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1. 发明申请

WO0242760A3 SENSOR ELEMENT OF A GAS SENSOR 审中-公开
标题翻译：气体传感器的传感器元件
公开(公告)号：WO0242760A3
公开(公告)日：2002-12-12
申请号：PCT/DE0104353
申请日：2001-11-20
申请人： BOSCH GMBH ROBERT , CRAMER BERNDT , SPRINGHORN CARSTEN , HEIMANN DETLEF , OEHLER GUDRUN , SCHUELE MARGRET , SCHUMANN BERND , OCHS THORSTEN , THIEMANN-HANDLER SABINE
发明人： CRAMER BERNDT , SPRINGHORN CARSTEN , HEIMANN DETLEF , OEHLER GUDRUN , SCHUELE MARGRET , SCHUMANN BERND , OCHS THORSTEN , THIEMANN-HANDLER SABINE
IPC分类号： G01N27/419 , G01N27/407
CPC分类号： G01N27/419
摘要： The invention relates to a sensor element of a gas sensor, said sensor element being used to determine the concentration of at least one component of a gas mixture, in particular in the exhaust gases of internal combustion engines. The element contains at least two electrodes (22, 23), which are arranged in an internal gas chamber (15) that is in direct contact with the gas mixture, one electrode (22) consisting of a first material and the second electrode (23) consisting of a second material. The inner gas chamber (15) contains a physically and/or chemically active agent (34, 36, 38, 39) for preventing a metallic diffusion between the two electrodes (22, 23).
摘要翻译：描述了气体传感器的传感器元件，其用于确定气体混合物的至少一种成分的浓度，特别是在内燃机的排气中。它包括布置在与气体混合物直接接触的内部气体空间（15）中的至少两个电极（22,23），一个电极（22）包含第一材料并且第二电极（23）包含第二材料，内部气体空间（15）包含用于避免电极（22,23）之间的金属扩散的物理和/或化学作用装置（34,36,38,39）。

2. 发明申请

WO0057169A3 ELECTROCHEMICAL GAS SENSOR 审中-公开
标题翻译：电化学气体传感器
公开(公告)号：WO0057169A3
公开(公告)日：2001-07-19
申请号：PCT/DE0000769
申请日：2000-03-11
申请人： BOSCH GMBH ROBERT , BLOEMER BERNHARD , STROHMAIER RAINER , SPRINGHORN CARSTEN , HEIMANN DETLEF , RENZ HANS JOERG , NEUMANN HARALD , SCHUELE MARGRET , SCHUMANN BERND , MOSER THOMAS , THIEMANN HANDLER SABINE
发明人： BLOEMER BERNHARD , STROHMAIER RAINER , SPRINGHORN CARSTEN , HEIMANN DETLEF , RENZ HANS-JOERG , NEUMANN HARALD , SCHUELE MARGRET , SCHUMANN BERND , MOSER THOMAS , THIEMANN-HANDLER SABINE
IPC分类号： G01N27/41 , G01N27/30 , G01N27/416 , G01N27/417 , G01N27/419
CPC分类号： G01N27/417
摘要： The invention relates to an electrochemical gas sensor for determining the concentration of gas components in a gas mixture, especially for determining NOx and HC. The gas sensor comprises a first chamber for the gas to be measured (13) which is connected to said gas; and a second chamber for the gas to be measured (15) which is connected to the first chamber for the gas to be measured (13) by a connecting channel (17). A first electrode (27) and a second electrode (31) which are each situated in the first chamber for the gas to be measured (13), at least one third electrode (35) which is situated in the second chamber for the gas to be measured (15) and at least one fourth electrode (33) are also provided. The two chambers for the gas to be measured (13, 15) are arranged in superposed, layered levels and are separated from each other by at least one layer which conducts oxygen ions. The connecting channel (17) runs through the oxygen ion-conducting layer.
摘要翻译：它提出了一种电化学气体传感器，用于确定气体成分的浓度的气体混合物，特别是用于NOx和HC的确定。所述气体传感器包括第一测量气体空间（13）中的连接与测量气体连通，并且其通过连接通道（17）连接到所述第一测量气体室（13）的第二测量气体室（15）。此外，第一电极（27）和分别设置在所述第一测量气体空间（13）的第二电极（31），和至少一个在所述第二测量气体室（15），设置第三电极（35）和至少一个第四电极（33）提供。两个测量气体室（13，15）是通过在叠置层平面彼此分离的至少一个氧离子传导层布置，所述连接通道（17）通过氧离子传导层领导。

