保护预涂基材的环境和热障涂层
公开(公告)号：WO2007087426A2
公开(公告)日：2007-08-02
申请号：PCT/US2007002120
申请日：2007-01-25
申请人： CERAMATEC INC , BALAGOPAL SHEKAR , AKASH AKASH , PENDELTON JUSTIN
发明人： BALAGOPAL SHEKAR , AKASH AKASH , PENDELTON JUSTIN
IPC分类号： B05D1/36
CPC分类号： C23C2/02 , C23C4/02 , C23C8/02 , C23C26/00 , C23C28/042 , C23C28/322 , C23C28/3225 , C23C28/345 , C23C28/3455 , Y02T50/67
摘要： An apparatus (100) and method to improve protection of a pre-coated substrate(102) in a high-temperature aqueous environment. The apparatus (100 may include a pre-coated substrate (012) having a substantially porous vapor-deposited coating (104) and one or more non-porous ceramic oxide-based layers (106) applied to the pre-coated substrate (102) by a non-vapor deposition technique. The coefficient of thermal expansion corresponding to the non-porous ceramic oxide-based layer (106) may substantially match the thermal expansion coefficient of the vapor-deposited coating (104) to facilitate thermal compatibility between the two. Further, the non-porous ceramic oxide-based layer (106) may infiltrate pores of the substantially porous vapor-deposited coating (104) to provide a well-bonded hermetic seal that limits fluid access to the pre-coated substrate (102) through the substantially porous vapor-deposited coating (104).
摘要翻译：一种改善在高温水溶液环境中对预涂底物（102）的保护的装置（100）和方法。该设备（100）可以包括具有基本上多孔的气相沉积涂层（104）和施加到预涂覆的基底（102）上的一个或多个无孔陶瓷氧化物基层（106）的预涂底物（012）对应于无孔陶瓷氧化物基层（106）的热膨胀系数可基本上与气相沉积涂层（104）的热膨胀系数相匹配，以促进两者之间的热相容性此外，无孔陶瓷氧化物基层（106）可以渗透基本上多孔的蒸汽沉积涂层（104）的孔隙，以提供良好粘合的气密密封，其限制流体进入预涂布的基底（102）通过基本上多孔的气相沉积涂层（104）。

8. 发明申请

WO2007025280A3 ELECTROCHEMICAL CELL FOR THE PRODUCTION OF SYNTHESIS GAS USING ATMOSPHERIC AIR AND WATER 审中-公开
标题翻译：利用大气和水生成合成气的电化学电池
公开(公告)号：WO2007025280A3
公开(公告)日：2007-09-20
申请号：PCT/US2006033640
申请日：2006-08-25
申请人： CERAMATEC INC , HARTVIGSEN JOSEPH , JOSHI ASHOK V , ELANGOVAN S , BALAGOPAL SHEKAR , GORDON JOHN HOWARD , HOLLIST MICHELE
发明人： HARTVIGSEN JOSEPH , JOSHI ASHOK V , ELANGOVAN S , BALAGOPAL SHEKAR , GORDON JOHN HOWARD , HOLLIST MICHELE
IPC分类号： H01M8/00 , C25B9/00 , C25C7/00
CPC分类号： C25B1/02 , C25B1/00 , C25B1/04 , C25B9/206 , H01M2008/1293 , Y02E60/364 , Y02E60/366
摘要： A method is provided for synthesizing synthesis gas from carbon dioxide obtained from atmospheric air or other available carbon dioxide source and water using a sodium- conducting electrochemical cell (10). Synthesis gas is also produced by the coelectrolysis of carbon dioxide and steam in a solid oxide fuel cell or solid oxide electrolytic cell. The synthesis gas produced may then be further processed and eventually converted into a liquid fuel suitable for transportation or other applications.
摘要翻译：提供了一种用于从使用导电钠电化学电池（10）从大气或其他可用二氧化碳源和水获得的二氧化碳合成合成气的方法。合成气也通过在固体氧化物燃料电池或固体氧化物电解池中共二氧化碳和蒸汽的共电解产生。所产生的合成气然后可以被进一步处理并且最终转化为适用于运输或其他应用的液体燃料。

