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1. 发明申请

WO2007037860A1 CLEARCOAT PAINT COMPOSITION 审中-公开
标题翻译： CLEARCOAT涂料组合物
公开(公告)号：WO2007037860A1
公开(公告)日：2007-04-05
申请号：PCT/US2006/033042
申请日：2006-08-24
申请人： BASF CORPORATION , RAMESH, Swaminathan , CAMPBELL, Donald , GREEN, Marvin , RINK, Heinz-Peter
发明人： RAMESH, Swaminathan , CAMPBELL, Donald , GREEN, Marvin , RINK, Heinz-Peter
IPC分类号： C09D201/02 , C09D133/06
CPC分类号： C09D133/06 , C08F8/14 , C08F220/06 , C08F220/18 , C08F220/32 , C08F220/36 , C09D4/00 , C09D133/062 , C09D201/025 , C08L2666/02
摘要： A coating composition including a copolymerization product of a mixture of monomers including one or more carbamate-functional monomers and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomers. The coating composition may be a solvent- borne clearcoat coating composition, preferably an automotive clearcoat coating composition, that may be applied over a water-borne basecoat coating composition.
摘要翻译：一种涂料组合物，其包括包含一种或多种氨基甲酸酯官能单体和（甲基）丙烯酸单体的单体混合物的共聚产物，一些具有羧酸官能团。单体混合物基本上不含羟基单体。涂料组合物可以是可涂覆在水性底涂层组合物上的溶剂型透明涂料涂料组合物，优选汽车透明涂料涂料组合物。

2. 发明申请

WO2002068553A2 CARBAMATE-FUNCTIONAL, RESINS AND THEIR USE IN HIGH SOLIDS COATING COMPOSITIONS 审中-公开
标题翻译：碳酸盐功能，树脂及其在高固体涂料组合物中的用途
公开(公告)号：WO2002068553A2
公开(公告)日：2002-09-06
申请号：PCT/US2001/044565
申请日：2001-11-28
申请人： BASF CORPORATION , RAMESH, Swaminathan , GREEN, Marvin , CAMPBELL, Donald , OHRBOM, Walter
发明人： RAMESH, Swaminathan , GREEN, Marvin , CAMPBELL, Donald , OHRBOM, Walter
IPC分类号： C09D201/02
CPC分类号： C09D201/025 , C09D201/005 , Y10T428/31511 , Y10T428/31551
摘要： The present invention provides a coating composition containing 1) a carbamate-functional resin having in its structure a hyperbranched or star polyol core, a first chain extension based on a polycarboxylic acid or anhydride, a second chain extension based on an epoxy containing compound, and having carbamate functional groups on the core, the second chain extension, or both; and 2) a second resin containing functional groups reactive with the carbamate groups on the carbamate-functional resin. In one embodiment, the coating compositions are used as a clearcoat to be applied over a basecoat to form a composite coating. The compositions exhibit a combination of desirable properties, such as scratch and mar resistance, resistance to environmental etch, good intercoat adhesion, and high solids.
摘要翻译：本发明提供了一种涂料组合物，其含有1）氨基甲酸酯官能树脂，其结构为超支化或星形多元醇芯，基于多元羧酸或酸酐的第一链延伸，基于含环氧化合物的第二链延伸，以及在芯上具有氨基甲酸酯官能团，第二链延伸或两者; 和2）含有与氨基甲酸酯官能树脂上的氨基甲酸酯基反应的官能团的第二树脂。在一个实施方案中，涂料组合物用作透明涂层以涂布在底涂层上以形成复合涂层。组合物显示出所需性能的组合，例如耐刮擦和耐擦伤性，耐环境腐蚀性，良好的涂层间粘附性和高固体。

