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1. 发明申请

WO2011123817A2 PRODUCTION OF ALKALI BICARBONATE AND ALKALI HYDROXIDE FROM ALKALI CARBONATE IN AN ELECTROLYTIC CELL 审中-公开
标题翻译：在电解槽中从碱式碳酸钙生产碱性二碳酸酯和碱金属氢氧化物
公开(公告)号：WO2011123817A2
公开(公告)日：2011-10-06
申请号：PCT/US2011/030996
申请日：2011-04-01
申请人： CERAMATEC, INC. , PENDLETON, Justin , JOSHI, Ashok , BHAVARAJU, Sai
发明人： PENDLETON, Justin , JOSHI, Ashok , BHAVARAJU, Sai
IPC分类号： C25B1/18 , C25B3/00 , C07C29/70 , C07C31/28 , C01D7/10
CPC分类号： C25B1/14 , C25B1/16 , C25B3/04 , Y02P20/132
摘要： Alkali bicarbonate is synthesized in an electrolytic cell (100) from alkali carbonate. The electrolytic cell (100) includes an alkali ion conductive membrane (110) positioned between an anolyte compartment (112) configured with an anode (116) and a catholyte compartment (114) configured with a cathode (118). The alkali conductive membrane (110) selectively transports alkali ions (120) and prevents the transport of anions produced in the catholyte compartment. An aqueous alkali carbonate solution is introduced into the anolyte compartment (112) and electrolyzed at the anode (116) to produce carbon dioxide and/or hydrogen ions which react with alkali carbonate to produce alkali bicarbonate. The alkali bicarbonate is recovered by filtration or other separation techniques. When the catholyte solution includes water, pure alkali hydroxide is produced. When the catholyte solution includes methanol, pure alkali methoxide is produced.
摘要翻译：在碱金属碳酸盐的电解池（100）中合成碱金属碳酸氢盐。电解池（100）包括位于由阳极（116）构成的阳极电解液室（112）和配置有阴极（118）的阴极电解液室（114）之间的碱金属离子传导膜（110）。碱性导电膜（110）选择性地输送碱离子（120）并防止在阴极电解液室中产生的阴离子的运输。将碱金属碳酸盐水溶液引入阳极电解液室（112）中并在阳极（116）处电解以产生与碱金属碳酸盐反应产生碱式碳酸氢盐的二氧化碳和/或氢离子。通过过滤或其他分离技术回收碱金属碳酸氢盐。当阴极电解液包含水时，产生纯碱氢氧化物。当阴极电解液包含甲醇时，产生纯碱金属甲醇盐。

2. 发明申请

WO2012106468A3 NICKEL-METAL HYDRIDE/HYDROGEN HYBRID BATTERY USING ALKALI ION CONDUCTING SEPARATOR 审中-公开
公开(公告)号：WO2012106468A3
公开(公告)日：2012-08-09
申请号：PCT/US2012/023541
申请日：2012-02-01
申请人： CERAMATEC, INC. , JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai
发明人： JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai
IPC分类号： H01M12/06 , H01M10/39 , H01M2/14
摘要： A nickel-metal hydride (hydrogen) hybrid storage battery comprising a positive electrode containing nickel hydroxide, a combination negative electrode containing a hydrogen storage alloy electrode and a reversible hydrogen electrode, an alkaline electrolyte, and an alkali conducting separator disposed between the positive electrode and the negative electrode. The alkali conducting separator may be a substantially non-porous ion conducting material wherein the alkali conducted is Na, K, or Li. A method of charging and discharging such a hybrid battery is also disclosed.

