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    • 2. 发明申请
    • HERBICIDAL COMPOSITIONS COMPRISING PYROXASULFONE VI
    • 包含PYROXASULFONE VI的除草组合物
    • WO2009115420A2
    • 2009-09-24
    • PCT/EP2009/052717
    • 2009-03-09
    • BASF SESIEVERNICH, BerndSIMON, AnjaMOBERG, William KarlEVANS, Richard R.
    • SIEVERNICH, BerndSIMON, AnjaMOBERG, William KarlEVANS, Richard R.
    • A01N43/80A01N37/34A01N37/40A01N43/58A01N43/64A01N43/68A01N43/70A01N43/707A01N43/88A01N47/22A01N47/30A01N47/36A01N61/00A01N2300/00
    • The present invention relates to herbicidally active compositions, which comprise 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro- 5,5-dimethyl-1,2-oxazole [common name pyroxasulfone] and at least one herbicide B which is an inhibitor of the electron transfer in photosynthesis and which is selected from the groups of: b.1 arylurea herbicides; b.2 triazin(di)one herbicides; b.3 terbuthylazine; b.4 pyridazinone herbicides; b.5 phenylcarbamate herbicides; b.6 nitrile herbicides; b.7 bentazone and its salts such as bentazone sodium;and b.8 methylthiotriazine herbicides.The invention furthermore relates to the use of a composition as defined herein for controlling undesirable vegetation in crops which, by genetic engineering or by breeding, are resistant to one or more herbicides and/or pathogens, such as plant-pathogenous fungi, and/or to attack by insects; preferably resistant to one or more herbicides that act as inhibitor of the electron transfer in photosynthesis. The invention furthermore relates to a method for controlling undesirable vegetation, which comprises applying an herbicidal composition according to the present invention to the undesirable plants. Application can be done before, during and/or after, preferably during and/or after, the emergence of the undesirable plants. The herbicide A and the at least one herbicide B can be applied simultaneously or in succession.
    • 本发明涉及除草活性组合物,其包含3- [5-(二氟甲氧基)-1-甲基-3-(三氟甲基)吡唑-4-基甲基磺酰基] -4,5-二氢-5,5-二甲基-1,3- 2-恶唑[通用名]和至少一种作为光合作用中电子转移抑制剂的除草剂B,其选自以下基团:b.1芳基脲除草剂; b.2三嗪(二)一种除草剂; b.3特丁津 b.4哒嗪酮除草剂; b.5苯基氨基甲酸酯除草剂; b.6腈类除草剂; b.7苯扎他酮及其盐如苯扎酮钠;以及b.8甲硫基三嗪除草剂。本发明还涉及本文定义的组合物用于控制作物中不希望的植物的用途,所述作物通过遗传工程或育种抗性 一种或多种除草剂和/或病原体,例如植物病原真菌,和/或由昆虫攻击; 优选对一种或多种用作光合作用中电子转移抑制剂的除草剂具有抗性。 本发明还涉及一种控制不期望植物的方法,其包括将根据本发明的除草组合物施用于不期望的植物。 应用可以在不期望的植物的出现之前,期间和/或之后,优选地在和/或之后进行。 除草剂A和至少一种除草剂B可以同时或相继施用。
    • 5. 发明申请
    • HERBICIDAL COMPOSITIONS COMPRISING A 3-HETEROCYCLYL-SUBSTITUTED BENZOYL COMPOUND
    • 包含3-杂环取代的苯甲酰化合物的除草组合物
    • WO2007147828A1
    • 2007-12-27
    • PCT/EP2007/056097
    • 2007-06-19
    • BASF AKTIENGESELLSCHAFTEVANS, Richard R.
    • EVANS, Richard R.
