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    • 5. 发明申请
    • PROCESS FOR PREPARING CARBOXYLIC ESTERS BY REACTIVE DISTILLATION
    • 反应蒸馏法制备羧酸酯的方法
    • WO2011131643A3
    • 2011-12-29
    • PCT/EP2011056189
    • 2011-04-19
    • BASF SEKRONEMAYER HELMUTDAHLHOFF ELLENLANVER ANDREAS
    • KRONEMAYER HELMUTDAHLHOFF ELLENLANVER ANDREAS
    • C07C67/03
    • C07C67/03Y02P20/127C07C69/06
    • In a process for preparing carboxylic esters by transesterification, a first feed stream comprising a first carboxylic ester, e.g. methyl formate, is introduced at the side into a reaction column at a first inlet located between the top and the bottom of the reaction column and a second feed stream comprising a first alcohol, e.g. ethanol, is introduced at the side into the reaction column at a second inlet located above the first inlet and the feed streams are reacted in a reaction zone of the reaction column to form a second carboxylic ester and a second alcohol. The first alcohol has a higher molecular weight than the second alcohol. A product fraction comprising the second carboxylic ester and unreacted first carboxylic ester is taken off at an offtake located above the second inlet. A bottom fraction comprising the second alcohol and unreacted first alcohol is taken off at the bottom of the reaction column. The product fraction is separated by distillation at a pressure which is different from the pressure in the reaction column into second carboxylic ester and a fraction containing unreacted first carboxylic ester and the fraction containing unreacted first carboxylic ester is at least partly recirculated to the reaction zone.
    • 在通过酯交换反应制备羧酸酯的方法中,第一种进料包含第一种羧酸酯, 当甲酸甲酯包含时,位于反应塔的顶部和底部之间的至少一个第一进料点横向进入反应塔,并且第二进料包含第一醇,以用于。 作为乙醇,在位于第一进料点上方的第二进料点横向引入反应塔中,并在反应塔的反应区中反应以形成第二羧酸酯和第二醇。 第一种醇比第二种醇具有更高的分子量。 在位于第二进料点之上的取出点处,取出包含第二羧酸酯和未反应的第一羧酸酯的产物馏分。 在反应塔的底部,取出包含第二醇和未反应的第一醇的塔底馏分。 通过蒸馏进入第二Carbonsäureester和未反应的第一Carbonsäureester馏分产物部分的压力是从在反应塔中的压力不同的是分离的,并含有至少部分地返回到反应区中的未反应的第一Carbonsäureester所得的级分。