3. 发明申请

WO2012048280A2 ELECTROCHEMICAL SYSTEMS AND METHODS FOR OPERATING ELECTROCHEMICAL CELL WITH AN ACIDIC ANOLYTE 审中-公开
标题翻译：用酸性抗坏血酸操作电化学电池的电化学系统和方法
公开(公告)号：WO2012048280A2
公开(公告)日：2012-04-12
申请号：PCT/US2011/055458
申请日：2011-10-07
申请人： CERAMATEC, INC. , BHAVARAJU, Sai , JOSHI, Ashok
发明人： BHAVARAJU, Sai , JOSHI, Ashok
IPC分类号： C25B9/08 , C25B1/24 , C25B13/04
CPC分类号： C25B9/08 , C02F1/4674 , C02F2001/46138 , C02F2001/46185 , C02F2101/101 , C02F2201/46115 , C02F2201/46135 , C02F2201/4618 , C02F2209/06 , C25B1/10 , C25B3/00 , C25B15/02 , C25B15/08 , Y02E60/366
摘要： An electrochemical cell (50) having a cation-conductive ceramic membrane (56) and an acidic anolyte. Generally, the cell (50) includes a catholyte compartment (54) and an anolyte compartment (52) that are separated by a cation-conductive membrane (56). While the catholyte compartment (54) houses a primary cathode (60), the anolyte compartment (52) houses an anode (58) and a secondary cathode (62). In some cases, a current is passed through the electrodes to cause the secondary cathode (62) to evolve hydrogen gas. In other cases, hydrogen peroxide is channeled between the secondary cathode (62) and the membrane (56) to form hydroxyl ions. In yet other cases, the cell (50) includes a diffusion membrane disposed between the secondary cathode (62) and the anode (58). In each of the aforementioned cases, the cell functions to maintain the pH of a fluid contacting the membrane (56) at an acceptably high level.
摘要翻译：具有阳离子导电陶瓷膜（56）和酸性阳极电解液的电化学电池（50）。通常，电解槽（50）包括由阳离子传导膜（56）分隔的阴极电解液隔室（54）和阳极电解液隔室（52）。当阴极电解液隔室（54）容纳主阴极（60）时，阳极电解液隔室（52）容纳阳极（58）和次级阴极（62）。在一些情况下，电流流过电极以使次级阴极（62）放出氢气。在其他情况下，过氧化氢在次级阴极（62）和膜（56）之间引导以形成羟基离子。在其他情况下，电池（50）包括设置在次级阴极（62）和阳极（58）之间的扩散膜。在上述每种情况下，细胞的作用是将接触膜（56）的流体的pH维持在可接受的高水平。

4. 发明申请

WO2009097445A2 ZINC ANODE BATTERY USING ALKALI ION CONDUCTING SEPARATOR 审中-公开
标题翻译：采用碱性离子导体分离器的锌阳极电池
公开(公告)号：WO2009097445A2
公开(公告)日：2009-08-06
申请号：PCT/US2009/032458
申请日：2009-01-29
申请人： CERAMATEC, INC , JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai
发明人： JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai
IPC分类号： H01M2/16 , H01M2/18 , H01M10/28 , H01M4/24
CPC分类号： H01M10/36 , C04B35/447 , C04B2235/3203 , C04B2235/3217 , C04B2235/3232 , H01M10/39
摘要： A zinc anode storage battery (50) comprising a first electrode (54) containing zinc or a zinc alloy, a second electrode (52) containing an oxidizing material capable of electrochemical reduction by zinc, an alkaline electrolyte, and a substantially non-porous, alkali-ion conducting separator (56) provided between the first electrode (54) and the second electrode (52). The alkali conducting separator (56) may be a solid alkali metal ion super ion conducting material, wherein the alkali metal is Na, K, or Li.
摘要翻译：锌阳极蓄电池（50）包括含有锌或锌合金的第一电极（54），含有能够被锌电化学还原的氧化材料的第二电极（52），碱性电解质以及设置在第一电极（54）和第二电极（52）之间的基本上无孔的碱金属离子导电分离器（56）。碱传导分离器（56）可以是固体碱金属离子超离子传导材料，其中碱金属是Na，K或Li。

5. 发明申请

WO2011011492A3 DECARBOXYLATION CELL FOR PRODUCTION OF COUPLED RADICAL PRODUCTS 审中-公开
公开(公告)号：WO2011011492A3
公开(公告)日：2011-01-27
申请号：PCT/US2010/042715
申请日：2010-07-21
申请人： CERAMATEC, INC. , BHAVARAJU, Sai , KARANJIKAR, Mukund , JOSHI, Ashok , HUNT, Joel , CHITTA, Pallavi
发明人： BHAVARAJU, Sai , KARANJIKAR, Mukund , JOSHI, Ashok , HUNT, Joel , CHITTA, Pallavi
IPC分类号： C25B9/08 , C25B3/10 , C07C1/207
摘要： An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.

