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    • 1. 发明申请
    • POLYMER COMPOSITIONS AND PRESSURE-RESISTANT PIPES MADE THEREFROM
    • 聚合物组合物和耐压管道
    • WO2009147023A1
    • 2009-12-10
    • PCT/EP2009/056308
    • 2009-05-25
    • BOREALIS AGBÄCKMAN, MatsEK, Carl-GustavPAKKANEN, AnneliPALMLÖF, Magnus
    • BÄCKMAN, MatsEK, Carl-GustavPAKKANEN, AnneliPALMLÖF, Magnus
    • C08L23/08
    • F16L9/12C08L23/04C08L23/06C08L23/0815C08L2314/06Y10T137/0318Y10T428/139C08L2666/06
    • The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m 3 , a melt index MFR 5 of from 0.5 to 6.0 g/10 min, a melt index MFR 2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI 2.7/210 of from 2 to 50. In addition the multimodal copolymer comprises: (A) from 30 to 70 % by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m 3 ; and (B) from 30 to 70 % by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 929 kg/m 3 .
    • 本发明涉及适于制造管道的聚合物组合物。 组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物,其中多峰乙烯共聚物的密度为924至935kg / m 3,熔体指数MFR 5为0.5至6.0g / 10分钟,熔体指数MFR 2为0.1至2.0g / 10min,剪切稀化指数SHI2.7 / 210为2至50.此外,多峰共聚物包含:(A)30至70重量% 基于组分(A)和(B)的组合量的低分子量乙烯聚合物,其选自乙烯均聚物和乙烯与一种或多种具有4至10个碳原子的α-烯烃的共聚物并具有重均分子量 分子量为5000至100000g / mol,密度为945至975kg / m 3; 和(B)30至70重量%,基于组分(A)和(B)的组合量,乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和 重均分子量为100000〜1000000g / mol,密度为890〜929kg / m 3。
    • 2. 发明申请
    • POLYMER COMPOSITIONS HAVING IMPROVED HOMOGENEITY AND ODOUR, A METHOD FOR MAKING THEM AND PIPES MADE THEREOF
    • 具有改善的均匀性和气味的聚合物组合物,制备它们的管道及其制造方法
    • WO2009147021A1
    • 2009-12-10
    • PCT/EP2009/056303
    • 2009-05-25
    • BOREALIS AGBÄCKMAN, MatsEk, Carl-GustavPAKKANEN, AnneliPALMLÖF, Magnus
    • BÄCKMAN, MatsEk, Carl-GustavPAKKANEN, AnneliPALMLÖF, Magnus
    • C08L23/00
    • C08L23/06C08L23/0815C08L2205/02Y10T428/139C08L2666/06
    • The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 960 kg/m 3 , a melt index MFR 5 of from 0.5 to 6.0 g/10 min, a melt index MFR 2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI 27/210 of from 2 to 50. The compositions further have a level of volatile compounds of at most 100 ppm by weight and/or a homogeneity rating of at most 3. In addition the multimodal copolymer comprises: (A) from 35 to 60 % by weight, based on the combined amount of components (A) and (B), of a low molecular weight ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 5000 to 100000 g/mol and a density of from 945 to 975 kg/m 3 ; and (B) from 40 to 65 % by weight, based on the combined amount of components (A) and (B), of a high molecular weight copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms and having a weight average molecular weight of from 100000 to 1000000 g/mol and a density of from 890 to 935 kg/m 3 .
    • 本发明涉及适于制造管道的聚合物组合物。 组合物包含乙烯和一种或多种具有4至10个碳原子的α-烯烃的多峰共聚物,其中多峰乙烯共聚物的密度为924至960kg / m 3,熔体指数MFR 5为0.5至6.0g / 10分钟,熔体指数MFR 2为0.1至2.0g / 10min,剪切稀化指数SHI27 / 210为2至50.该组合物还具有至多100重量ppm的挥发性化合物水平和/或 均一性等级至多为3.另外,多峰共聚物包含:(A)35至60重量%,基于组分(A)和(B)的组合量,选自乙烯的低分子量乙烯聚合物 均聚物和乙烯与一种或多种具有4至10个碳原子的α-烯烃的共聚物,其重均分子量为5000至100000g / mol,密度为945至975kg / m 3; 和(B)40至65重量%,基于组分(A)和(B)的组合量,乙烯和一种或多种具有4至10个碳原子的α-烯烃的高分子量共聚物和 重均分子量为100000〜1000000g / mol,密度为890〜935kg / m 3。
    • 6. 发明申请
    • PIPES MADE FROM A POLYETHYLENE COPOLYMER WITH SLOW CRACK GROWTH
    • 来自具有缓慢裂纹增长的聚乙烯共聚物的管道
    • WO2012007082A1
    • 2012-01-19
    • PCT/EP2011/002614
    • 2011-05-26
    • BOREALIS AGBÄCKMAN, Mats
    • BÄCKMAN, Mats
    • C08K5/13C08K5/134C08L23/08C08L23/06
    • C08K5/13C08K5/1345C08L23/04C08L23/06C08L23/0815C08L2205/02C08L2666/06Y10T428/1397
    • The present invention relates to a pipe consisting of a polyethylene composition which comprises - a base resin, comprising • a first ethylene homo- or copolymer (A): and • a second ethylene copolymer (B); and the polyethylene composition further comprises - a phenol-type stabilizer (C); and - a phenol-type stabilizer (D); whereby stabilizers (C) and (D) are different. The present invention is furthermore directed to the use of - a phenol-type stabilizer (C); and - a phenol-type stabilizer (D); whereby stabilizers (C) and (D) are different and, optionally, - a further stabilizer (E) selected from • phosphorous containing stabilizer (E1 ); • sulphur containing stabilizers (E2); • nitrogen containing stabilizers (E3); and/or • mixtures thereof; for increasing the slow crack growth resistance of pipes.
    • 本发明涉及一种由聚乙烯组合物组成的管,该管包括:基础树脂,其包含第一乙烯均聚物或共聚物(A);和第二乙烯共聚物(B); 并且所述聚乙烯组合物还包含 - 酚型稳定剂(C); 和 - 酚型稳定剂(D); 由此稳定剂(C)和(D)不同。 本发明还涉及苯酚型稳定剂(C)的用途; 和 - 酚型稳定剂(D); 其中稳定剂(C)和(D)不同,并且任选地,选自含磷磷酸酯稳定剂(E1)的另外的稳定剂(E); 含硫稳定剂(E2); 含氮稳定剂(E3); 和/或其混合物; 用于增加管道的缓慢的裂纹扩展阻力。