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    • 1. 发明申请
    • 1-(AZOLIN-2-YL)AMINO-1,2-DIPHENYLETHANE COMPOUNDS FOR COMBATING ANIMAL PESTS
    • 1-(AZOLIN-2-YL)氨基-1,2-二苯醚化合物,用于组合动物饲料
    • WO2009004032A1
    • 2009-01-08
    • PCT/EP2008/058517
    • 2008-07-02
    • BASF SEKORDES, MarkusKORADIN, ChristopherLE VEZOUET, RonanBAUMANN, ErnstCULBERTSON, Deborah L.ANSPAUGH, Douglas D.OLOUMI-SADEGHI, HassanEBUENGA, Cecile
    • KORDES, MarkusKORADIN, ChristopherLE VEZOUET, RonanBAUMANN, ErnstCULBERTSON, Deborah L.ANSPAUGH, Douglas D.OLOUMI-SADEGHI, HassanEBUENGA, Cecile
    • C07D233/48C07D263/28C07D277/18C07D417/12C07D417/06A01N43/50A01N43/76A01N43/78
    • C07D263/28A01N43/50A01N43/76A01N43/78A01N47/12A01N47/16C07D233/48C07D277/18C07D417/06C07D417/12
    • The present invention relates to 1-(azolin-2-yl)amino-1,2-diphenylethane compounds of the formula I and to their salts which are useful for combating animal pests. The invention also relates to a method for controlling animal pests by using these compounds, to seed and to an agricultural and veterinary composition comprising said compounds, wherein A is a radical of formulae A.1 or A.2 wherein # denotes the bond to the remaining compound of formula I, X is selected from O, S and NR x , R 1 is selected from the group consisting of -OR A , -NR B1 R B2 , -C(=O)-R C , -C(=O)-OR D , -C(=O)-SR E , -C(=O)-NR B1 R B2' , -C(=S)-R C' , -C(=S)-OR D' , -C(=S)-SR E' , -C(=S)-NR B1 R B2 , -C(=NR 1a )-R C' , -C(=NR 1b )-OR D' , -C(=NR 1c )-SR E' , -C(=NR 1d )-NR B1 R B2 , -S(=O)-R F , -S(=O) 2 -R G , -S(=O) 2 -NR B1 R B2' , -P(=O)R H1 R H2 , -P(=S)R H1 R H2 , -B-C(=O)-R I , -B-O-C(=O)-R I , -B-S-C(=O)-R I , -B-N(R J )-C(=O)-R K , -B-C(=S)-R K , -B-O-C(=S)-R K , -B-S-C(=S)-R K , -B-N(R J )-C(=S)-R K , C 1 -C 8 -alkenyl, C 1 -C 8 -alkynyl, C 3 -C 8 -cycloalkyl, which is unsubstituted or may carry 1 to 4 substituents R 1e , naphthyl, which is unsubstituted or may carry 1 to 4 substituents R 1f , a saturated or partially unsaturated heterocycle, which is unsubstituted or may carry 1 to 4 substituents R 1g , hetaryl, which is unsubstituted or may carry 1 to 4 substituents R 1h , and C 1 -C 6 -alkyl, which carries a radical selected from the group consisting of -NR 1i R 1j , C 1 -C 4 -alkoxycarbonyl, C 3 -C 8 -cycloalkyl, aryl, aryloxy, arylthio, heterocyclyl, heterocyclyloxy and heterocyclylthio, R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are each independently hydrogen, halogen, OH, SH, NH 2 , SO 3 H, COOH, cyano, nitro, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylamino etc.