6. 发明申请

WO2009070541A3 NICKEL-METAL HYDRIDE BATTERY USING ALKALI ION CONDUCTING SEPARATOR 审中-公开
公开(公告)号：WO2009070541A3
公开(公告)日：2009-06-04
申请号：PCT/US2008/084572
申请日：2008-11-24
申请人： CERAMATEC, INC , JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai , WATKINS, John , FONDA, David
发明人： JOSHI, Ashok , GORDON, John , BHAVARAJU, Sai , WATKINS, John
IPC分类号： H01M10/34 , H01M2/16 , H01M10/28 , H01M4/24
摘要： A nickel-metal hydride storage battery (50) comprising a positive electrode (52) containing nickel hydroxide, a negative electrode (54) containing a hydrogen absorbing alloy, an alkaline electrolyte, and an alkali conducting separator (56) provided between the positive electrode (52) and the negative electrode (54). The alkali conducting separator (56) may be a solid alkali metal ion super ion conducting material, wherein the alkali metal is Na, K, or Li.

7. 发明申请

WO2011011537A3 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS FROM BIOMASS 审中-公开
公开(公告)号：WO2011011537A3
公开(公告)日：2011-01-27
申请号：PCT/US2010/042780
申请日：2010-07-21
申请人： CERAMATEC, INC. , KARANJIKAR, Mukund , BHAVARAJU, Sai , JOSHI, Ashok , CHITTA, Pallavi , HUNT, David
发明人： KARANJIKAR, Mukund , BHAVARAJU, Sai , JOSHI, Ashok , CHITTA, Pallavi , HUNT, David
IPC分类号： C25B3/10 , C07C1/207 , C25B9/08
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.

8. 发明申请

WO2010027825A2 METHODS FOR PRODUCING SODIUM HYPOCHLORITE WITH A THREE-COMPORTMENT APPARATUS CONTAINING AN ACIDIC ANOLYTE 审中-公开
标题翻译：用含有酸性抗坏血酸的三元装置生产次氯酸钠的方法
公开(公告)号：WO2010027825A2
公开(公告)日：2010-03-11
申请号：PCT/US2009/054966
申请日：2009-08-25
申请人： CERAMATEC, INC. , BHAVARAJU, Sai , BALAGOPAL, Shekar , PENDELTON, Justin , JOSHI, Ashok
发明人： BHAVARAJU, Sai , BALAGOPAL, Shekar , PENDELTON, Justin , JOSHI, Ashok
IPC分类号： C25B1/34 , C02F1/467
CPC分类号： C25B1/46 , C25B9/08 , C25B15/02
摘要： An electrochemical method for the production of a chlorine-based oxidant product, such as sodium hypochlorite, is disclosed. The method may potentially be used to produce sodium hypochlorite from sea water or low purity un-softened or NaCl-based salt solutions. The method utilizes alkali cation-conductive ceramic membranes, such as membranes based on NaSICON-type materials, and organic polymer membranes in electrochemical cells to produce sodium hypochlorite. Generally, the electrochemical cell includes three compartments and the first compartment contains an anolyte having an acidic pH.
摘要翻译：公开了一种用于生产氯基氧化剂产品如次氯酸钠的电化学方法。该方法可潜在地用于从海水或低纯度未软化或NaCl基盐溶液生产次氯酸钠。该方法使用碱性阳离子导电陶瓷膜，例如基于NaSICON型材料的膜和电化学电池中的有机聚合物膜来生产次氯酸钠。通常，电化学电池包括三个室，第一室包含具有酸性pH的阳极电解液。