    • A01N43/80A01N25/32A01P13/00
    • A01N43/80A01N25/32A01N43/56A01N2300/00
    • The present invention relates to herbicidal composition comprising: a) at least one 3-heterocyclyl-substituted benzoyl compound of the formula I wherein: R 1 , R 3 are halogen, C 1 -C 6 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 6 -alkoxy, C 1 -C 4 -haloalkoxy, C 1 -C 6 -alkylthio, C 1 -C 6 -alkylsulfinyl or C 1 -C 6 -alkylsulfonyl; R 2 is an optionally substituted heterocyclic radical selected from the group consisting of isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R 4 is hydrogen, halogen or C 1 -C 6 -alkyl; R 5 is C 1 -C 6 -alkyl; R 6 is hydrogen or C 1 -C 6 -alkyl; and/or an agriculturally acceptable salt thereof; and b) a at least one 3-sulfonylisoxazoline compound of formula II and/or an agriculturally acceptable salt thereof wherein: R 7 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; and R 8 is selected from the group of phenyl, naphthyl, pyrazolyl, isoxazolyl and pyridyl, the radicals being unsubstituted or optionally substituted.
    • 本发明涉及除草组合物,其包含:a)至少一种式I的3-杂环基取代的苯甲酰基化合物,其中:R 1,R 3,R 3是卤素,C C 1 -C 6 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 6 - C 1 -C 6 - 烷氧基,C 1 -C 4 - 卤代烷氧基,C 1 -C 3 C 1 -C 6 - 烷硫基,C 1 -C 6 - 烷基亚磺酰基或C 1 -C 6 - 烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基,4 ,5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或C 1 -C 6 - 烷基; R 5是C 1 -C 6 - 烷基; R 6是氢或C 1 -C 6 - 烷基; 和/或其农业上可接受的盐; 和b)至少一种式II的3-磺酰基异恶唑啉化合物和/或其农业上可接受的盐,其中:R 7是C 1 -C 4烷基, 烷基或C 1 -C 4 - 卤代烷基; R 8选自苯基,萘基,吡唑基,异恶唑基和吡啶基,该基团是未取代的或任选取代的。
    • 7. 发明申请
    • SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES III
    • 取代的1,2,5-氧杂氮杂化合物及其作为除草剂的用途
    • WO2013072450A1
    • 2013-05-23
    • PCT/EP2012/072810
    • 2012-11-16
    • BASF SE
    • KRAUS, HelmutWITSCHEL, MatthiasSEITZ, ThomasNEWTON, Trevor WilliamPARRA RAPADO, LilianaAPONTE, RaphaelKREUZ, KlausGROßMANN, KlausLERCHL, JensEVANS, Richard R.
    • C07D413/12C07D471/04A01N43/82
    • A01N43/82C07D413/12C07D471/04
    • The present invention relates to substituted 1,2,5-oxadiazole compounds of the formula I and the N-oxidesand saltsthereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. Wherein X 1 is N or CR 1 ; X 2 is N or CR 2 ; X 4 is N or CR 4 ; provided that a least one of X 1 , X 2 and X 4 is N; R is e.g. selected from the group consisting of hydrogen, cyano, nitro, halogen, C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl, C 3 -C 7 -cycloalkyl-C 1 -C 4 -alkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -alkynyl, C 2 -C 6 -haloalkynyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkyl, O-R a , Z-S(O) n -R b , Z-C(=O)-R c , Z-C(=O)-OR d , Z-C(=O)-N R e R f , Z-NR g R h , Z-phenyl and Z-heterocyclyl; R 1 is e.g. selected from the group consisting of Z 1 -cyano, halogen, nitro, C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl, C 2 -C 8 -alkynyl, C 1 -C 8 -haloalkyl, C 1 -C 8 -alkoxy, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -alkoxy-C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -alkylthio-C 1 -C 4 -alkylthio, C 2 -C 6 -alkenyloxy, C 2 -C 6 -alkynyloxy, C 1 -C 6 -haloalkoxy, C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkoxy, Z 1 -S(O) k -R 1b , Z 1 -phenoxy and Z 1 -heterocyclyloxy; R 2 , R 3 are identical or different and e.g. selected from the group consisting of hydrogen, halogen, Z 2 -OH, Z 2 -NO 2 , Z 2 -cyano, C 1 -C 6 -alkyl, C 2 -C 8 -alkenyl, C 2 -C 8 -alkynyl, Z 2 -C 3 -C 10 -cycloalkyl, Z 2 -C 3 -C 10 -cycloalkoxy, C 1 -C 8 -haloalkyl, Z 2 -C 1 -C 8 -alkoxy, Z 2 -C 1 -C 8 -haloalkoxy, Z 2 -C 1 -C 4 -alkoxy-C 1 -C 4 -alkoxy, Z 2 -C 1 -C 4 -alkylthio-C 1 -C 4 -alkylthio, etc., R 4 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C 1 -C 4 -alkyl and C 1 -C 4 -haloalkyl; R 5 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C 1 -C 4 -alkyl and C 1 -C 4 -haloalkyl.
