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    • 3. 发明申请
    • METHOD FOR THE PRODUCTION OF THERMALLY CROSS-LINKED LASER ENGRAVABLE FLEXOGRAPHIC ELEMENTS
    • 生产热交联,激光切割柔性版印刷元件的方法
    • WO02054154A3
    • 2002-09-19
    • PCT/EP0200066
    • 2002-01-07
    • BASF DRUCKSYSTEME GMBHTELSER THOMASSCHADEBRODT JENSHILLER MARGITWENZL WOLFGANG
    • TELSER THOMASSCHADEBRODT JENSHILLER MARGITWENZL WOLFGANG
    • G03F7/004B41C1/05B41N1/12G03F7/00G03F7/11
    • B41C1/05Y10S430/146
    • Disclosed is a method for the production of a laser engravable flexographic element with a thermally cross-linked elastomer laser engravable relief-forming layer (E), comprising the following steps: (i) production of a multilayer composite at least comprising one two-layer composite made of a deposit layer (D) and a non cross-linked precursor layer (V) for the relief-forming layer (E) disposed in a directly adjacent position with respect to the deposit layer (D), and optionally other layers, carrier films and/or protective films, whereby the precursor layer (V) contains (a) at least one elastomer binding agent, (b) at least one ethylenically unsaturated monomer, (c) optionally one absorber for laser radiation, and (d) optionally other additives and the deposit layer (D) contains at least one elastomer binding agent, (f) at least one thermally decomposing polymerisation initiator, (g) optionally one absorber for laser radiation and (h) other additives; (ii) the thermally decomposing polymerisation initiators are allowed to diffuse inwards into the precursor layer (V) from the deposit layer (D); (iii) the deposit layer (D) is optionally removed; and (iv) the precursor layer (V) is thermally cross-linked to the cross-linked elastomer laser engravable relief-forming layer (E).
    • 公开的是用于制造可激光雕刻的柔性版印刷部件,包括一个热交联,弹性体的,可激光雕刻的凸版形成层E.包括下列步骤的方法:(i)至少一种制备多层复合材料,其包括两层复合组成的贮库层d和贮库层d直接相邻的非交联的前体V层中的一个的 对于凸版形成层E,和任选的其它层中,背衬片和/或保护膜,其中,所述前体层V(a)至少一种弹性体的粘合剂,(b)至少一种烯属不饱和单体,(c)任选地(对于激光辐射的吸收器;和d )任选的其他添加剂,其中所述贮库层d(e)至少一种弹性体的粘合剂,(f)如需要的话,任选地含有至少一种可热分解的聚合引发剂,(G),用于激光辐射的吸收器,以及(h)其它添加剂,(ⅱ)Eindiffundie (iii)任选地去除沉积层D,和(iv)使前体层V热交联以形成交联的弹性体可激光雕刻的凸版形成层E.