9. 发明申请

WO2009059315A1 ELECTROLYTIC PROCESS TO SEPARATE ALKALI METAL IONS FROM ALKALI SALTS OF GLYCERINE 审中-公开
标题翻译：从酸碱盐中分离碱金属离子的电解方法
公开(公告)号：WO2009059315A1
公开(公告)日：2009-05-07
申请号：PCT/US2008/082278
申请日：2008-11-03
申请人： CERAMATEC, INC , BALAGOPAL, Shekar , PENDELTON, Justin , JOSHI, Ashok , BHAVARAJU, Sai
发明人： BALAGOPAL, Shekar , PENDELTON, Justin , JOSHI, Ashok , BHAVARAJU, Sai
IPC分类号： C25B1/46 , B01D61/42 , C10L1/30
CPC分类号： C25B3/00 , B01D61/44 , C25B1/02
摘要： Methods and apparatus for separating alkali metal ions from alkali salts of glycerine to thereby form clean glycerine. These methods are enabled by the use of alkali ion conductive membranes (12) in electrolytic cells (10) that are chemically stable in low pH conditions. The alkali ion conductive membrane (12) preferably includes a chemically stable ionic-selective polymer membrane. A layered composite of a chemically stable ionic-selective polymer and a cation-conductive ceramic membrane is disclosed.
摘要翻译：将碱金属离子与甘油碱性盐分离从而形成干净的甘油的方法和设备。这些方法通过在低pH条件下化学稳定的电解槽（10）中使用碱离子传导膜（12）来实现。碱性离子传导膜（12）优选包括化学稳定的离子选择性聚合物膜。公开了一种化学稳定的离子选择性聚合物和阳离子导电陶瓷膜的层状复合材料。

10. 发明申请

WO2012129472A2 AMMONIA SYNTHESIS USING LITHIUM ION CONDUCTIVE MEMBRANE 审中-公开
标题翻译：使用锂离子导电膜的氨合成合成
公开(公告)号：WO2012129472A2
公开(公告)日：2012-09-27
申请号：PCT/US2012/030264
申请日：2012-03-23
申请人： CERAMATEC, INC. , JOSHI, Ashok , BHAVARAJU, Sai
发明人： JOSHI, Ashok , BHAVARAJU, Sai
IPC分类号： C01C1/04 , B01J23/745 , C07B61/00
CPC分类号： C25B1/00 , C25B9/08 , C25B11/035 , C25B13/04
摘要： Ammonia is synthesized using electrochemical and non-electrochemical reactions. The electrochemical reactions occur in an electrolytic cell (110) having a lithium ion conductive membrane (112) that divides the electrochemical cell (110) into an anolyte compartment (114) and a catholyte compartment (116). The catholyte compartment (116) includes a porous cathode (120) closely associated with the lithium ion conductive membrane (112). The overall electrochemical reaction is: 6LiOH + N 2 → Li 3 N ( s ) + 3H 2 O + 3/2O 2 . The nitrogen (128) may be produced by a nitrogen generator (130). The non-electrochemical reaction involves reacting lithium nitride with water and/or steam as follows: Li 3 N ( s ) + 3H 2 O→ 3LiOH + NH 3 ( g ). The ammonia is vented and collected. The lithium hydroxide is preferably recycled and introduced into the anolyte compartment. The electrolytic cell (110) is shut down prior to reacting the lithium nitride with water. The cathode (120) is preferably dried prior to start up of the electrolytic cell (1 10) and electrolyzing Li + and N 2 at the cathode (120).
摘要翻译：使用电化学和非电化学反应合成氨。电化学反应发生在具有将电化学电池（110）分成阳极电解液室（114）和阴极电解液隔室（116）的锂离子传导膜（112）的电解槽（110）中。阴极电解液隔室（116）包括与锂离子传导膜（112）紧密相关的多孔阴极（120）。整个电化学反应是：6LiOH + N2？ Li 3 N（s）+ 3H 2 O + 3 / 2O 2。氮气（128）可以由氮气发生器（130）产生。非电化学反应包括使氮化钠与水和/或蒸汽反应如下：Li 3 N（s）+ 3H 2 O 3LiOH + NH3（g）。将氨排出并收集。优选将氢氧化锂再循环并引入阳极电解液室。在使氮化锂与水反应之前关闭电解池（110）。阴极（120）优选在电解槽（110）启动之前被干燥并在阴极（120）处电解Li +和N 2。

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