    • 本发明涉及式I的取代的1,2,5-恶二唑化合物和N-氧化物和盐衍生物及其组合物。 本发明还涉及1,2,5-二唑化合物或包含这些化合物的组合物用于防治有害植物的用途。 其中X1为N或CR1; X2为N或CR2; X4是N或CR4; 条件是X1,X2和X4中的至少一个为N; R是例如 选自氢,氰基,硝基,卤素,C 1 -C 6 - 烷基,C 3 -C 7 - 环烷基,C 3 -C 7 - 环烷基-C 1 -C 4 - 烷基,C 1 -C 6 - 卤代烷基,C 2 -C 6 - 烯基, C 2 -C 6卤代链烯基,C 2 -C 6炔基,C 2 -C 6卤代炔基,C 1 -C 4烷氧基-C 1 -C 4烷基,C 1 -C 4卤代烷氧基-C 1 -C 4烷基,O-R a,ZS(O) n-Rb,ZC(= O)-Rc,ZC(= O)-ORd,ZC(= O)-N ReRf,Z-NRgRh,Z-苯基和Z-杂环基; R1是例如 选自Z1-氰基,卤素,硝基,C1-C8-烷基,C2-C8-烯基,C2-C8-炔基,C1-C8-卤代烷基,C1-C8-烷氧基,C1-C4-烷氧基 - C1-C4-烷基,Z1-C1-C4-烷氧基-C1-C4-烷氧基,C1-C4-烷硫基-C1-C4烷基,Z1-C1-C4-烷硫基-C1-C4-烷硫基,C2-C6- 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6卤代烷氧基,C 1 -C 4卤代烷氧基-C 1 -C 4烷基,Z 1 -C 1 -C 4卤代烷氧基-C 1 -C 4 - 烷氧基,Z 1 -S(O)k -R 1b, Z1-苯氧基和Z1-杂环氧基; R2,R3相同或不同, 选自氢,卤素,Z2-OH,Z2-NO2,Z2-氰基,C1-C6-烷基,C2-C8-烯基,C2-C8-炔基,Z2-C3-C10-环烷基,Z2- C 3 -C 10 - 环烷氧基,C 1 -C 8 - 卤代烷基,Z 2 -C 1 -C 8 - 烷氧基,Z 2 -C 1 -C 8 - 卤代烷氧基,Z 2 -C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷氧基,Z 2 -C 1 -C 4烷硫基 - C 1 -C 4 - 烷硫基等,R 4选自氢,卤素,氰基,硝基,C 1 -C 4 - 烷基和C 1 -C 4卤代烷基; R 5选自氢,卤素,氰基,硝基,C 1 -C 4 - 烷基和C 1 -C 4卤代烷基。
    • 8. 发明申请
    • SUBSTITUTED 1,2,5-OXADIAZOLE COMPOUNDS AND THEIR USE AS HERBICIDES II
    • 取代的1,2,5-氧杂吖啶化合物及其作为除草剂的用途II
    • WO2013072402A1
    • 2013-05-23
    • PCT/EP2012/072692
    • 2012-11-15
    • BASF SE
    • KRAUS, HelmutWITSCHEL, MatthiasSEITZ, ThomasNEWTON, Trevor WilliamPARRA RAPADO, LilianaAPONTE, RaphaelKREUZ, KlausGROSSMANN, KlausLERCHL, JensEVANS, Richard R.