3. 发明申请

WO2006039122A2 FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION 审中-公开
标题翻译：功能性添加聚合物及其制备方法
公开(公告)号：WO2006039122A2
公开(公告)日：2006-04-13
申请号：PCT/US2005/033201
申请日：2005-09-16
申请人： BASF CORPORATION , OHRBOM, Walter , CAMPBELL, Donald , ST. AUBIN, Donald , RAMESH, Swaminathan , RÖCKRATH, Ulrike , HARRIS, Paul
发明人： OHRBOM, Walter , CAMPBELL, Donald , ST. AUBIN, Donald , RAMESH, Swaminathan , RÖCKRATH, Ulrike , HARRIS, Paul
IPC分类号： C08F8/14 , C08F8/30 , C08F222/20 , C08F222/22 , C09D201/02
CPC分类号： C08F222/20 , C08F8/14 , C08F220/06 , C08F220/08 , C08F222/22 , C08G18/00 , C09D201/025 , Y10T428/31511 , C08F265/06
摘要： Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C=C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.
摘要翻译：公开了一种从线性不饱和酸酐制造非功能性加成聚合物的方法。该方法使线性不饱和酸酐化合物，活性氢化合物和环氧化合物进行反应，使得发生以下三个反应中的每一个：（i）可聚合的C = C键的聚合，（ii）酸酐的开环通过活性氢化合物的线性不饱和酸酐化合物的官能团，以产生酸官能团，和（iii）由酸酐开环产生的酸官能团与环氧化合物的反应。在反应（iii）时，由酸酐开环产生的酸官能团可以选自烯属不饱和单体，聚合物或两者。在一个实施方案中，该方法不包括物理去除任何酸官能单体或聚合产物。还公开了可固化涂料组合物和涂布的基材。

4. 发明申请

WO2006063304A1 COATING COMPOSITION 审中-公开
标题翻译：涂料组合物
公开(公告)号：WO2006063304A1
公开(公告)日：2006-06-15
申请号：PCT/US2005/044767
申请日：2005-12-09
申请人： BASF CORPORATION , MENOVCIK, Gregory , OHRBOM, Walter , RAMESH, Swaminathan , LAMBERTY, Paul , BOISSEAU, John , CAMPBELL, Donald
发明人： MENOVCIK, Gregory , OHRBOM, Walter , RAMESH, Swaminathan , LAMBERTY, Paul , BOISSEAU, John , CAMPBELL, Donald
IPC分类号： C09D7/06 , C09D5/02 , C09D5/03 , C09D201/02
CPC分类号： C09D133/14 , C08L33/04 , C09D5/024 , C09D175/04 , C09D201/025 , C08L2666/04 , C08L2666/16
摘要： A composition comprising a binder polymer with a first functional group that is reactive with a second functional group, a crosslinking agent with the second functional group, and a polymer additive with a third functional group that can react with the second functional group and may optionally contain additional functionality which does not react with the first or second functional group and wherein said polymer additive will concentrate more at a surface interface region of a cured film formed from the composition than in the bulk of the coating.
摘要翻译：一种组合物，其包含具有与第二官能团反应的第一官能团的粘合剂聚合物，具有第二官能团的交联剂和具有可与第二官能团反应的第三官能团的聚合物添加剂，并且可任选地含有不与第一或第二官能团反应的附加官能团，并且其中所述聚合物添加剂将更多地集中在由所述组合物形成的固化膜的表面界面区域而不是在所述涂层的主体中。

5. 发明申请

WO2004003051A1 CARBAMATE-FUNCTIONAL POLYMER, CURABLE COATING COMPOSITION THEREOF, ANDMETHOD OF PREPARING THE POLYMER 审中-公开
标题翻译：碳酸酯官能聚合物，其可固化涂料组合物，制备聚合物的方法
公开(公告)号：WO2004003051A1
公开(公告)日：2004-01-08
申请号：PCT/US2003/014421
申请日：2003-05-09
申请人： BASF CORPORATION GENERAL COUNSEL , CAMPBELL, Donald , RAMESH, Swaminathan
发明人： CAMPBELL, Donald , RAMESH, Swaminathan
IPC分类号： C08G59/40
CPC分类号： C08G59/4215 , C08G59/3245 , C09D163/06 , C08L2666/16
摘要： The present invention is directed to a carbamate-functional polymer that is used to promote the acid etch resistance and recoat adhesion of coating compositions. The polymer is the reaction product of a first compound having a hydroxyl group and a carbamate group, and a carboxylic acid anhydride that is reactive with the hydroxyl group of the first compound. The first compound and the carboxylic acid anhydride form an intermediate compound having a carboxylic acid group and the carbamate group. A second compound has an epoxy group that is reactive with the carboxylic acid group of the intermediate compound for preparing the carbamate-functional polymer. The present invention is also directed to a curable coating composition including the polymer and a method of preparing the polymer.
摘要翻译：本发明涉及一种氨基甲酸酯官能聚合物，其用于促进涂料组合物的耐酸蚀性和重涂性。聚合物是具有羟基和氨基甲酸酯基的第一化合物和与第一化合物的羟基反应的羧酸酐的反应产物。第一化合物和羧酸酐形成具有羧酸基和氨基甲酸酯基的中间体化合物。第二化合物具有与用于制备氨基甲酸酯官能聚合物的中间体化合物的羧酸基反应的环氧基。本发明还涉及包含聚合物的可固化涂料组合物和制备聚合物的方法。