3. 发明申请

WO0123729A3 METHOD FOR MONITORING THE FUNCTION OF A GAS SENSOR AND/OR FOR REGENERATING THE SAME 审中-公开
标题翻译：用于功能监测和/或再生的加西索的方法
公开(公告)号：WO0123729A3
公开(公告)日：2001-08-16
申请号：PCT/DE0003383
申请日：2000-09-28
申请人： BOSCH GMBH ROBERT , SPRINGHORN CARSTEN , SCHUMANN BERND , THIEMANN HANDLER SABINE
发明人： SPRINGHORN CARSTEN , SCHUMANN BERND , THIEMANN-HANDLER SABINE
IPC分类号： G01N27/419 , G01N27/416 , G01N27/417
CPC分类号： G01N27/419
摘要： The invention relates to a method for monitoring the function of a gas sensor and/or for regenerating the same, especially for use as a lambda sensor or NOx sensor for an internal combustion engine. According to the invention, the sensor is provided with a heatable ceramic sensor body that detects gas molecules, with a first pump electrode disposed in a chamber and with a second pump electrode disposed in the exhaust gas of the internal combustion engine. Between the first and the second pump electrode a pump voltage is applied by means of a pump voltage source so that in the interior of the chamber an oxygen partial pressure is adjusted due to the electrochemical pumping of the oxygen molecules. The inventive method is characterized by the following steps: a) applying a first pump voltage and measuring a first pump current; b) applying a second pump voltage that is higher or lower than the first pump voltage and measuring a second pump current; c) establishing the difference between the first and the second pump current; d) if said difference exceeds a defined value, applying a previously determined saturation pump voltage and comparing the resulting pump current with a minimum pump current previously stored; e) establishing the difference between the minimum pump current and the pump current that occurs at the saturation pump voltage: f) if the difference between the minimum pump current and the pump current that results when the saturation voltage is applied exceeds a defined amount, applying a regeneration voltage that is larger than the saturation voltage and that is generated by a further voltage source.
摘要翻译：具有设置在第一泵电极的腔室中，一种用于监测功能和/或再生的气体传感器，特别是用作λ传感器或用于内燃发动机的NO x传感器，其具有可加热的，气体分子检测的探针陶瓷，方法和具有设置在所述内燃机的废气中的第二泵电极，其特征在于，通过泵电压源的装置中的第一和第二泵电极之间施加泵浦电压，以使氧气分压力由腔室内部的电化学泵出的氧分子进行调整，其特征在于以下步骤：a）将第一泵电压并测量第一泵电流; b）施加高于或低于第一泵浦电压的第二泵浦电压并测量第二泵浦电流; c）形成第一泵浦电流和第二泵浦电流的差值; d）如果差值超过预定值，则应用先前确定的饱和泵浦电压并将所得的泵浦电流与先前存储的最小泵浦电流进行比较; e）形成最小泵浦电流与饱和泵浦电压处的泵浦电流调整之间的差值; f）如最小泵电流和之间的差的施加时饱和泵电压超过预定量时，施加由一个再生电压比所述饱和电压时产生的进一步的电压源得到的。

