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1. 发明申请

WO2014096166A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2014096166A1
公开(公告)日：2014-06-26
申请号：PCT/EP2013/077339
申请日：2013-12-19
申请人： BOREALIS AG
发明人： RESCONI, Luigi , CASTRO, Pascal , VIRKKUNEN, Ville , IZMER, Vyatcheslav V , KONONOVICH, Dmitry S , KULYABIN, Pavel Sergeevich , VOSKOBOYNIKOV, Alexander Z
IPC分类号： C08F10/06 , C08F4/6592 , C07F17/00 , C07F7/08 , C08F4/02
CPC分类号： C08F110/06 , C07C1/326 , C07C2531/18 , C07F7/0818 , C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F4/02 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A catalyst comprising (i) an asymmetric complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, Cl-C20-alkyl, tri(Cl- C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R 2 and R 2' are each independently linear C 1-10 hydrocarbyl; R 5 and R 5' are each independently hydrogen or a CI -20 hydrocarbyl group; R6 and R 6' are each independently hydrogen or a CI -20 hydrocarbyl group; R 7 is hydrogen or a CI -20 hydrocarbyl group or is ZR 3 ; Z is O or S, preferably O; R 3 is a Cl-10 hydrocarbyl group; Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8 ; Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 8' ; R 8 and R 8' are each independently is a CI -20 hydrocarbyl group; with the proviso that at least one of R 6 or R 7 is not H; and (ii) a cocatalyst comprising a compound of a group 13 metal, e.g. boron.
摘要翻译：一种催化剂，其包含（i）式（I）的不对称配合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地是氢原子，C 1 -C 20 - 烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20烷基芳基; R2和R2'各自独立地为直链C 1-10烃基; R5和R5'各自独立地为氢或C1〜20烃基; R6和R6'各自独立地为氢或C1〜20烃基; R 7为氢或C 1-20烃基或ZR 3; Z是O或S，优选O; R3是C1-10烃基; Ar是任选被一个或多个基团R 8取代的具有至多20个碳原子的芳基或杂芳基; Ar'是任选被一个或多个R 8'基团取代的具有至多20个碳原子的芳基或杂芳基; R8和R8'各自独立地为C1〜20烃基; 条件是R6或R7中的至少一个不是H; 和（ii）包含第13族金属化合物的助催化剂，例如硼。

2. 发明申请

WO2014096164A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2014096164A1
公开(公告)日：2014-06-26
申请号：PCT/EP2013/077335
申请日：2013-12-19
申请人： BOREALIS AG
发明人： RESCONI, Luigi , CASTRO, Pascal , VIRKKUNEN, Ville , IZMER, Vyatcheslav V , KONONOVICH, Dmitry S , KULYABIN, Pavel Sergeevich , VOSKOBOYNIKOV, Alexander Z
IPC分类号： C07F17/00 , C07F7/08 , C08F10/06 , C08F4/6592
CPC分类号： C08F4/65927 , C07C1/321 , C07C17/16 , C07C45/00 , C07C51/00 , C07F7/0818 , C07F7/082 , C07F17/00 , C08F210/06 , C08F10/06 , C08F4/65912 , C08F210/16 , C08F2500/03 , C08F2500/12
摘要： An asymmetric complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R 2 and R 2 ' are each independently a C 1 -C 20 hydrocarbyl radical; R 5' is a C 1-20 hydrocarbyl group; R 5 is hydrogen, or a C 1-20 hydrocarbyl group; R 6 is a non tertiary C 1-10 alkyl group or C6-10-aryl group or C7-10 arylalkyl group or ZR 3 ; R 6' is a tertiary C 4-20 alkyl group; Z is O or S; R 3 is a C1-20 hydrocarbyl group optionally substituted with halo; Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ; Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R 1 ; each R 1 is a C 1-20 hydrocarbyl group or two R 1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered ring with the Ar group, said ring being itself optionally substituted with one or more groups R 4 ; and each R 4 is a C 1-20 hydrocarbyl group.
摘要翻译：式（I）的不对称配合物，其中M是锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; R2和R2'各自独立地为C1-C20烃基; R5'是C1-20烃基; R5是氢或C1-20烃基; R6是非叔C 1-10烷基或C 6-10 - 芳基或C 7-10芳基烷基或ZR 3; R6'是叔C4-20烷基; Z是O或S; R3是任选被卤素取代的C 1-20烃基; Ar是任选被一个或多个R 1基团取代的具有至多20个碳原子的芳基或杂芳基; Ar'是任选被一个或多个R 1基团取代的具有至多20个碳原子的芳基或杂芳基; 每个R 1是C 1-20烃基或相邻碳原子上的两个R 1基团可以与Ar基团形成稠合的5或6元环，所述环本身任选地被一个或多个基团R 4取代; 并且每个R 4是C 1-20烃基。

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