    • 本发明涉及式I的1-(吡唑-2-基)氨基-1,2-二苯基乙烷化合物及其盐,其可用于防治动物害虫。 本发明还涉及通过使用这些化合物,种子和包含所述化合物的农业和兽医组合物来控制动物害虫的方法,其中A是式A.1或A.2的基团,其中#表示与 剩余的式I化合物,X选自O,S和NR x,R1选自-ORA,-NRB1RB2,-C(= O)-RC,-C(= O)-OR,-C (= O)-SRE,-C(= O)-NRB1RB2',-C(= S)-RC',-C(= S)-OR',-C(= S)-SRE' =(NR1c)-SR',-C(= NR1d)-NRB1RB2,-S(= O) )-RF,-S(= O)2 -RG,-S(= O)2 -NRB 1 R B 2',-P(= O)RH1RH 2,-P(= S)RH1RH 2,-BC(= O) -BOC(= O)-RI,-BSC(= O)-RI,-BN(RJ)-C(= O)-RK,-BC(= S)-RK,-BOC(= S)-RK, -BSC(= S)-RK,-BN(RJ)-C(= S)-RK,C1-C8-烯基,C1-C8-炔基,C3-C8-环烷基,其未被取代或可携带1至4 取代基R 1e,萘基,其是未取代的或可以携带1至4个取代基R 1f,饱和或部分不饱和的杂环,其为未制备的 或可以携带1至4个未取代的或可以携带1至4个取代基R 1h的取代基R 1g,杂芳基,其中C 1 -C 6 - 烷基带有选自以下的基团:-NR 1 1 R 1,C 1 -C 4 - 烷氧基羰基, C 3 -C 8 - 环烷基,芳基,芳氧基,芳硫基,杂环基,杂环基氧基和杂环硫基,R 2,R 3,R 4,R 5,R 6和R 7各自独立地为氢,卤素,OH,SH,NH 2,SO 3 H,COOH,氰基,硝基, C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基,C 1 -C 6烷基氨基等
    • 3. 发明申请
    • AZOLIN-2-YLAMINO COMPOUNDS FOR COMBATING ANIMAL PESTS
    • 用于组合动物饲料的AZOLIN-2-YLAMINO化合物
    • WO2009115491A1
    • 2009-09-24
    • PCT/EP2009/053079
    • 2009-03-16
    • BASF SELE VEZOUET, RonanKORDES, MarkusKORADIN, ChristopherBAUMANN, ErnstCULBERTSON, Deborah, L.
    • LE VEZOUET, RonanKORDES, MarkusKORADIN, ChristopherBAUMANN, ErnstCULBERTSON, Deborah, L.
    • C07D233/48C07D263/28C07D277/18C07C275/24C07C335/12A01N43/50A01N43/76A01N43/78A61P33/14A61P33/10
    • C07D263/28C07C275/24C07C335/12C07D233/48C07D277/18
    • The present invention relates to azolin-2-ylamino compounds of formulae (I) and (II), wherein n is 0 to 3; Ar is phenyl; A is a radical of formulae A 1 or A 2 , wherein * indicates the point of attachment; X is S, O or N(R 10 ); R 7a-d are H, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylamino or C 3 -C 6 -cycloalkyl; R 8-10 are H, CN, NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, Ar 3 , -B-C(=O)R a , -B-C(=S)R a , -B-C(=NR f )R a , etc., wherein B is a single bond or C 1 -C 4 -alkanediyl; R 1 is H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, phenyl or benzyl; R 2,3 are H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, phenyl or benzyl; R 4 is H, halogen, CN, N 3 , NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, a heterocycle, Ar 5 , -C(=O)R a, -C(=S)R a , -C(=NR f )R a , etc.; or R 4 and R 5 together form a carbocycle or heterocycle; R 5,6 are H, halogen, CN, N 3 , NO 2 , C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, heterocycle, Ar 8 , -C(=O)R a , -C(=S)R a , -C(=NR f )R a , etc.; or R 5 and R 6 together form a carbocycle or heterocycle; R a-h are H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 8 -cycloalkyl, heterocycles or Ar 10 ; Ar 1 to 11 are phenyl, naphthyl or heteroaryl; and A' is a radical of formula A 3 , wherein W is halogen or OR 11 ; R 11 is H or -C(=O)-R i ; R i is H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C3-C8-cycloalkyl, heterocycle or Ar 12 ; and Ar 12 is phenyl, naphthyl or heteroaryl; as well as to agricultural composition containing such compounds, the use of such compounds for controlling animal pests, seed, comprising such compounds, a method for controlling animal pests and a method for treating or protecting an animal from infestation or infection by parasites.
