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    • 4. 发明申请
    • SUBSTITUTED OXAZACYCLOALKENES, INTERMEDIATE PRODUCTS AND USE AS FUNGICIDES
    • 取代OXAZACYCLOALKENE,中间体和使用作为杀真菌剂
    • WO1995021833A1
    • 1995-08-17
    • PCT/EP1995000311
    • 1995-01-30
    • BAYER AKTIENGESELLSCHAFTSEITZ, ThomasASSMANN, LutzGAYER, HerbertGERDES, PeterHEINEMANN, UlrichKRÜGER, Bernd-WielandKUHNT, DietmarTIEMANN, RalfDEHNE, Heinz-WilhelmDUTZMANN, StefanHÄNSSLER, GerdSTENZEL, Klaus
    • BAYER AKTIENGESELLSCHAFT
    • C07D265/08
    • C07D265/08A01N43/72A01N43/76A01N43/78C07C251/48C07D263/14C07D267/06
    • Substituted oxazacycloalkenes of formula (I) in which A is optionally substituted alkane diyl (alkylene), Ar is optionally substituted arylene or heteroarylene; E is a 1-alkene-1,1-diyl group containing a radical R in the 2nd position or a 2-aza-1-alkene-1,1-diyl group containing a radical R in the 2nd position, or a 3-aza-1-propene-2,3-diyl group containing a radical R in the 3rd position and a radical R in the 1st position, or a 1-aza-1-propene-2,3-diyl group containing a radical R in the 1st position, or a 1,3-diaza-1-propene-2,3-diyl group containing a radical R in the 3rd position and a radical R in the 1st position, or an optionally substituted imino group ("azamethylene", N-R ), G is oxygen or, optionally substituted by halogen, hydroxy, alkyl, halogen alkyl or cycloalkyl, alkane diyl or one of the groups: -Q-CQ-, -CQ-Q-, -CH2-Q-, -Q-CH2-, -CQ-Q-CH2-, -CH2-Q-CQ-, -Q-CQ-CH2-, -Q-CQ-Q-CH2-, -N=N-, -S(O)n-, -CH2-S(O)n-, -CQ-, -S(O)n-CH2-, -C(R )=N-O-, -C(R )=N-O-CH2-, -N(R )-, -CQ-N(R )-, -N(R )-CQ-, -Q-CQ-N(R )-, -N=C(R )-Q-CH2-, -CH2-O-N=C(R )-, -N(R )-CQ-Q-, -CQ-N(R )-CQ-Q-, -N(R )-CQ-Q-CH2-, -CQ-CH2- oder -N=N-C(R )=N-O-; Z is optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aryl or heterocyclyl, a process for their production and the use of oxazacycloalkenes as fungicides.
