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1. 发明申请

WO2020002654A1 CATALYSTS 审中-公开
公开(公告)号：WO2020002654A1
公开(公告)日：2020-01-02
申请号：PCT/EP2019/067435
申请日：2019-06-28
申请人： BOREALIS AG
发明人： AJELLAL, Noureddine , VIRKKUNEN, Ville , RESCONI, Luigi Maria Cristoforo , IZMER, Vyatcheslav V. , KONONOVICH, Dmitry S. , VOSKOBOYNIKOV, Alexander Z. , WANG, Jingbo , SCHWARZENBERGER, Simon , TÖLTSCH, Wilfried Peter
IPC分类号： C08F110/06 , C08F4/659
摘要： A complex of formula (I): (I') M is Hf; each X is a sigma ligand; L is a bridge of formula -(ER 8 2 ) y -; y is 1 or 2; E is C or Si; each R 8 is independently a C 1 -C 20 -hydrocarbyl, tri(C 1 -C 20 -alkyl)silyl, C 6 -C 20 - aryl, C 7 -C 20 -arylalkyl or C 7 -C 20 -alkylaryl or L is an alkylene group such as methylene or ethylene; Ar and Ar' are each independently an aryl or heteroaryl group optionally substituted by 1 to 3 groups R 1 or R 1' respectively; R 1 and R 1' are each independently the same or can be different and are a linear or branched C 1 -C 6 -alkyl group, C 7-20 arylalkyl, C 7-20 alkylaryl group or C 6-20 aryl group with the proviso that if there are four or more R 1 and R 1' groups present in total, one or more of R 1 and R 1' is other than tert butyl; R 2 and R 2' are the same or are different and are a CH 2 -R 9 group, with R 9 being H or linear or branched C 1 -C 6 -alkyl group, C 3-8 cycloalkyl group, C 6-10 aryl group; each R 3 is a -CH 2 -, -CHRx- or C(Rx) 2 - group wherein Rx is C 1-4 alkyl and where m is 2-6; R 5 is a linear or branched C 1 -C 6 -alkyl group, C 7-20 arylalkyl, C 7-20 alkylaryl group or C 6 -C 20 -aryl group; R 6 is a C(R 10 ) 3 group, with R 10 being a linear or branched C 1 -C 6 alkyl group; and R 7 and R 7' are the same or are different and are H or a linear or branched C 1 - C 6 -alkyl group. Invention relates also to a catalyst in solid form comprising (i) a complex of formula (I) and (ii) a cocatalyst of an aluminium compound and (iii) a cocatalyst of a boron compound.

2. 发明申请

WO2021185924A1 HETEROPHASIC POLYPROPYLENE COMPOSITION 审中-公开
公开(公告)号：WO2021185924A1
公开(公告)日：2021-09-23
申请号：PCT/EP2021/056854
申请日：2021-03-17
申请人： BOREALIS AG
发明人： WANG, Jingbo , GAHLEITNER, Markus , BERNREITNER, Klaus , TOELTSCH, Wilfried , SCHWARZENBERGER, Simon
IPC分类号： C08F210/06 , C08F4/6592 , C08L23/06 , C08F210/16
摘要： The present invention provides a heterophasic polypropylene composition with good response to nucleating agents, increased crystallisation temperature, good mechanical properties The present invention further relates to articles made thereof, and the use of the heterophasic polypropylene composition for specific applications and producing these.