    • 本发明涉及式(I)和(II)的唑啉-2-基氨基化合物,其中n为0至3; Ar是苯基; A是式A1或A2的基团,其中*表示连接点; X是S,O或N(R10); R7a-d为H,卤素,C1-C6-烷基,C1-C6-烷氧基,C1-C6-烷基氨基或C3-C6-环烷基; R8-10是H,CN,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,Ar3,-BC(= O)Ra,-BC(= S) Ra,-BC(= NRf)Ra等,其中B为单键或C1-C4-烷二基; R1是H,卤素,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C6-环烷基,苯基或苄基; R2,3是H,卤素,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C6-环烷基,苯基或苄基; R4是H,卤素,CN,N3,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,杂环,Ar5,-C(= O) C(= S)Ra,-C(= NRf)Ra等; 或R4和R5一起形成碳环或杂环; R5,6是H,卤素,CN,N3,NO2,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C8-环烷基,杂环,Ar8,-C(= O) -C(= S)R a,-C(= NR f)R a等; 或R5和R6一起形成碳环或杂环; R h为H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 8 - 环烷基,杂环或Ar 10; Ar 1至11是苯基,萘基或杂芳基; 并且A'是式A3的基团,其中W是卤素或OR 11; R 11为H或-C(= O)-R i; R 1是H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 8环烷基,杂环或Ar 12; 和Ar 12是苯基,萘基或杂芳基; 以及含有这种化合物的农业组合物,这些化合物用于控制动物害虫,种子,包含这些化合物的用途,控制动物害虫的方法以及用于治疗或保护动物不受寄生虫感染或感染的方法。
    • 5. 发明申请
    • SUBSTITUTED AZOLIN-2-YL-AMINO COMPOUNDS
    • 取代的AZOLIN-2-YL-AMINO化合物
    • WO2008017649A1
    • 2008-02-14
    • PCT/EP2007/058109
    • 2007-08-06
    • BASF AKTIENGESELLSCHAFTKORADIN, ChristopherKORDES, MarkusLE VEZOUET, RonanCULBERTSON, Deborah L.ANSPAUGH, Douglas D.
    • KORADIN, ChristopherKORDES, MarkusLE VEZOUET, RonanCULBERTSON, Deborah L.ANSPAUGH, Douglas D.
    • C07D277/18C07D417/12A01N43/00
    • C07D417/12A01N43/50A01N43/76A01N43/78C07D277/18
    • The present invention relates to azolin-2-yl-amino compounds of formulae (I. a) and (l.b) and their salts which are useful for combating animal pest, in particular arthropod and nematodes. The present invention also relates to a method for combating such pests and for protecting crops against infestation or infection by such pests. Furthermore, the present invention relates to veterinary compositions for combating animal pests. Formula (I.a), formula (I.b) wherein n is 0 to 4; X is S, O or NR 5 ; A is -C(R 6a )(R 6b )-, O, NR 7 , S, S(O) or S(O) 2 ; B is a bond Or CH 2 ; R 1 is H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 2a , R 2b are H, CN, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, (C 1 -C 6 -alkyl)thiocarbonyl, C(O)NR a R b , C(S)NR a R b , (SO 2 )NR a R b , phenyl, benzyl, 5 or 6 membered heterocyclic ring etc.; or R 1 together with R 2a is C 3 -C 5 -alkandiyl; or R 1 together with R 2b are C(O); R 3a , R 3b , R 3c , R 3d are H, halogen, CN, C 1 -C 6 -alkyl, C 1 -C 6 -alkylamino, C 3 -C 6 -cycloalkyl, phenyl, benzyl, etc.; R 4a , R 4b are H, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, phenyl, benzyl, 5 or 6 membered hetaryl; or R 4a together with R 4b may also be =0, =NR C or =CR d R e ; or R 2a together with R 4a may form a bridging bivalent radical.
