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    • 1. 发明申请
    • PREPARATION OF COMPONENTS FOR TRANSPORTATION FUELS
    • 运输燃料组分的准备
    • WO02062927A3
    • 2002-11-14
    • PCT/US0201439
    • 2002-01-17
    • BP CORP NORTH AMERICA INC
    • MORRIS GEORGE ELUCY ANDREW RGONG WILLIAM HREGALBUTO MONICA CRISTINAHUFF GEORGE A JR
    • C10G67/12C10G27/12
    • C10G67/12
    • Economical processes are disclosed for the production of component for refinery blending of transportation fuels by selective oxidation of feedstocks comprising a mixture of hydrocarbons, sulfur-containing and nitrogen-containing organic compounds. Oxidation feedstock is contacted with a soluble quaternary ammonium salt containing halogen, suflate, or bisulfate anion, and an immiscible aqueous phase comprising a source of hydrogen peroxide, and at least one member of the group consisting of phosphomolybdic acid and phosphotungstic acid, in a liquid reaction mixture under conditions suitable for reaction of one or more of the sulfur-containing and/or nitrogen-containing organic compounds. Blending components containing less sulfur and/or less nitrogen than the oxidation feedstock are recovered from the reaction mixture. Advantageously, at least a portion of the immiscible acid-containing phase is recycled to the oxidation.
    • 公开了用于通过选择性氧化包含烃,含硫和含氮有机化合物的混合物的原料来生产用于炼油厂混合运输燃料的组件的经济过程。 氧化原料与含有卤素,磺酸盐或硫酸氢根阴离子的可溶性季铵盐和含有过氧化氢源的不混溶性水相以及磷钼酸和磷钨酸中的至少一员在液体中接触 反应混合物在适合于一种或多种含硫和/或含氮有机化合物的反应的条件下反应。 从反应混合物中回收含有比氧化原料少的硫和/或少于氮的组分。 有利地,至少一部分不混溶的含酸相被循环至氧化。