3. 发明申请

WO2020011825A1 HETEROPHASIC POLYPROPYLENE COMPOSITION WITH IMPROVED BALANCE OF PROPERTIES 审中-公开
公开(公告)号：WO2020011825A1
公开(公告)日：2020-01-16
申请号：PCT/EP2019/068486
申请日：2019-07-10
申请人： BOREALIS AG
发明人： GAHLEITNER, Markus , WANG, Jingbo , BERNREITNER, Klaus , SCHWARZENBERGER, Simon , RESCONI, Luigi
IPC分类号： C08L23/12
摘要： The present invention is directed to a heterophasic polypropylene composition having an improved balance of desirable properties, i.e. high stiffness, high toughness, and high transparency. The heterophasic polypropylene composition of the present invention comprises 60.0 to 95.0 wt% of a crystalline propylene homopolymer with a melting temperature T m1 measured by differential scanning calorimetry of higher than 155 °C, 5.0 to 20.0 wt% of an elastomeric ethylene-propylene rubber, and at least one polymeric nucleating agent, wherein the crystalline propylene homopolymer (H-PP) and the elastomeric ethylene-propylene rubber (EPR) have been produced in the presence of a single-site catalyst, wherein the heterophasic polypropylene composition is characterized by a soluble fraction determined in 1,2,4-trichlorobenzene at 40 °C in the range of 5.0 to 20.0 wt%, and wherein the soluble fraction has an ethylene content in the range of 12.0 to 40.0 wt%. The present invention is further directed to a process for the preparation of the heterophasic polypropylene composition comprising polymerizing propylene in at least three polymerization steps in the presence of a single-site catalyst, wherein the at least one polymeric nucleating agent is introduced either as a master batch by a compounding step or via a prepolymerization step prior to the first polymerization step. The present invention is further directed to an article obtained by extrusion of the heterophasic polypropylene composition, and to a packaging article comprising the extruded article.Finally, the present invention is directed to the use of the heterophasic polypropylene composition for the production of extruded articles such as films or sheets.

4. 发明申请

WO2014083130A1 TIGER STRIPE MODIFIER 审中-公开
公开(公告)号：WO2014083130A1
公开(公告)日：2014-06-05
申请号：PCT/EP2013/075015
申请日：2013-11-28
申请人： BOREALIS AG
发明人： TRANNINGER, Michael , GRESTENBERGER, Georg , SANDHOLZER, Martina , SCHWARZENBERGER, Simon , KAHLEN, Susanne , POTTER, Gregory
IPC分类号： C08L23/12 , C08F2/00
CPC分类号： C08L23/12 , C08L2205/02 , C08L2207/02 , C08L23/14 , C08L23/16 , C08F210/06 , C08F2/001 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/21 , C08F110/06
摘要： Tiger stripe modifier being a heterophasic polypropylene composition comprising a propylene homopolymer and an elastomeric propylene copolymer, wherein said propylene homopolymer has a melt flow rate MFR2 (230°C) in the range of above 70 to 300 g/l Omin; the xylene cold soluble fraction of the heterophasic polypropylene composition has an intrinsic viscosity in the range of more than 4.0 to below 12.0 dl/g; and the comonomer content of the xylene cold soluble fraction of the heterophasic polypropylene composition is in the range of 20.0 to 60.0 wt.-%; wherein further the heterophasic polypropylene composition fulfills the inequation (I) 0.30 ≥ (0.241 X C ) - (1.14 X IV ) (I) wherein C is the comonomer content of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1), and IV is the intrinsic viscosity of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1).
摘要翻译： Tiger条纹改性剂是包含丙烯均聚物和弹性体丙烯共聚物的多相聚丙烯组合物，其中所述丙烯均聚物的熔体流动速率MFR 2（230℃）在70-300g / l Omin范围内; 多相聚丙烯组合物的二甲苯冷可溶部分的特性粘度在大于4.0至低于12.0dl / g的范围内; 并且多相聚丙烯组合物的二甲苯冷可溶部分的共聚单体含量在20.0至60.0重量％的范围内; 其中进一步的异相聚丙烯组合物满足不等式（I）0.30≥（0.241XC） - （1.14XIV）（I）其中C是多相聚丙烯组合物（HECO1）的二甲苯冷可溶（XCS）级分的共聚单体含量，，IV是异相聚丙烯组合物（HECO1）的二甲苯冷可溶（XCS）部分的特性粘度。