    • 本发明涉及用于对抗动物害虫,特别是节肢动物和线虫的式(Ⅰa)和(Ⅰ.B)的吡咯烷-2-基氨基化合物及其盐。 本发明还涉及一种防治这种害虫并防止作物抵抗这种害虫侵染或感染的方法。 此外,本发明涉及用于对抗动物害虫的兽用组合物。 式(Ⅰa),式(Ⅰb)其中n为0-4; X是S,O或NR 5; A是-C(R 6a)(R 6b) - ,O,NR 7,S,S(O)或S(O ) 2 ; B是键或CH 2 2; R 1是H,CN,C 1 -C 6 - 烷基,C 2 -C 3 - C 1 -C 6 - 亚烷基,C 1 -C 6 - 烷基羰基,C 3 -C 6 - 环烷基,苯基,苄基等; R 2a,R 2b是H,CN,C 1 -C 6 - 烷基,C 1 -C 6烷基, C 1 -C 6亚烷基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - 烷基羰基,C 1 -C 6 - C 6 -C 6 - 烷氧基羰基,(C 1 -C 6 - 烷基)硫代羰基,C(O)NR a C C(S)NR a R b,(SO 2)NR a, 苯基,苄基,5或6元杂环等; 或R 1与R 2a一起为C 3 -C 5 - 亚烷基; 或R 1和R 2b一起是C(O); R 3a,R 3b,R 3c,R 3d是H,卤素,CN,C C 1 -C 6 - 烷基,C 1 -C 6 - 烷基氨基,C 3 - C 6 -C 6 - 环烷基,苯基,苄基等; R 4a,R 4b是H,卤素,C 1 -C 6 - 烷基,C 1 -C 4烷基, C 2 -C 6 - 烯基,苯基,苄基,5或6元杂芳基; 或R 4a与R 4b一起也可以是= 0,= NR C或= CR D, SUP>电子; 或R 2a与R 4a一起可以形成桥连二价基团。
    • 6. 发明申请
    • PESTICIDAL ACTIVE MIXTURES COMPRISING AMINOTHIAZOLINE COMPOUNDS
    • 包含氨基苯甲酸化合物的农药活性混合物
    • WO2009118297A2
    • 2009-10-01
    • PCT/EP2009/053402
    • 2009-03-24
    • BASF SEKORDES, MarkusVEZOUET, Ronan LeLANGEWALD, JürgenPAULINI, RalphCULBERTSON, Deborah L.ANSPAUGH, Douglas D.JOSE, Luiz AntonioOLOUMI-SADEGHI, Hassan
    • KORDES, MarkusVEZOUET, Ronan LeLANGEWALD, JürgenPAULINI, RalphCULBERTSON, Deborah L.ANSPAUGH, Douglas D.JOSE, Luiz AntonioOLOUMI-SADEGHI, Hassan
    • A01N43/78A01P5/00A01P7/02A01P7/04
    • A01N43/78A01N43/08A01N43/40A01N43/54A01N43/56A01N43/58A01N43/707A01N43/88A01N43/90A01N47/02A01N47/06A01N47/30A01N47/34A01N47/40A01N51/00A01N53/00A01N2300/00
    • The present invention relates to pesticidal mixtures comprising as active compounds 1 ) at least one aminothiazoline compound (I) of formula (I), tautomer a), b) wherein R 1 is selected from hydrogen, COCH 3 , COCH 2 CH 3 or COCH 2 C(CH 3 ) 3 ; R 2 and R 3 together with the carbon atoms of the phenyl ring to which they are attached form a ring which, depending on the tautomeric formula I a) or b) is depicted as: a benzene ring, a saturated 5-, 6-, or 7-membered carbocycle, a partially unsaturated 5-, 6-, or 7-membered carbocycle, a 5-, 6-, or 7-membered saturated heterocycle, a partially unsaturated 5-, 6-, or 7-membered heterocycle, which heterocycles contain 1, 2, or 3 heteroatoms selected from O, S and N as ring members, and a 5- or 6- membered heteroaromatic ring which contains 1, 2, or 3 heteroatoms selected from O, S and N as ring members, and wherein the ring is unsubstituted or may carry any combination of 1, 2, 3, or 4 radicals selected from the group consisting of halogen, CH 3 , CH 2 CH 3 , CF 3 , CH 3 O, cyano and (=0) (oxo); R 4 is selected from hydrogen, fluoro, chloro, bromo, CF 3 , CH 3 O or CH 3 ; R 5 , R 6 are selected from hydrogen, chloro, fluoro, bromo, CH 3 , CH 3 O or CF 3 , wherein at least one of R 5 or R 6 is not hydrogen; with the proviso that R 2 and R 3 together do not form a -OCH 2 -O- or a -OCF 2 O-group; or the tautomers, enantiomers, diastereomers or salts thereof, and 2) at least one active compound Il selected from group A as defined in the description, use of these mixtures for combating insects, acarids, or nematodes, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using these mixtures.
