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    • 4. 发明申请
    • SUBSTITUTED TERRYLENE AND QUATERRYLENE DERIVATIVES AND THE USE AS SEMICONDUCTORS
    • 取代的叔丁基和季戊四醇衍生物和作为半导体的用途
    • WO2014002061A2
    • 2014-01-03
    • PCT/IB2013/055309
    • 2013-06-28
    • BASF SEMAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E. V.BASF (CHINA) COMPANY LIMITEDGEßNER, ThomasREICHELT, HelmutBATTAGLIARIN, GlaucoLI, ChenMÜLLEN, Klaus
    • GEßNER, ThomasREICHELT, HelmutBATTAGLIARIN, GlaucoLI, ChenMÜLLEN, Klaus
    • H01L51/0072C07D471/06C07D487/06C07F5/04C09B5/62H01L27/283H01L51/0053H01L51/0545H01L51/0558H01L51/105H01L51/5012H01L51/5088H01L51/5234Y02E10/549
    • The present invention relates to terrylene and quaterrylene derivates of the general formula I (formula I) (I) wherein n is 0 or 1, R a and R b are independently of one another selected from hydrogen and in each case unsubstituted or substituted alkyl, alkenyl, alkadienyl, alkynyl, cycloalkyl, bicyclo- alkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl, X 1 , X 2 , X 3 and X 4 are independently of one another selected from F, CI, Br, I, CN and B(OR c ) 2 , wherein R c is selected from in each case unsubstituted or substituted alkyl, cycloalkyl or aryl, or wherein two radicals R c may together form a divalent bridging group selected from in each case unsubstituted or substituted C 2 - C 10 -alkylene, C 3 -C 6 -cycloalkylene and C 6 -C 14 -arylene, wherein C 2 -C 10 - alkylene, C 3 -C 6 -cycloalkylene and C 6 -C 14 -arylene may carry one or more identical or different C 2 -C 12 -alkyl radicals, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 11 and R 12 and, if present, R 7 , R 8 , R 9 and R 10 are independently of one another selected from hydrogen, F, CI, Br, I, CN, hydroxy, mercapto, nitro, cyanato, thiocyanato, formyl, acyl, carboxy, carboxylate, alkylcarbonyloxy, car¬ bamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, sulfo, sulfonate, sulfoamino, sulfamoyl, alkylsulfonyl, arylsulfonyl, amidino, NE 1 E 2 , where E 1 and E 2 are each independently selected from hydrogen, alkyl, cycloalkyi, heterocycloalkyl, aryl or hetaryl, in each case unsubstituted or substituted alkyl, alkoxy, alkylthio, (monoal- kyl)amino, (dialkyl)amino, cycloalkyi, cycloalkoxy, cycloalkylthio, (monocycloal- kyl)amino, (dicycloalkyl)amino, heterocycloalkyi, heterocycloalkoxy, heterocyclo- alkylthio, (monoheterocycloalkyl)amino, (diheterocycloalkyl)amino, aryl, aryloxy, arylthio, (monoaryl)amino, (diaryl)amino, hetaryl, hetaryloxy, hetarylthio, (mono- hetaryl)amino, (dihetaryl)amino, and the use thereof as organic semiconductor materials.
    • 本发明涉及通式I(式I)(I)的二亚烷基和四亚甲基衍生物,其中n为0或1,Ra和Rb彼此独立地选自氢,并且在每种情况下均为未取代或取代的烷基,烯基, 链烯基,炔基,环烷基,双环烷基,环烯基,杂环烷基,芳基或杂芳基,X1,X2,X3和X4彼此独立地选自F,Cl,Br,I,CN和B(ORc)2,其中Rc 在每种情况下选自未取代或取代的烷基,环烷基或芳基,或其中两个基团Rc可以一起形成二价桥基,其选自在每种情况下未取代或取代的C 2 -C 10 - 亚烷基,C 3 -C 6 - 亚环烷基和C 6 -C 14 亚芳基,其中C 2 -C 10 - 亚烷基,C 3 -C 6 - 亚环烷基和C 6 -C 14亚芳基可以携带一个或多个相同或不同的C 2 -C 12 - 烷基,R 1,R 2,R 3,R 4,R 5,R 6,R 11和 R 12,如果存在,R 7,R 8,R 9和R 10彼此独立地选自氢, F,Cl,Br,I,CN,羟基,巯基,硝基,氰基,硫氰酸酯,甲酰基,酰基,羧基,羧酸酯,烷基羰氧基,羧酰基,烷基氨基羰基,二烷基氨基羰基,磺基,磺酸酯基,磺氨基,氨磺酰基,烷基磺酰基,芳基磺酰基, 脒基,NE1E2,其中E1和E2各自独立地选自氢,烷基,环烷基,杂环烷基,芳基或杂芳基,在每种情况下为未取代或取代的烷基,烷氧基,烷硫基,(单烷基)氨基,(二烷基)氨基, ,环烷氧基,环烷硫基,(单环烷基)氨基,(二环烷基)氨基,杂环烷基,杂环烷氧基,杂环烷硫基,(单杂环烷基)氨基,(二杂环烷基)氨基,芳基,芳氧基,芳硫基,(单芳基)氨基,(二芳基)氨基 ,杂芳基,杂芳氧基,杂芳硫基,(单杂芳基)氨基,(二杂芳基)氨基及其作为有机半导体材料的用途。