6. 发明申请

WO2006039013A1 CARBAMATE FUNCTIONAL ADDITION POLYMERS AND A METHOD FOR THEIR PREPARATION 审中-公开
标题翻译：碳酸酯官能添加聚合物及其制备方法
公开(公告)号：WO2006039013A1
公开(公告)日：2006-04-13
申请号：PCT/US2005/030248
申请日：2005-08-26
申请人： BASF CORPORATION , OHRBOM, Walter , CAMPBELL, Donald , ST. AUBIN, Donald , RAMESH, Swaminathan , HARRIS, Paul , RÖCKRATH, Ulrike
发明人： OHRBOM, Walter , CAMPBELL, Donald , ST. AUBIN, Donald , RAMESH, Swaminathan , HARRIS, Paul , RÖCKRATH, Ulrike
IPC分类号： C08F20/00
CPC分类号： C08F220/06 , C08F8/00 , C08F8/14 , C08F220/08 , C08F222/20 , C08F222/22 , C08L2312/00 , C09D133/14 , C09D201/025 , C08F265/06
摘要： Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C=C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C=C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.
摘要翻译：公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C = C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C = C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

7. 发明申请

WO2007016534A1 ORGANIC DISPERSIONS OF INORGANIC PARTICLES AND COATING COMPOSITIONS CONTAINING THEM 审中-公开
标题翻译：无机颗粒和含有它们的涂料组合物的有机分散体
公开(公告)号：WO2007016534A1
公开(公告)日：2007-02-08
申请号：PCT/US2006/029860
申请日：2006-07-31
申请人： BASF CORPORATION , CAMPBELL, Donald
发明人： CAMPBELL, Donald
IPC分类号： C09D7/00
CPC分类号： C09D7/00 , C09D7/80
摘要： The present invention provides a method of preparing an organosol of inorganic particles, comprising mixing an aqueous dispersion or sol of inorganic particles with an organic liquid and a polymer or oligomer having functionality that adsorbs onto the inorganic particles; and allowing the mixture to separate into an aqueous layer and an organic layer, the organic layer comprising the inorganic particles. The invention also provides a polymer composition or coating composition made by this method. A coating composition is applied to a substrate and cured to provide a coating layer on the substrate. A polymer composition containing the inorganic particles is molded into an article.
摘要翻译：本发明提供一种制备无机颗粒的有机溶胶的方法，包括将无机颗粒的水性分散体或溶胶与有机液体和具有吸附在无机颗粒上的官能团的聚合物或低聚物混合; 并使混合物分离成水层和有机层，有机层包含无机颗粒。本发明还提供了通过该方法制备的聚合物组合物或涂料组合物。将涂料组合物施加到基材上并固化以在基材上提供涂层。将含有无机颗粒的聚合物组合物模制成制品。

8. 发明申请

WO2002086001A1 CURABLE COATING COMPOSITIONS HAVING IMPROVED COMPATIBILITY AND SCRATCH AND MAR RESISTANCE, CURED COATED SUBSTRATES MADE THEREWITH AND METHODS FOR OBTAINING THE SAME COATING 审中-公开
标题翻译：具有改进的兼容性和剥离性和耐电弧性的可固化涂料组合物，其固化的涂覆基材和用于获得相同涂层的方法
公开(公告)号：WO2002086001A1
公开(公告)日：2002-10-31
申请号：PCT/US2002/012845
申请日：2002-04-23
申请人： BASF CORPORATION , CAMPBELL, Donald , COOK, Vincent , OERMANN, Bruce , BEARYMAN, William
发明人： CAMPBELL, Donald , COOK, Vincent , OERMANN, Bruce , BEARYMAN, William
IPC分类号： C09D201/02
CPC分类号： C09D201/025 , C08L61/32 , C09D133/14 , C09D161/20 , C09D161/34 , C09D175/04 , Y10T428/31551 , C08L2666/16
摘要： The invention provides coating compositions having improved scratch and mar resistance. The curable coating compositions of the invention comprise a film-forming component (A) comprising one or more active hydrogen containing components (a), and one or more curing agents (b) comprising at least one aminoplast resin (bi) having from 0.5 to 3.5 moles of NH per mole of aminoplast resin (bi), a blocked acid catalyst (B) having a blocking agent which is not a tertiary amine, and a tertiary amine (C) present in an amount equal to 10 to 150% by weight of the blocking agent. The invention further provides a method of making cured coated substrates having improved scratch and mar resistance as well as a method of making multilayer coating compositions.
摘要翻译：本发明提供了具有改善的耐划伤性和耐擦伤性的涂料组合物。本发明的可固化涂料组合物包含含有一种或多种含活性氢成分（a）的成膜组分（A）和一种或多种包含至少一种具有0.5至 3.5摩尔NH /摩尔氨基塑料树脂（bi），具有不是叔胺的封闭剂的封闭酸催化剂（B）和等于10至150重量％的叔胺（C）的阻断剂。本发明还提供了一种制备具有改善的耐划伤性和耐擦伤性的固化的涂覆基材的方法以及制备多层涂料组合物的方法。