    • C07D409/12C07D413/12C07D417/12A01N43/82
    • C07D413/12A01N43/82C07D409/12C07D413/14C07D417/12
    • The present invention relates to substituted 1,2,5-oxadiazole compounds of the formula (I) and the N-oxides and salts thereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. Furthermore, the invention relates to methods of applying such compounds. In formula I, the variables have the following meanings: R is e.g. hydrogen, cyano, nitro, halogen, C 1 -C 6 -alkyl, C 3 -C 7 -cycloalkyl, C 3 -C 7 -cycloalkyl-C 1 -C 4 -alkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -alkynyl, C 2 -C 6 -haloalkynyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkyl, O-R a , Z-S(O) n -R b , Z-C(=O)-R c , Z-C(=O)-OR d , Z-C(=O)-NR e R f , Z-NR g R h , Z-phenyl or Z-heterocyclyl;CYC is a bi- or tricyclic radical of the following formulae Cyc-1 or Cyc-2 where # is the point of attachment of the bicyclic radical to the carbonyl group, Q, Q' independently of each other are e.g. a fused 5-, 6-, 7-, 8-, 9- or 10-membered carbocycle or a fused 5-, 6-, 7-, 8-, 9- or 10-membered heterocycle; R 1 is e.g. Z 1 -cyano, halogen, nitro, C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl, C 2 -C 8 -alkynyl, C 1 -C 8 -haloalkyl, C 1 -C 8 -alkoxy, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -alkoxy-C 1 -C 4 -alkoxy, C 1 - C 4 -alkylthio-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -alkylthio-C 1 -C 4 -alkylthio, C 2 -C 6 -alkenyloxy, C 2 -C 6 - alkynyloxy, C 1 -C 6 -haloalkoxy, C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkyl, Z 1 -C 1 -C 4 -haloalkoxy-C 1 -C 4 - alkoxy, Z 1 -S(O) k -R 1b , Z 1 -phenoxy or Z 1 -heterocyclyloxy; R 3 is e.g. hydrogen, halogen, Z 3 -OH, Z 3 -NO 2 , Z 3 -cyano, C 1 -C 6 -alkyl, C 2 -C 8 - alkenyl, C 2 -C 8 -alkynyl, Z 2 -C 3 -C 10 -cycloalkyl, Z 3 -C 3 -C 10 -cycloalkoxy, C 1 -C 8 -haloalkyl, Z 3 -C 1 -C 8 -alkoxy, Z 3 -C 1 -C 8 -haloalkoxy, Z 3 -C 1 -C 4 -alkoxy-C 1 -C 4 -alkoxy, Z 3 -C 1 -C 4 -alkylthio-C 1 -C 4 -alkylthio, Z 3 -C 2 -C 8 -alkenyloxy, Z 3 -C 2 -C 8 -alkynyloxy, Z 3 -C 1 -C 8 -haloalkoxy, Z 3 -C 2 -C 8 - haloalkenyloxy, Z 3 -C 2 -C 8 -haloalkynyloxy, Z 3 -C 1 -C 4 -haloalkoxy-C 1 -C 4 -alkoxy, Z 3 -(tri-C 1 - C 4 -alkyl)silyl, Z 3 -S(O) k -R 3b , Z 3 -C(=O)-R 3c , Z 3 -C(=O)-OR 3d , Z 3 -C(=O)-NR 3e R 3f , Z 3 - NR 3g R 3h , Z 3a -phenyl or Z 3a -heterocyclyl; R 4 is hydrogen, halogen, cyano, nitro, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; R 5 is hydrogen, halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; provided that at least one of the radicals R 4 and R 5 is different from hydrogen; n is 0, 1 or 2; k is 0, 1 or 2; and the variables Z, Z 1 , Z 2 , Z 3 , Z 3a , R a , R b , R 1b , R 2b , R 3b , R c , R 2c , R 3c , R d , R 3d , R e , R f , R 3e , R 3f , R g , R h , R 2g , R 2h , R 3g and R 3h have the meanings given in the claims.