    • 取代的式(I),其中A代表任选取代的烷二基(亚烷基),Ar是任选取代的亚芳基或亚杂芳基的Oxazacycloalkene,E表示的1-烯烃-1,1-二基分组这在2- 定位一个基团R <1>包含,或者是2-氮杂-1-链烯-1,1-二基分组其中基团R <2>包含2位或3-氮杂 其中基团R和1位在位置3包含一个基团R <1>,或代表1-氮杂-1-丙烯-2,3-二基部分的丙烯-2,3-二基分组 是一个基团R <2>包含在1-位,或表示1,3-二氮杂-1-丙烯-2,3-二基,其分组在3位的基团R和在1-位 一个基团R <2>包含,或(“azamethylene”,NR <3>)是任选取代的亚氨基,G表示氧,在每种情况下任选地被卤素,羟基,烷基,卤代烷基或环烷基取代的烷二基,或其中一个取代的 下面-Q-CQ-分组是,-CQ-Q-,-CH 2 -Q-,-Q-CH 2 - ,-CQ-Q-CH2-,-CH2-Q-CQ-,-Q-CQ-CH2- ,-Q-CQ-Q-CH 2 - , - N = N-,-S(O)N-,-CH 2 S(O)N-,-CQ-,-S(O)N-CH 2 - , - C(R <4>)= NO-,-C(R <4>)= NO-CH 2 - ,-N(R <5>) - ,-CQ-N(R <5>) - , - N( [R <5>) - CQ-,-Q-CQ-N(R <5>) - , - N = C(R <4>) - Q-CH2-,-CH2-ON = C(R <4> ) - , - N(R <5>) - CQ-Q-,-CQ-N(R <5>) - CQ-Q,-N(R <5>) - CQ-Q-CH2 - CQ-CH 2或-N = NC(R <4>)= NO-,Z代表任选取代的烷基,烯基,炔基,环烷基,芳基或杂环基,一种方法和用于制备它们的中间体和使用作为Oxazacycloalkenen 杀菌剂。
    • 7. 发明申请
    • OXIMETHER AND ACRYLIC ACID DERIVATIVES AND THEIR USE AS FUNGICIDES
    • 肟醚和丙烯酸衍生物及其作为杀菌剂
    • WO1997003950A1
    • 1997-02-06
    • PCT/EP1996002931
    • 1996-07-04
    • BAYER AKTIENGESELLSCHAFTGERDES, PeterGAYER, HerbertHEINEMANN, UlrichTIEMANN, RalfSTENZEL, KlausDUTZMANN, Stefan
    • BAYER AKTIENGESELLSCHAFT
    • C07C255/62
    • C07D239/34A01N37/50A01N43/16A01N43/54A01N43/82A01N47/48C07C251/60C07C255/62C07C311/10C07D285/08
    • Ether derivatives having the general formula (I), several processes for preparing the same and their use as fungicides are disclosed, as well as intermediate products and several processes for preparing the same. In the formula (I): Ar stands for optionally substituted arylene ou heteroarylene; E stands for =CH- or nitrogen; G stands for a simple bond, for oxygen, sulphur or optionally halogen-, hydroxy-, alkyl-, halogen alkyl- or cycloalkyl-substituted alkandiyl, alkendiyl, alkindiyl or one of the groups -Q-CQ-, -CQ-Q-, -CH2-Q-, -Q-CH2-, -CQ-Q-CH2-, -CH2-Q-CQ-, Q-CQ-CH2-, -Q-CQ-Q-CH2-, -N=N-, -S(O)n-, -CH2-S(O)n-, -CQ-, -S(O)n-CH2-, -C(R )=N-O-, -C(R )=N-O-CH2-, -N(R )-, -CQ-N(R )-, -N(R )-CQ-, -Q-CQ-N(R )-, -N=C(R )-Q-CH2-, -CH2-O-N=C(R )-, -C(CH3)-O-N=C(R )-, -N(R )-CQ-Q-, -CQ-N(R )-CQ-Q-, -N(R )-CQ-Q-CH2-, -Q-C(R )=N-O-CH2-, -N(R )-C(R )=N-O-CH2-, -O-CH2-C(R )=N-O-CH2-, -N=N-C(R )=N-O-CH2-, -C(=N-O-R )-C(R )=N-OCH2-, -C(=N-O-R )-C(R )-O-N=CH-, -C(=N-O-R )-C(R )-O-N=C(CH3)-, -T-Ar - or -T-Ar -Q-; R stands for alkoxy, alkylamino or dialkylamino; R stands for cyano, thiocyanato, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, aminothiocarbonyl, alkylaminocarbonyl or dialkylaminocarbonyl; and Z stands for optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aryl or heterocyclyl.
