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    • 2. 发明申请
    • CATALYST MASTERBATCH
    • 催化剂主板
    • WO2013159924A1
    • 2013-10-31
    • PCT/EP2013/001235
    • 2013-04-24
    • BOREALIS AG
    • DAHLÉN, KristianNYLANDER, Perry
    • C08J3/22C08K5/09C08L43/04H01B3/44
    • C08J3/24C08J3/226C08J2323/08C08J2343/04C08J2451/06C08K5/09C08K5/42C08L23/0869C08L43/04C08L51/06C08L2203/202C08L2310/00C08L2312/08H01B3/44
    • The present invention relates to a catalyst masterbatch for cross-linking a polyolefin comprising cross-linkable silicon-containing groups comprising - a Brønsted acid and/or Brønsted acid anhydride (A); and - a polyolefin (B) containing Brønsted acid and/or Brønsted acid anhydride groups. The present invention further relates to a polyolefin composition comprising a polyolefin (C) comprising cross-linkable silicon-containing groups; a Brønsted acid and/or Brønsted acid anhydride; and a polyolefin (B) containing Brønsted acid and/or Brønsted acid anhydride groups. The present invention further relates to the use of the catalyst masterbatch according to the invention for cross-linking a polyolefin composition comprising a polyolefin with cross-linkable silicon-containing groups (C). The present invention further relates to the use of polyolefin (B) containing Brønsted acid and/or Brønsted acid anhydride groups together with a sulphonic acid silanol condensation catalyst in a polyolefin composition comprising: a polyolefin with cross-linkable silicon-containing groups (C). The present invention further relates to the use of the catalyst masterbatch according to any one of the preceding claims 1 to 11 in a cable layer.
    • 本发明涉及用于交联包含可交联的含硅基团的聚烯烃的催化剂母料,其包含布朗斯台德酸和/或布朗斯台德酸酐(A); 和 - 含有布朗斯台德酸和/或布朗斯台德酸酐基团的聚烯烃(B)。 本发明还涉及包含含有可交联的含硅基团的聚烯烃(C)的聚烯烃组合物; 布朗斯台德酸和/或布朗斯台德酸酐; 和含有布朗斯台德酸和/或布朗斯台德酸酐基团的聚烯烃(B)。 本发明还涉及根据本发明的催化剂母料用于交联包含具有可交联的含硅基团(C)的聚烯烃的聚烯烃组合物的用途。 本发明还涉及在聚烯烃组合物中含有布朗斯台德酸和/或布朗斯台德酸酐基团的聚烯烃(B)与磺酸硅烷醇缩合催化剂的用途,所述聚烯烃组合物包含:具有可交联的含硅基团的聚烯烃(C) 。 本发明还涉及根据前述权利要求1至11中任一项的催化剂母料在电缆层中的用途。
    • 6. 发明申请
    • CROSSLINKABLE POLYOLEFIN COMPOSITION COMPRISING SILANE GROUPS FORMING AN ACID OR A BASE UPON HYDROLYSATION
    • 可交联的聚烯烃组合物,包含形成酸或基于水解的硅烷基团
    • WO2010130458A1
    • 2010-11-18
    • PCT/EP2010/002972
    • 2010-05-14
    • BOREALIS AGDAHLÉN, KristianCARLSSON, Roger
    • DAHLÉN, KristianCARLSSON, Roger
    • C08F255/00C08F255/02C08L51/06C08F8/00C08F8/12
    • C08F255/00C08F255/02C08L51/06C08L2666/04C08L2666/02
    • The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90°C cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR 2 = 2 g/10min, a density of 923 g/cm 3 , and 2 wt.% of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90°C, and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90°C cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR 2 = 2 g/10min, a density of 923 g/cm 3 , and 2 wt.% of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90°C.
    • 本发明涉及一种聚烯烃组合物,其包含(A)具有可水解硅烷基团的可交联聚烯烃,其在水解形成酸或碱时,​​其特征在于所述酸或碱在40小时后产生至少40%的凝胶含量 90℃交联试验,其中将酸或碱以4.5mmol / kg的量加入到MFR 2 = 2g / 10min,密度为923g / cm 3和2wt。%的乙烯/乙烯基三甲氧基硅烷共聚物中。 %的乙烯基三甲氧基硅烷,然后在90℃的水浴中交联,以及包含(i)具有可水解硅烷基团的可交联聚烯烃的聚烯烃组合物,和(ii)在水解时可水解硅烷基团的非聚合化合物 形成酸或碱,其特征在于酸或碱在90℃交联试验中40小时后产生至少40%的凝胶含量,其中酸或碱的加入量为4.5mmol / kg至乙烯/乙烯基三甲氧基硅烷 共聚物,MFR 2 = 2g / 10min,密度为923g / cm 3,和2重量%的乙烯基三甲氧基硅烷,然后在90℃的水浴中交联。