9. 发明申请

WO2010151468A3 ALKALI METAL SUPER IONIC CONDUCTING CERAMIC 审中-公开
标题翻译： ALKALI金属超离子导电陶瓷
公开(公告)号：WO2010151468A3
公开(公告)日：2011-04-07
申请号：PCT/US2010038877
申请日：2010-06-16
申请人： BALAGOPAL SHEKAR , FLINDERS MARC , CERAMATEC INC
发明人： BALAGOPAL SHEKAR , FLINDERS MARC
IPC分类号： C04B35/01 , B01D17/06 , B01D71/02 , C04B35/14 , C04B35/447
CPC分类号： C04B35/16 , C01B25/38 , C04B35/19 , C04B35/462 , C04B35/481 , C04B2235/3201 , C04B2235/3203 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3241 , C04B2235/3244 , C04B2235/3272 , C04B2235/3286 , C04B2235/3291 , C04B2235/447 , C04B2235/76 , C04B2235/77 , C04B2235/9692 , H01M10/054
摘要： Metal ion conducting ceramic materials are disclosed having characteristics of high ion conductivity for certain alkali and monovalent metal ions at low temperatures, high selectivity for the metal ions, good current efficiency and stability in water and corrosive media under static and electrochemical conditions. The metal ion conducting ceramic materials are fabricated to be deficient in the metal ion. One general formulation of the metal ion conducting ceramic materials is Me1+x+y-zMIII yMIV 2-ySixP3-xO12-z/2, wherein Me is Na+, Li+, K+, Rb+, Cs+, Ag+, or mixtures thereof, 2.0 = x = 2.4, 0.0 = y = 1.0, and 0.05 = z = 0.9, where MIII is Al3+, Ga3+, Cr3+, Sc3+, Fe3+, In3+, Yb3+, Y3+, or mixtures thereof and MIV is Ti4+, Zr4+, Hf4+, or mixtures thereof.
摘要翻译：公开了金属离子传导陶瓷材料，其在低温下对于某些碱金属离子和一价金属离子具有高离子传导性，对于金属离子具有高选择性，在静态和电化学条件下具有良好的电流效率以及在水中和腐蚀性介质中的稳定性。金属离子导电陶瓷材料被制造为缺乏金属离子。金属离子导电陶瓷材料的一般公式是Me1 + x + y-zMIII yMIV 2-ySixP3-xO12-z / 2，其中Me是Na +，Li +，K +，Rb +，Cs +，Ag +或其混合物，2.0 = x = 2.4,0.0 = y = 1.0，0.05 = z = 0.9，其中M III为Al3 +，Ga3 +，Cr3 +，Sc3 +，Fe3 +，In3 +，Yb3 +，Y3 +或其混合物，MIV为Ti4 +，Zr4 +，Hf4 + 它们。

10. 发明申请

WO2011022162A3 SENSOR TO MEASURE A CONCENTRATION OF ALKALI ALCOHOLATE 审中-公开
标题翻译：传感器测量碱性酒精的浓度
公开(公告)号：WO2011022162A3
公开(公告)日：2011-04-14
申请号：PCT/US2010042940
申请日：2010-07-22
申请人： CERAMATEC INC , BHAVARAJU SAI , PENDLETON JUSTIN , BALAGOPAL SHEKAR , WALL PETER
发明人： BHAVARAJU SAI , PENDLETON JUSTIN , BALAGOPAL SHEKAR , WALL PETER
IPC分类号： G01N27/31 , G01N27/49
CPC分类号： G01N27/49
摘要： A sodium sensor to measure a concentration of sodium methylate in methanol. The sensor assembly includes a solid alkali ion conducting membrane (102), a reference electrode (110), and a measurement electrode (108). The solid alkali ion conducting membrane (102) transports ions between two alkali-containing solutions, including an aqueous solution (106) and a non-aqueous solution (104). The reference electrode (110) is at least partially within an alkali halide solution of a known alkali concentration on a first side of the solid alkali ion conducting membrane (102). The measurement electrode (108) is on a second side of the solid alkali ion conducting membrane (102). The measurement electrode (108) exhibits a measurable electrical characteristic corresponding to a measured alkali concentration within the non-aqueous solution (104), to which the measurement electrode (108) is exposed.
摘要翻译：用于测量甲醇钠甲醇浓度的钠传感器。传感器组件包括固体碱离子传导膜（102），参比电极（110）和测量电极（108）。固体碱离子传导膜（102）在包含水溶液（106）和非水溶液（104）的两种含碱溶液之间输送离子。参考电极（110）至少部分地位于固体碱离子传导膜（102）的第一侧上已知碱浓度的碱金属卤化物溶液中。测量电极（108）位于固体碱离子传导膜（102）的第二侧上。测量电极（108）显示对应于测量电极（108）暴露于的非水溶液（104）内的测量的碱浓度的可测量电特性。

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