    • 本发明涉及包含作为活性化合物的至少一种式(I)的至少一种氨基噻唑啉化合物(I),互变异构体a),b)其中R 1选自氢,COCH 3,COCH 2 CH 3或COCH 2 C(CH 3)3的农药混合物; R2和R3与它们所连接的苯环的碳原子一起形成环,其取决于互变异构体式a a)或b)被描述为:苯环,饱和的5-,6-或 7元碳环,部分不饱和5-,6-或7-元碳环,5-,6-或7-元饱和杂环,部分不饱和5-,6-或7-元杂环,其中 杂环含有选自O,S和N作为环成员的1,2或3个杂原子,以及含有1,2或3个选自O,S和N作为环成员的杂原子的5-或6-元杂芳族环, 并且其中所述环是未取代的或可以携带选自卤素,CH 3,CH 2 CH 3,CF 3,CH 3 O,氰基和(= O)(氧代)的1,2,3或4个基团的任何组合。 R4选自氢,氟,氯,溴,CF 3,CH 3 O或CH 3; R5,R6选自氢,氯,氟,溴,CH3,CH3O或CF3,其中R5或R6中的至少一个不是氢; 条件是R2和R3一起不形成-OCH2-O-或-OCF2O-基团; 或其互变异构体,对映异构体,非对映异构体或其盐,以及2)选自如说明书中定义的组A的至少一种活性化合物II,这些混合物用于防治昆虫,螨虫或线虫的用途,以及治疗,控制 ,防止或保护动物免受使用这些混合物的寄生虫的感染或感染。
    • 8. 发明申请
    • RESORCINE DERIVATIVES AND THEIR USE AS PESTICIDES
    • WO2007054558A3
    • 2007-05-18
    • PCT/EP2006/068329
    • 2006-11-10
    • BASF AKTIENGESELLSCHAFTPUHL, MichaelKORDES, MarkusPOHLMAN, MatthiasGÖTZ, NorbertRACK, MichaelLANGEWALD, JürgenSCHNEIDER, FelixANSPAUGH, Douglas D.CULBERTSON, Deborah L.OLOUMI-SADEGHI, HassanKUHN, David G.
    • PUHL, MichaelKORDES, MarkusPOHLMAN, MatthiasGÖTZ, NorbertRACK, MichaelLANGEWALD, JürgenSCHNEIDER, FelixANSPAUGH, Douglas D.CULBERTSON, Deborah L.OLOUMI-SADEGHI, HassanKUHN, David G.
    • C07C43/29C07D213/16C07D213/26C07D277/22A01N29/10
    • This invention relates to resorcine derivatives of formula (I) wherein R 1 is phenyl or a 5- to 6-membered heteroaromatic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the heteroaromatic ring may be fused to a ring selected from phenyl and a 5- to 6-membered saturated, partially unsaturated or aromatic heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, nitrogen and sulfur, wherein phenyl or the 5- to 6-membered heteroaromatic ring or the respective fused ring systems may be unsubstituted or substituted by any combination of 1 to 6 optionally substituted groups R 3 , wherein R 3 is halogen, cyano, nitro, hydroxy, mercapto, amino, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, halocycloalkenyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, haloalkenyloxy, haloalkynyloxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, haloalkenylthio, haloalkynylthio, alkylamino, alkenylamino, alkynylamino, dialkylamino, dialkenylamino, dialkynylamino, alkyl-alkenylamino, alkyl-alkynylamino, alkenyl- alkynylamino, trialkylsilyl, or phenyl or a 5-to 7-membered saturated or partially unsaturated heterocyclic ring which may contain 1 to 3 heteroatoms selected from oxygen, sulfur and nitrogen or a 5- to 6-membered heteraromatic ring system which may contain 1 to 4 heteroatoms selected from oxygen, nitrogen and sulfur, which phenyl and which heteroaromatic ring may be bonded via an oxygen or a sulfur atom, or -C(=G)R a , -C(=G)OR a , -C(=G)NR a 2 , -C(=G)[N=SR a 2 ], -C(=NOR a )R a , -C(=NOR a )NR a 2 , -C(=NNR a 2 )R a , -OC(=G)-OC(=G)OR a , N=SR a 2 , -NR a C(=G)R a , -N[C(=G)R a ] 2 , - NR a C(=G)OR a , -C(=G)NR a -NR a 2 , -C(=G)NR a -NR a [C(=G)R a ], -NR a -C(=G)NR a 2 , -NR a -NR a C(=G)R a , -NR a -N[C(=G)R a ] 2 , -N[(C=G)R a ]-NR a 2 , -NR a -NR a [(C=G)GR a ], -NR a [(C=G)NR a 2 , -NR a [C=NR a ]R a , -NR a (C=NR a )NR a 2 , -O-NR a 2 , -O-NR a (C=G)R a , - SO 2 NR a 2 , -NR a SO 2 R a , -S(=O)R a , -S(=O) 2 R a , -SO 2 OR a , or -OSO 2 R a , wherein G is oxygen or sulfur and Ra is as defined in the description, R 2 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, alkoxy, or haloalkoxy, x is 2, 3, 4, 5, 6, or 7, or the diastereomers, enantiomers, salts or N-oxides thereof, with the proviso that R 1 is not 5-chloro-2,2,-dimethyl-2,3-dihydrobenzo[b]furan-7-yl when R 2 is hydrogen and x is 3 or 4, processes and intermediates for the preparation of compounds I, use of compounds I for combating insects, acarids, or nematodes, and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using compounds I.