    • 通式(I),本发明涉及醚衍生物:它们的制备和它们的用途的几种方法作为杀真菌剂,以及中间体和几个进程及其制备,其中Ar代表各自任选被取代的亚芳基或亚杂芳基,E代表= CH或氮, 中,G表示单键,表示氧,硫,或任选地被卤素,羟基,烷基,卤代烷基或环烷基取代的烷二基,烯二,alkinediyl或低于-Q-CQ-的分组之一,-CQ-Q-,取代的-CH 2 -Q-,-Q-CH 2 - ,-CQ-Q-CH2-,-CH2-Q-CQ-,-Q-CQ-CH2-,-Q-CQ-Q-CH 2 - , - N = N-, -S(O)N-,-CH 2 -S N-(O),-CQ-,-S(O)N-CH 2 - ,-C(R <3>)= NO-,-C(R <3 >)= NO-CH 2 - ,-N(R <4>) - ,-CQ-N(R <4>) - , - N(R <4>) - CQ,CQ-Q-N(R <4>) - , - N = C(R <3>) - = C(R <3>)Q-CH2-,-CH2-ON - , - C(CH 3)-ON = C(R <3> ) - , - N(R <4>) - CQ-Q-,-CQ-N(R <4>) - CQ-Q,-N(R <4>) - CQ-Q-CH2 - QC(R <3>)= NO-CH 2 - ,-N(R <4>) - C(R <3>)= NO-CH 2 - ,-O-CH2-C(R <3>)= NO- CH 2,N = NC(R <3>)= NO-CH 2,-C (= NOR <5>) - C(R <3>)= N-OCH 2 -C(= NOR <5>) - C(R <3>) - ON = CH-,-C(= NOR < 5>) - C(R <3>) - ON = C(CH 3) - ,-T-的Ar <1> - 或-T-的Ar <1> -Q-,R <1>是烷氧基,烷基氨基或 二烷基氨基,R <2>表示氰基,氰硫基,烷基羰基,烷氧基羰基,氨基羰基,氨基硫代,烷基氨基羰基或二烷基氨基,并且Z代表各自任选被取代的烷基,烯基,炔基,环烷基,芳基或杂环基。
    • 8. 发明申请
    • CARBOXYLIC ACID AMIDE DERIVATIVES AND THEIR USE AS PESTICIDES
    • 甲酰胺及其作为农药
    • WO1997000856A1
    • 1997-01-09
    • PCT/EP1996002511
    • 1996-06-10
    • BAYER AKTIENGESELLSCHAFTHEINEMANN, UlrichGERDES, PeterGAYER, HerbertSEITZ, ThomasTIEMANN, RalfSTENZEL, KlausDUTZMANN, Stefan
    • BAYER AKTIENGESELLSCHAFT
    • C07C251/48
    • A01N37/50A01N43/10C07C251/48C07C251/60C07D333/22
    • Carboxylic acid amide derivatives having formula (I) are disclosed, as well as several processes for preparing the same and their use as fungicides. In formula (I), Ar stands for optionally substituted arylene or heteroarylene; E stands for an 1-alken-1,1-diyl grouping that contains a rest R in position 2, a 2-aza-1-alken-1,1-diyl grouping that contains a rest R in position 2, an optionally substituted imino grouping ("azamethylene", N-R ), a 3-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 3-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1, a 3-thia-1-propen-2,3-diyl grouping that contains a rest R in position 1, a 1-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1,3-diaza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1-aza-3-oxa-1-propen-2,3-diyl grouping that contains a rest R in position 1, or for a 1-aza-3-thia-1-propen-2,3-diyl grouping that contains a rest R in position 1; G stands for a simple bond, oxygen, sulphur or alkandiyl, alkendiyl, alkindiyl or one of the groupings represented in the formula: -Q -CQ -, -CQ -Q -, -CH2-Q -, -Q -CH2-, -CQ -Q -CH2-, -CH2-Q -CQ -, -Q -CQ -CH2-, -Q -CQ -Q -CH2-, -N=N-, -S(O)n-, -CH2-S(O)n-, -CQ -, -S(O)n-CH2-, -C(R )=N-O-, -C(R )=N-O-CH2-, -N(R )-, -CQ -N(R )-, -N(R )-CQ -, -Q -CQ -N(R )-, -N=C(R )-Q -CH2-, -CH2-O-N=C(R )-, -N(R )-CQ -Q -, -CQ -N(R )-CQ -Q1-, -N(R5)-CQ1-Q1-CH2-, -Q -C(R )=N-O-, -C(R )=N-O-CH2-, -N(R )-C(R )=N-O-CH2-, -O-CH2-C(R )=N-O-CH2-, -N=N-C(R )=N-O-CH2-, -C(CH3)-O-N=C(R )-, -C(=N-O-L)-C(R )=N-O-CH2-, -C(=N-O-L)-C(R )-O-N=CH-, -C(=N-O-L)-C(R )-O-N=C(CH3)-, -T-Ar - or -T-Ar -Q - that may be substituted by halogen, hydroxy, alkyl, alkyl halide or cycloalkyl; R stands for hydrogen, amino or optionally substituted alkyl, alkoxy, alkylamino or dialkylamino; Y stands for -CO-, -CS- or -SO2; and Z stands for optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aryl or heterocyclyl.