5. 发明申请

WO2014083129A1 TIGER STRIPE MODIFIER 审中-公开
公开(公告)号：WO2014083129A1
公开(公告)日：2014-06-05
申请号：PCT/EP2013/075014
申请日：2013-11-28
申请人： BOREALIS AG
发明人： TRANNINGER, Michael , GRESTENBERGER, Georg , SANDHOLZER, Martina , SCHWARZENBERGER, Simon , KAHLEN, Susanne , POTTER, Gregory
IPC分类号： C08L23/12 , C08F2/00
CPC分类号： C08L23/12 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L23/14 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/21 , C08F2/001 , C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/6492
摘要： Tiger stripe modifier being a heterophasic polypropylene composition having a melt flow rate MFR 2 (230°C) in the range of 0.5 to 20 g/10 min and comprises a propylene homopolymer and an elastomeric propylene copolymer, wherein said propylene homopolymer has a melt flow rate MFR 2 (230°C) in the range of above 10 to 300 g/10 min; the xylene cold soluble fraction of the heterophasic polypropylene composition has an intrinsic viscosity in the range of more than 2.5 to below 11.0 dl/g; and the comonomer content of the xylene cold soluble fraction of the heterophasic polypropylene composition is in the range of 10.0 to 25.0 wt.-%; wherein further the heterophasic polypropylene composition fulfills the inequation (I) 0.3 ≥ (0.241 x C ) - (1.14 x IV ) (I) wherein C is the comonomer content of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1), and IV is the intrinsic viscosity of the xylene cold soluble (XCS) fraction of the heterophasic polypropylene composition (HECO1).
摘要翻译： Tiger条纹改性剂是熔体流动速率MFR 2（230℃）在0.5至20g / 10min范围内并包含丙烯均聚物和弹性体丙烯共聚物的多相聚丙烯组合物，其中所述丙烯均聚物具有熔体流动速率在10〜300g / 10min范围内的MFR2（230℃）; 多相聚丙烯组合物的二甲苯冷可溶部分的特性粘度在大于2.5至低于11.0dl / g的范围内; 并且多相聚丙烯组合物的二甲苯冷可溶部分的共聚单体含量在10.0至25.0重量％的范围内; 其中进一步的异相聚丙烯组合物满足不等式（I）0.3≥（0.241×C） - （1.14×IV）（I）其中C是多相聚丙烯组合物的二甲苯冷可溶（XCS）级分的共聚单体含量（HECO1 ），IV是异相聚丙烯组合物（HECO1）的二甲苯冷可溶（XCS）级分的特性粘度。

6. 发明申请

WO2019215122A1 PROCESS FOR PREPARING PROPYLENE COPOLYMERS COMPRISING C4-C12-ALPHA OLEFIN COMONOMER UNITS 审中-公开
公开(公告)号：WO2019215122A1
公开(公告)日：2019-11-14
申请号：PCT/EP2019/061635
申请日：2019-05-07
申请人： BOREALIS AG
发明人： HOFF, Matthias , RESCONI, Luigi , SCHWARZENBERGER, Simon , TÖLTSCH, Wilfried
IPC分类号： C08F4/659 , C08F210/06 , C07F17/00
摘要： The present invention relates to a process for producing a copolymer of propylene, optionally ethylene, and at least one comonomer selected from alpha olefins having from 4 to 12 carbon atoms using a specific class of metallocene complexes in combination with a cocatalyst system comprising a boron containing cocatalyst and an aluminoxane cocatalyst, preferably in a multistage polymerization process including a gas phase polymerization step.

7. 发明申请

WO2019012110A1 POLYPROPYLENE COMPOSITION 审中-公开
公开(公告)号：WO2019012110A1
公开(公告)日：2019-01-17
申请号：PCT/EP2018/069093
申请日：2018-07-13
申请人： BOREALIS AG
发明人： WANG, Jingbo , SCHWARZENBERGER, Simon , BERNREITNER, Klaus , GAHLEITNER, Markus
IPC分类号： C08L23/14
摘要： New polypropylene composition which combines low sealing initiation temperature (SIT), low overall migration, good optical properties, like low haze and good retortability, its use and articles made therefrom.

