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    • 3. 发明申请
    • PROCESS FOR COATING REACTORS USING ORGANIC COMPOUND VAPOR APPLICATION
    • 使用有机化合物蒸气涂覆反应器的方法
    • WO1981000684A1
    • 1981-03-19
    • PCT/US1980001063
    • 1980-08-18
    • BF GOODRICH CO
    • BF GOODRICH COJONES RWITENHAFER D
    • B08B17/02
    • B08B17/02C08F2/004
    • This invention relates to the reduction of polymer buildup on the inner surfaces of a polymerization reactor by applying a polymer buildup resistant coating to the inner surfaces thereof, the method or process of applying said coating being the subject of this invention. An approximate monolayer coating on the inner surfaces of the reactor results from applying thereto an aqueous or organic solvent solution of the coating material by means of vinyl chloride in vapor form. The coating material is an organic compound or polymer which is capable of resisting polymer buildup thereon As examples of such coating materials, there may be named the polyaromatic amines, self-condensed polyhydric phenols, tannic acid and tannates, various dyes, such as nigrosine, and the like, etc. When using vinyl chloride to apply the coating material, the same reaches the inner reactor surfaces in the form of a mist. When polymerizing olefinic monomers, such as vinyl halides, vinylidene halides, and vinylidene monomers having at least one terminal CH2=C
    • 在聚合反应器的内表面上通过施加抗聚合物在其内表面上形成的涂层来减少聚合物的形成,施加该涂层的方法构成所处理的对象。 在反应器内表面上的单层涂层由于在气相中使用氯乙烯而在其上施加涂层材料的水溶液或有机溶剂而产生。 涂层材料是能够抵抗在其上形成聚合物的有机或聚合物化合物。 这种涂层材料的实例包括聚芳族胺,多元酚自缩合,单宁酸和鞣酸盐,各种染料如苯胺黑等。 通过使用氯乙烯涂覆涂层材料,它以敲击的形式到达反应器的内表面。 通过在该涂层存在下聚合烯烃单体如乙烯基卤化物,偏二卤乙烯和具有至少一个端基CH 2 = C <的乙烯叉基单体及其混合物, 反应器的内表面基本上被消除。