4. 发明申请

WO2005072860A8 METHOD AND APPARATUS FOR CARRYING OUT ELECTROCHEMICALLY PROMOTED REACTIONS 审中-公开
标题翻译：携带电化学反应的方法和装置
公开(公告)号：WO2005072860A8
公开(公告)日：2005-10-27
申请号：PCT/GR2004000006
申请日：2004-01-28
申请人： UNIV PATRAS , VAYENAS CONSTANTINOS G , BALOMENOU STELLA , TSIPLAKIDES DEMETRIOS , KATSAOUNIS ALEXANDROS , BROSDA SUSANNE , FOTI GYORGY , COMNINELLIS CHRISTOS , THIEMANN-HANDLER SABINE , CRAMER BERNDT
发明人： VAYENAS CONSTANTINOS G , BALOMENOU STELLA , TSIPLAKIDES DEMETRIOS , KATSAOUNIS ALEXANDROS , BROSDA SUSANNE , FOTI GYORGY , COMNINELLIS CHRISTOS , THIEMANN-HANDLER SABINE , CRAMER BERNDT
IPC分类号： B01D53/32 , B01D53/86 , B01J12/00 , B01J19/00 , B01J19/24 , C10G2/00 , C10G47/00 , H01M8/12
CPC分类号： B01J19/249 , B01D53/326 , B01D2257/702 , B01J2219/00186 , B01J2219/002 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2474 , B01J2219/2479 , B01J2219/2487 , B01J2219/2495 , B01J2219/2497
摘要： Disclosed herein is a new method and apparatus for carrying out electrochemically promoted catalytic reactions, i.e., catalytic reactions where the catalytic rate and selectivity is modified by applying an electrical current or potential between the porous catalyst film which is deposited on a solid electrolyte and a second catalytic material which is also coated on the other side of the solid electrolyte component. The new apparatus, termed monolithic electropromoted reactor, consists of an appropriately grooved ceramic monolithic casing and of flat or ribbed solid electrolyte plates coated with the appropriate catalysts and support and electrical connections in the parallel grooves carved in the inside walls of the ceramic monolithic reactor casing. The flat of ribbed solid electrolyte plates are parallel to each other and are coated on one side by one catalyst (Catalyst 1) and on the other side by a second catalyst (Catalyst 2). All the catalyst 1 coatings are brought in electronic contact with an electronically conductive coating on one of the inside wall surfaces of the ceramic reactor casing and all the catalyst 2 coatings are brought in electronic contact with a second conductive coating on the opposite wall surface of the ceramic reactor casing. In this way all the electrochemical cells formed one in each plate are electrically connected in parallel and the reactor can be electropromoted by electrical potential or current application at the two terminals. Series electrical connection is also possible via electrical connection of catalyst 2 in each plate with catalyst I in the next plate.
摘要翻译：本文公开了一种用于进行电化学促进的催化反应的新方法和装置，即催化反应，其中催化速率和选择性通过在沉积在固体电解质上的多孔催化剂膜之间施加电流或电位而被修饰，还涂覆在固体电解质组分的另一侧上的催化材料。称为单片电动反应器的新设备由适当开槽的陶瓷整体式外壳和平坦或肋状固体电解质板组成，其中涂覆有合适的催化剂，并且在陶瓷整体式反应器壳体的内壁中雕刻的平行凹槽中的支撑和电连接。肋状固体电解质板的平面彼此平行，并且通过一个催化剂（催化剂1）一面涂覆，另一侧由第二催化剂（催化剂2）涂覆。所有催化剂1涂层与陶瓷反应器壳体的一个内壁表面上的电子导电涂层电子接触，并且所有催化剂2涂层与第二导电涂层电连接在第二导电涂层的相对壁表面上陶瓷电抗器外壳。以这种方式，在每个板中形成的所有电化学电池单独电连接，并且电抗器可以通过在两个端子处的电位或电流施加而电气化。也可以通过每个板中的催化剂2与下一个板中的催化剂I的电连接来实现串联电连接。

5. 发明申请

WO0214660A3 GAS SENSOR, ESPECIALLY A LAMBDA PROBE 审中-公开
标题翻译：气体传感器，尤其是氧传感器
公开(公告)号：WO0214660A3
公开(公告)日：2003-01-16
申请号：PCT/DE0103150
申请日：2001-08-16
申请人： BOSCH GMBH ROBERT , SCHEER HEINER , RENZ HANS-JOERG , RIEGEL JOHANN , DIEHL LOTHAR , THIEMANN-HANDLER SABINE
发明人： SCHEER HEINER , RENZ HANS-JOERG , RIEGEL JOHANN , DIEHL LOTHAR , THIEMANN-HANDLER SABINE
IPC分类号： G01N27/419 , G01N27/407 , G01N27/417
CPC分类号： G01N27/4071
摘要： Zur Verbesserung der elektrischen Eigenschaften des Gassensors können folgende Massnahmen eingesetzt werden: Leiterbahnen für Elektroden sind in Draufsicht auf die Schichtebenen des Körpers des Sensors ausserhalb von Kavitäten im Körper, insbesondere ausserhalb des Referenzluftkanals, angeordnet. Die Elektroden sind in Richtung des abgasseitigen Endes des Sensors hin vergrössert. Die Leiterbahnen weisen eine erhöhte Schichtdicke auf oder sind als Doppelschicht ausgebildet.
摘要翻译：以下措施可以用来提高气体传感器的电气特性：用于电极的条形导体位于在传感器主体的空腔，爱的外尤其外部基准空气通道的，雅丁到所述传感器的层平面的平面图体。电极是放大在所述传感器的废气端的方向上。带状导体必须增加层厚度或构造为双层。

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