9. 发明申请

WO2002085540A1 CURABLE COATING COMPOSITIONS HAVING IMPROVED COMPATIBILITY AND SCRATCH AND MAR RESISTANCE, CURED COATED SUBSTRATES MADE THEREWITH AND METHODS FOR OBTAINING THE SAME 审中-公开
标题翻译：具有改进的兼容性和剥离性和耐电弧性的可固化涂料组合物，其固化的涂覆的基材及其获得的方法
公开(公告)号：WO2002085540A1
公开(公告)日：2002-10-31
申请号：PCT/US2002/012846
申请日：2002-04-23
申请人： BASF CORPORATION , CAMPBELL, Donald , COOK, Vincent , OERMANN, Bruce , BEARYMAN, William
发明人： CAMPBELL, Donald , COOK, Vincent , OERMANN, Bruce , BEARYMAN, William
IPC分类号： B05D1/36
CPC分类号： B05D7/536 , C09D161/20 , C09D161/32 , C09D201/00 , C09D201/025 , C08L2666/14
摘要： The invention provides curable coating compositions which have improved compatibility with other coating compositions and which provide improved scratch and mar resistance. The compositions comprise a film-forming component (A), a catalyst (B) for the film-forming reaction comprising one or more strong acids having a pK a of 2.5 or less, and a volatile catalyst carrier (C) comprising one or more tertiary amines having a boiling point of 100 degrees C. The film-forming component (A) comprises one or more crosslinking agents (b) at least one of which is an aminoplast curing agent (bi) having from 0.5 to 3.5 moles of NH per mole of aminoplast curing agent (bi). The invention also provides a method of making thermally cured films having improved scratch and mar as well as a method of making multilayer-cured films.
摘要翻译：本发明提供了具有改善的与其它涂料组合物的相容性并且提供改善的耐刮擦和耐擦伤性的可固化涂料组合物组合物包含成膜组分（A），用于成膜反应的催化剂（B），其包含一种或多种pKa为2.5或更小的强酸，和包含一种或多种叔碳酸酯的挥发性催化剂载体（C）沸点为100℃的胺。成膜组分（A）包含一种或多种交联剂（b），其中至少一种是每摩尔0.5至3.5摩尔NH的氨基塑料固化剂（bi）的氨基塑料固化剂（bi）。本发明还提供一种制备具有改进的划痕和耐磨性的热固化膜的方法以及制备多层固化膜的方法。

10. 发明申请

WO2007044481A1 CLEARCOAT COATING COMPOSITION 审中-公开
标题翻译： CLEARCOAT涂料组合物
公开(公告)号：WO2007044481A1
公开(公告)日：2007-04-19
申请号：PCT/US2006/039017
申请日：2006-10-05
申请人： BASF CORPORATION , BOISSEAU, John , CAMPBELL, Donald , OHRBOM, Walter , BALATAN, Sergio , MENOVCIK, Gregory
发明人： BOISSEAU, John , CAMPBELL, Donald , OHRBOM, Walter , BALATAN, Sergio , MENOVCIK, Gregory
IPC分类号： C09D133/06 , C08G18/62
CPC分类号： C09D133/06 , C08G18/6254 , C08K3/36 , C08K5/0008 , C09D175/04
摘要： A clearcoat coating composition comprises a vinyl or acrylic polymeric resin prepared by reacting a functional group on a vinyl or acrylic polymer, wherein the polymer has a glass transition temperature (Tg) ≥ 40°C as calculated by the Fox equation, with a reactant that provides a curable functional group that is separated from the polymer backbone by at least two alkylene, cycloalkylene, or arylene groups of at least two carbons each long.
摘要翻译：透明涂料组合物包括通过乙烯基或丙烯酸类聚合物上的官能团反应制备的乙烯基或丙烯酸聚合物树脂，其中该聚合物具有通过Fox方程计算的玻璃化转变温度（Tg）= 40℃，反应物为提供了通过至少两个长度为至少两个碳的亚烷基，亚环烷基或亚芳基与聚合物主链分离的可固化官能团。

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