8. 发明申请

WO2021058742A1 HETEROPHASIC POLYPROPYLENE COPOLYMERS 审中-公开
公开(公告)号：WO2021058742A1
公开(公告)日：2021-04-01
申请号：PCT/EP2020/076901
申请日：2020-09-25
申请人： BOREALIS AG
发明人： WANG, Jingbo , GAHLEITNER, Markus , BERNREITNER, Klaus , RESCONI, Luigi Maria Cristoforo , SCHWARZENBERGER, Simon
IPC分类号： C08F210/16 , C08F4/6592
摘要： A heterophasic polypropylene copolymer having an MFR2 of 0.05 to 20 g/10min (ISO 1133 at 230°C with a loading of 2.16 kg) and a melting point (Tm) of 156 to 164°C (measured by DSC according to ISO 11357) wherein the heterophasic polypropylene copolymer comprises at least the following components: (A) 55.0 to 95.0 wt% of a crystalline fraction (CF) having a comonomer content of 0 to 3.0 wt%; and (B) 5.0 to 45.0 wt% of a soluble fraction (SF) having a comonomer content of 12 to 45 wt%; wherein the intrinsic viscosity (IV) (in decalin at 135°C) of the soluble fraction (SF) is 2.5 to 11 dl/g, and wherein the amount of crystalline fraction (CF) and the amount of soluble fraction (SF) are determined in 1,2,4-trichlorobenzene at 40°C.

9. 发明申请

WO2021058740A1 CATALYSTS 审中-公开
公开(公告)号：WO2021058740A1
公开(公告)日：2021-04-01
申请号：PCT/EP2020/076897
申请日：2020-09-25
申请人： BOREALIS AG
发明人： RESCONI, Luigi Maria Cristoforo , SCHWARZENBERGER, Simon , VIRKKUNEN, Ville , REZNICHENKO, Alexander , IZMER, Vyatcheslav V. , KONONOVICH, Dmitry S. , VOSKOBOYNIKOV, Alexander Z.
IPC分类号： C08F210/16 , C08F4/6592 , C07F17/00 , C08L23/10
摘要： A metallocene complex of formula (I): each X is a sigma-ligand; in the group R2Si- at least one R is methyl or ethyl, and the other R is selected from methyl, ethyl, n-propyl, isopropyl, n-butyl or isobutyl, pentyl, hexyl, cyclohexyl and phenyl; each R1 independently is the same or can be different and are a CH2-R7 group, with R7 being H or linear or branched C1-6-alkyl group, C3-8 cycloalkyl group, or C6-10 aryl group; each R2 is independently a –CH=, -CY=, –CH2-, -CHY- or -CY2- group, wherein Y is a C1-6 hydrocarbyl group and where n is 2-6; each R3 and R4 are independently the same or can be different and are hydrogen, a linear or branched C1-6-alkyl group, a C7-20 arylalkyl, C7-20 alkylaryl group, C6-20 aryl group, or an -OY group, wherein Y is a is a C1-6 hydrocarbyl group; R5 is a linear or branched C1-6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-20-aryl group; and R6 is a C(R8)3 group, with R8 being a linear or branched C1-6 alkyl group; (A) wherein at least one R3 per phenyl group and at least one R4 is not hydrogen, and wherein at least one R3 per phenyl group and at least one R4 is hydrogen; or (B) wherein one R3 is an -OY group, wherein Y is a is a C1-6 hydrocarbyl group, in 4 position of each phenyl group and the two other R3 groups are tert-butyl groups; and/or (C) wherein one R4 is an -OY group, wherein Y is a is a C1-6 hydrocarbyl group, in 4-position of the phenyl ring and the two other R4 groups are tert-butyl groups.

10. 发明申请

WO2019141546A1 HETEROPHASIC POLYPROPYLENE COMPOSITION WITH HIGH FLEXIBILITY AND SOFTNESS 审中-公开
公开(公告)号：WO2019141546A1
公开(公告)日：2019-07-25
申请号：PCT/EP2019/050361
申请日：2019-01-09
申请人： BOREALIS AG
发明人： GAHLEITNER, Markus , WANG, Jingbo , BERNREITNER, Klaus , TÖLTSCH, Wilfried Peter , SCHWARZENBERGER, Simon
IPC分类号： C08L23/12 , C08L23/16
CPC分类号： C08L23/12 , C08L23/16 , C08L2203/10 , C08L2205/22 , C08L2207/02 , C08L2308/00 , C08L2314/06 , C08F210/16 , C08F2/001 , C08F4/65927 , C08F210/06 , C08F210/02 , C08F2500/17
摘要： The present invention relates to a heterophasic propylene copolymer polymerized the presence of a single-site catalyst with a low tensile modulus, a process for preparing such a heterophasic propylene copolymer and articles made therefrom.

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