    • 本发明涉及式(I)的取代的1,2,5-恶二唑化合物及其N-氧化物及其盐及其组合物。 本发明还涉及1,2,5-二唑化合物或包含这些化合物的组合物用于防治有害植物的用途。 此外,本发明涉及应用这些化合物的方法。 在式I中,变量具有以下含义:R为例如 氢,氰基,硝基,卤素,C 1 -C 6 - 烷基,C 3 -C 7 - 环烷基,C 3 -C 7 - 环烷基-C 1 -C 4烷基,C 1 -C 6卤代烷基,C 2 -C 6 - 烯基,C 2 -C 6 - C 2 -C 6 - 炔基,C 2 -C 6 - 卤代炔基,C 1 -C 4 - 烷氧基-C 1 -C 4烷基,C 1 -C 4卤代烷氧基-C 1 -C 4烷基,O-R a,ZS(O)n -R b, = O)-Rc,ZC(= O)-OR d,ZC(= O)-NRRf,Z-NRgRh,Z-苯基或Z-杂环基; CYC是下式的二环或三环基团:Cyc-1或 Cyc-2其中#是双环基团与羰基的连接点,Q,Q'彼此独立地为例如 稠合的5-,6-,7-,8-,9-或10-元碳环或稠合的5-,6-,7-,8-,9-或10-元杂环; R1是例如 Z1-氰基,卤素,硝基,C1-C8-烷基,C2-C8-烯基,C2-C8-炔基,C1-C8-卤代烷基,C1-C8-烷氧基,C1-C4-烷氧基-C1-C4-烷基, Z 1 -C 1 -C 4烷氧基-C 1 -C 4烷氧基,C 1 -C 4烷硫基-C 1 -C 4烷基,Z 1 -C 1 -C 4烷硫基-C 1 -C 4烷硫基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 烷氧基,C 1 -C 6卤代烷氧基,C 1 -C 4卤代烷氧基-C 1 -C 4烷基,Z 1 -C 1 -C 4卤代烷氧基-C 1 -C 4烷氧基,Z 1 -S(O)k -R 1b,Z 1 - 苯氧基或Z 1 - 杂环; R3是例如 氢,卤素,Z3-OH,Z3-NO2,Z3-氰基,C1-C6-烷基,C2-C8-烯基,C2-C8-炔基,Z2-C3-C10-环烷基,Z3-C3-C10-环烷氧基, C 1 -C 8卤代烷基,Z 3 -C 1 -C 8 - 烷氧基,Z 3 -C 1 -C 8 - 卤代烷氧基,Z 3 -C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷氧基,Z 3 -C 1 -C 4 - 烷硫基-C 1 -C 4烷硫基, Z3-C2-C8-链烯氧基,Z3-C2-C8-炔氧基,Z3-C1-C8-卤代烷氧基,Z3-C2-C8-卤代烯氧基,Z3-C2-C8-卤代炔氧基,Z3-C1-C4-卤代烷氧基C1- C4-烷氧基,Z3-(三-C1 -C4烷基)甲硅烷基,Z3-S(O)k-R3b,Z3-C(= O)-R3c,Z3-C(= O)-OR3d,Z3-C (= O)-NR3eR3f,Z3-NR3gR3h,Z3a-苯基或Z3a-杂环基; R4是氢,卤素,氰基,硝基,C1-C4-烷基或C1-C4卤代烷基; R5是氢,卤素,C1-C4-烷基或C1-C4卤代烷基; 条件是基团R4和R5中的至少一个不同于氢; n为0,1或2; k为0,1或2; 变量Z,Z1,Z2,Z3,Z3a,Ra,Rb,R1b,R2b,R3b,Rc,R2c,R3c,Rd,R3d,Re,Rf,R3e,R3f,Rg,Rh,R2g,R2h,R3g 和R3h具有权利要求中给出的含义。