    • 本发明涉及甲酰胺的通式(I),它们的制备以及它们作为杀真菌剂的使用的几种方法其中Ar表示任选取代的亚芳基或亚杂芳基的衍生物中,E表示的1-烯烃-1,1-二基分组, 一个基团R <1>包含在2位,或表示2-氮杂-1-烯-1,1-二基分组其中基团R <2>包含2位,或任选取代的 亚氨基分组(“Azamethzylen”,NR <3>),或代表3-氮杂-1-丙烯-2,3-二基,其分组在位置1中的基团R <1>和3- 定位一个基团R <3>包含,或代表含有一个基团R <1>在1位上的3-氮杂-1-丙烯-2,3-二基分组,或代表3-硫杂-1- 丙烯-2,3-二基,其分组含有自由基中的R <1>,的1-位或表示1-氮杂-1-丙烯-2,3-二基部分,a的1位 R是基团R <3>包含<2>和在位置3,或FO R为在位置1中的基团R <1>和自由基含有在r <3>的3位上具有1-氮杂-1-丙烯-2,3-二基分组,或者为1.3 其中在位置1中的基团R <2>和自由基含有在r <3>,或3-位二氮杂-1-丙烯-2,3-二基分组表示1-氮杂-3-氧杂 -1-丙烯-2,3-二基,其分组一个基团R <2>包含在1-位,或表示1-氮杂-3-硫杂-1-丙烯-2,3-二基部分 含有残基R <2>包含在1-位,G表示单键,表示氧,硫或代表各自任选被卤素,羟基,烷基,卤代烷基取代的烷基或环烷基链烷二基,烯二,下面-Q分组中alkinediyl或一个 <1> -CQ <1> - ,-CQ <1> -Q <1> - ,-CH 2-Q <1> - ,-Q <1> -CH 2 - ,-CQ <1> -Q <1> -CH 2 - ,-CH 2-Q <1> -CQ <1> - ,-Q <1> -CQ <1>的-CH 2 - ,Q <1> -CQ <1> -Q <1> -CH2- , - N = N-,-S(O)N-,-CH 2 S(O)N-,-CQ <1> - , - S(O)N-CH 2 - ,-C(R <4>) = NOC(R <4>)= NO-CH 2 - ,-N(R <5>) - ,-CQ <1> -N(R <5>) - , - N(R <5>) - CQ < 1> - ,-Q <1> -CQ <1> -N(R <5>) - ,-N = C(R <4>) - Q <1> -CH 2 - ,-CH 2 ON = C(R <4>) - , - N(R <5>) - CQ <1> -Q < 1> - ,-CQ <1> -N(R <5>) - CQ <1> -Q <1> - , - N(R <5>) - CQ <1> -Q <1> -CH2- ,-Q <1> -C(R <4>)= NO-CH 2 - ,-N(R <5>) - C(R <4>)= NO-CH 2 - ,-O-CH2-C(R <4>)= NO-CH 2 - , - N = NC(R <4>)= NO-CH 2 - , - C(CH 3)-ON = C(R <4>) - , - C(= NOL) - C(R <4>)= NO-CH 2,-C(= NOL)-C(R <4>) - ON = CH-,-C(= NOL)-C(R <4>) - ON = C(CH 3) - ,-T-的Ar <1> - 或-T-的Ar <1> -Q <1> - ,R是氢,氨基或分别任选被取代的烷基,烷氧基,烷基氨基或二烷基氨基,Y -CO - , - CS-或-SO 2 Z表示分别任选被取代的烷基,烯基,炔基,环烷基,芳基或杂环基。